公开(公告)号：DE69030680T2

公开(公告)日：1997-10-23

申请号：DE69030680

申请日：1990-03-05

Applicant: MITSUI TOATSU CHEMICALS

Inventor： OGATA NAOYA ,  ASANUMA TADASHI ,  NAKANISHI TAKEHISA

IPC: C08G63/81 ,  C08G69/28 ,  C08L67/00 ,  C08L67/02 ,  C08L77/00

Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.

公开(公告)号：DE69030680D1

公开(公告)日：1997-06-19

申请号：DE69030680

申请日：1990-03-05

Applicant: MITSUI TOATSU CHEMICALS

Inventor： OGATA NAOYA ,  ASANUMA TADASHI ,  NAKANISHI TAKEHISA

IPC: C08G63/81 ,  C08G69/28 ,  C08L67/00 ,  C08L67/02 ,  C08L77/00

Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.

公开(公告)号：CA2011630A1

公开(公告)日：1990-09-08

申请号：CA2011630

申请日：1990-03-07

Applicant: MITSUI TOATSU CHEMICALS

Inventor： OGATA NAOYA ,  NAKANISHI TAKEHISA ,  ASANUMA TADASHI

IPC: C08G63/81 ,  C08G69/28 ,  C08L67/00 ,  C08L67/02 ,  C08L77/00 ,  C08L67/04 ,  C08L77/10

Abstract: of the Disclosure The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.

公开(公告)号：JPH01229033A

公开(公告)日：1989-09-12

申请号：JP5266588

申请日：1988-03-08

Applicant: MITSUI TOATSU CHEMICALS

Inventor： NAKANISHI TAKEHISA ,  MIURA TOSHISUMI ,  OGATA NAOYA

IPC: C09K19/38 ,  C08G63/06

Abstract: PURPOSE:To obtain the title movel polymer outstanding in heat resistance, giving liquid crystal property when dissolved in a specific solvent, thus useful for e.g., liquid crystal display elements, by copolycondensation between p- oxyenzoic acid and a dimethyl-hydroxybenzoic acid in specified proportion. CONSTITUTION:The objective polymer obtained by copolycondensation between (A) p-oxybenzoic acid and (B) 3,5-dimethyl-4-hydroxybenzoic acid in the molar ratio A/B=0.35/0.65-0.65/0.35, with its 10wt.% 0-chlorophenol solution prepared at 50 deg.C having liquid crystal property. This polymer is suggested to be obtained by the following process: a solvent such as nitrobenzene is incorporated with triphenylphosphine oxide and phosgene to form triphenylphosphine dichloride as the catalyst followed by incorporating the resultant catalytic system with the components A and B and carrying out polycondensation in the presence of e.g., triethylamine.

公开(公告)号：JPH0320327A

公开(公告)日：1991-01-29

申请号：JP4580890

申请日：1990-02-28

Applicant: MITSUI TOATSU CHEMICALS

Inventor： OGATA NAOYA ,  NAKANISHI TAKEHISA ,  ASANUMA TADASHI

IPC: C08G69/02 ,  C08G63/19 ,  C08G63/60 ,  C08G63/78 ,  C08G69/04 ,  C08G69/28 ,  C08G69/32 ,  C08G69/36 ,  C08J3/21 ,  C08L67/00 ,  C08L67/02 ,  C08L77/00

Abstract: PURPOSE:To obtain the subject composite having excellent heat resistance characteristic of an aromatic condensation polymer and improved processability by polycondensing a starting monomer in a solution of a soluble polymer in an organic solvent to form an aromatic condensation polymer insoluble in the solvent. CONSTITUTION:An aromatic dicarboxylic acid and an aromatic diol, or an aromatic dicarboxylic acid, an aromatic diamine, an aromatic aminocarboxylic acid or the like are polycondensed in the presence of a catalyst, or an aromatic dicarboxylic dihalide and an aromatic diol, or an aromatic dicarboxylic dihalide and an aromatic diamine as starting monomers are polycondensed in the absence of any catalyst in a solution of a soluble polymer in an organic solvent (e.g. a solution of a polyarylate in a mixed chloroform/pyridine solvent) to form an aromatic polyester or an aromatic polyamide insoluble in the solvent. In this way, a thermoplastic resin composite composed of a homogeneous mixture of the polymer soluble in the solvent with the aromatic condensation polymers insoluble in the solvent can be obtained.