公开(公告)号：GB2199586B

公开(公告)日：1990-05-23

申请号：GB8700164

申请日：1987-01-06

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/00 ,  C08G73/10 ,  C09J5/06 ,  C09J179/08 ,  C09J3/16

Abstract: This invention relates to a novel polyimide and describes method of its preparation, adhesives of the polyimide and the method for their application.The polyimide has recurring units of the formula(where R is a tetra-valent radical selected from the group consisting of aliphatic radical having not less than two carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function).The polyimide can be prepared by reacting 2,6-bis(3--amino-phenoxy)pyridine with tetracarboxylic dianhydride in an organic solvent and imidizing resultant polyamic acid.Various tetracarboxylic dianhydrides can be used and particularly preferred are pyromellitic dianhydride and 3,3',4,4'--benzophenonetetracarboxylic dianhydride.

公开(公告)号：GB2199585B

公开(公告)日：1990-05-23

申请号：GB8630966

申请日：1986-12-29

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/00 ,  C08G73/10 ,  C09J179/08 ,  C08G69/26 ,  C09J3/16

公开(公告)号：FR2609037B1

公开(公告)日：1989-11-17

申请号：FR8618369

申请日：1986-12-30

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/00 ,  C08G73/10 ,  C09J179/08 ,  C09J3/16 ,  C09J5/06

公开(公告)号：CH671403A5

公开(公告)日：1989-08-31

申请号：CH25187

申请日：1987-01-26

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/00 ,  C08G73/10 ,  C09J179/08

公开(公告)号：FR2609992B1

公开(公告)日：1989-04-28

申请号：FR8700857

申请日：1987-01-26

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/10 ,  C09J3/16 ,  C09J5/06

公开(公告)号：GB2199585A

公开(公告)日：1988-07-13

申请号：GB8630966

申请日：1986-12-29

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUGHI AKIHIRO

IPC: C08G73/00 ,  C08G73/10 ,  C09J179/08 ,  C08G69/26 ,  C09J3/16

公开(公告)号：AU6703686A

公开(公告)日：1988-06-30

申请号：AU6703686

申请日：1986-12-30

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/00 ,  C08G73/10 ,  C09J179/08 ,  C09J3/14

公开(公告)号：CH671230A5

公开(公告)日：1989-08-15

申请号：CH787

申请日：1987-01-05

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/00 ,  C08G73/10 ,  C09J5/06 ,  C09J179/08

公开(公告)号：FR2609992A1

公开(公告)日：1988-07-29

申请号：FR8700857

申请日：1987-01-26

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/10 ,  C09J3/16 ,  C09J5/06

Abstract: Polyimide which has repeat units of formula: in which formula the positions of the two carbonyl radicals on the benzene nucleus are meta or para positions and R is a tetravalent radical chosen from the group consisting of aliphatic radicals containing not fewer than two carbon atoms, cycloaliphatic radicals, monoaromatic radicals, condensed polyaromatic radicals and uncondensed polyaromatic radicals, where the aromatic radicals are mutually linked by a bond or a crosslinking functional group. This polyimide can be prepared by reaction of a diamine (ether diamine such as 1,3- or 1,4-bis[4-(3-aminophenoxy)benzoyl]benzene) with a tetracarboxylic dianhydride (pyromellitic dianhydride or 3,3',4,4'-benzophenonetetracarboxylic dianhydride) in organic solvents, and by imidation of the resulting poly(acid amide).

公开(公告)号：GB2199586A

公开(公告)日：1988-07-13

申请号：GB8700164

申请日：1987-01-06

Applicant: MITSUI TOATSU CHEMICALS

Inventor： TAMAI SHOJI ,  KAWASIMA SABURO ,  SONOBE YOSHIHO ,  OHTA MASAHIRO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08G73/00 ,  C08G73/10 ,  C09J5/06 ,  C09J179/08 ,  C09J3/16

Abstract: The polyimide has recurring units of the formula (where X is carbonyl radical or sulfonyl radical, and R is a tetra-valent radical selected from aliphatic radical having not less than two carbons, cyclo-aliphatic radical, monoaromatic radical, condensed polyaromatic radical, and non condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function). The polyimide can be prepared by reacting diamine with tetracarboxylic dianhydride in organic solvents and imidizing resultant polyamic acid. The diamine in use is ether diamine and includes 4,4'-bis [4-(4-amino- alpha ??? alpha -dimethylbenzyl) phenoxy] benzophenone and 4,4'-bis [4-(4-amino- alpha ??? alpha -dimethylbenzyl) phenoxy] diphenylsulfone. Various tetracarboxylic dianhydrides can be used and particularly preferred are pyromellitic dianhydride and 3,3 min , 4,4 min - benzophenonetetracarboxylic dianhydride. Uses:- Adhesives.b