公开(公告)号：WO2008135529A2

公开(公告)日：2008-11-13

申请号：PCT/EP2008055416

申请日：2008-05-02

Applicant: MULTIBASE SA ,  MILESI DANIEL ,  PRELE PATRICK ,  VON TSCHAMMER ALEXIS

Inventor： MILESI DANIEL ,  PRELE PATRICK ,  VON TSCHAMMER ALEXIS

IPC: C08K3/36 ,  B29B7/90 ,  B29B9/12 ,  B60J5/00 ,  B60K37/00 ,  B60R19/03 ,  C08J3/20 ,  C08J3/22 ,  C08K3/34 ,  C08K7/00 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16

CPC classification number: C08L23/12 ,  B29C47/369 ,  B29C47/6087 ,  B29C47/92 ,  C08K3/36 ,  C08K7/00 ,  C08L23/10 ,  C08L2205/02 ,  C08L2666/06 ,  C08L2666/04 ,  C08L2666/24

Abstract: A process is disclosed of obtaining a thermoplastic composition formed from a polyolefin matrix comprising a polypropylene with a fluidity index of from 2 to 100 g/10 minutes when measured at 230°C under 2.16 kg, and a mineral lamellar filler which is talc with a median diameter D50 of at least 1 µm, as measured by Sedigraph, and a lamellarity index of at least 4 before introduction into the matrix and at least 3 when measured in the thermoplastic composition, by dispersing the lamellar talc in the polyolefin matrix in a viscoelastic state by means of at least on compounding extruder, which process comprises (a) the formation of a viscoelastic mixture of the polypropylene matrix and the lamellar mineral talc particles by heating and kneading the said composition at a temperature at least equal to the working temperature of the polypropylene, (b) the submission of the viscoelastic mixture to thermo-mechanical work, (c) the elimination of volatile components from the viscoelastic mixture, (d) the transformation of the viscoelastic mixture resulting from step (c) into an industrially usable granulated material, characterised in that, to obtain a controlled and homogenous dispersion and distribution of the lamellar mineral talc in the polypropylene matrix, while substantially retaining initial morphological characteristics of the lamellar mineral talc particles, the viscoelastic mixture is subjected during steps (a) and (b) to a weak and controlled rate of shearing of no more than 200s -1 and the viscoelastic mixture is subjected in step (b) to at least one cycle of extension and relaxation in a dedicated zone which is at least 25% of the total length of the at least one screw of the compounding extruder. Also disclosed is the use of thermoplastic compositions obtained by such process in the manufacture of products for the automotive industry, domestic appliance industry, electronic industry, building industry, construction industry, internal design industry, sport and leisure industry, in packaging or in toys.

Abstract translation: 公开了一种获得由聚烯烃基质形成的热塑性组合物的方法，该聚烯烃基质包含流体指数为2至100g / 10分钟的聚丙烯，在2.16kg的230℃下测量，以及一种矿物层状填料，其为具有 通过Sedigraph测量的中值粒径D50至少为1μm，在引入基质之前的薄层指数至少为4，并且在热塑性组合物中测量时至少为3，通过将层状滑石分散在聚烯烃基质中，以粘弹性 通过至少在复合挤出机上进行处理，该方法包括（a）通过在至少等于工作温度的温度下加热和捏合所述组合物来形成聚丙烯基质和层状矿物滑石颗粒的粘弹性混合物 聚丙烯，（b）将粘弹性混合物提交到热机械工作，（c）从粘弹性混合物中消除挥发性组分 （d）将由步骤（c）得到的粘弹性混合物转化成工业上可用的造粒材料，其特征在于，为了获得在聚丙烯基质中的层状矿物滑石的受控且均匀的分散和分布，同时基本保持 层状矿物滑石颗粒的初始形态特征，在步骤（a）和（b）期间将粘弹性混合物施加到不超过200s -1的弱和受控的剪切速率和粘弹性混合物 在步骤（b）中进行至少一个在专用区域中延伸和松弛的循环，所述专用区域是复合挤出机的至少一个螺杆的总长度的至少25％。 还公开了通过这种方法获得的热塑性组合物在制造用于汽车工业，家用电器工业，电子工业，建筑工业，建筑业，内部设计行业，体育和休闲产业，包装或玩具中的产品中的用途。

公开(公告)号：CA2743106A1

公开(公告)日：2010-07-01

申请号：CA2743106

申请日：2009-12-23

Applicant: MULTIBASE SA

Inventor： MILESI DANIEL

IPC: C08L53/02 ,  A41D31/00 ,  C08L83/04

Abstract: Use of a material for the absorption of impact energy wherein the composition of the material is a mixture of, at least component (A) which is an organic thermoplastic elastomer having a hardness below 80 shore A measured at 23°C and component (B) which is a non cross- linked and substantially non reactive silicone polymer or a cross-linked silicone polymer, with the exclusion of borated silicone polymers exhibiting dilatant properties.

公开(公告)号：FR2791062B1

公开(公告)日：2003-09-12

申请号：FR9903540

申请日：1999-03-15

Applicant: MULTIBASE SA

Inventor： MICHEL ALAIN ,  VERBOIS AGNES ,  BERT MICHEL ,  ANGELLOZ CHRISTOPHE ,  BLANC PATRICE ,  PAGES XAVIER ,  MILESI DANIEL

IPC: C08J3/24 ,  C08F8/00 ,  C08K5/057 ,  C08K5/57 ,  C08L23/00 ,  C08L31/04 ,  C08L75/04 ,  C08L77/00 ,  C08L101/00 ,  C08F8/42 ,  C08L23/08

公开(公告)号：FR2791062A1

公开(公告)日：2000-09-22

申请号：FR9903540

申请日：1999-03-15

Applicant: MULTIBASE SA

Inventor： MICHEL ALAIN ,  VERBOIS AGNES ,  BERT MICHEL ,  ANGELLOZ CHRISTOPHE ,  BLANC PATRICE ,  PAGES XAVIER ,  MILESI DANIEL

IPC: C08J3/24 ,  C08F8/00 ,  C08K5/057 ,  C08K5/57 ,  C08L23/00 ,  C08L31/04 ,  C08L75/04 ,  C08L77/00 ,  C08L101/00 ,  C08F8/42 ,  C08L23/08

Abstract: The invention concerns a method for crosslinking a thermoplastic polymer or copolymer with vinyl acetate units, which consists in reacting, during the implementing processes, at a temperature ranging between 80 DEG C and 280 DEG C: the polymer or copolymer with vinyl acetate units, and a polyfunctional alcoholate, in the presence of a catalyst. The crosslinking of polymers or copolymers with vinyl acetate units in the presence of a second thermoplastic polymer or copolymer enables to prepare TPV materials. The method for obtaining a hybrid organic-inorganic material consists in: dispersing and grafting an inorganic network on a thermoplastic polymer or copolymer with vinyl acetate units inducing hydrolysis-condensation of the polyfunctional alcoholate pertaining to the network based on polymer or copolymer with vinyl acetate units and of the excess polyfunctional alcoholate. Said dispersion and said grafting can be carried out in the presence of a second thermoplastic polymer or copolymer for producing hybrid organic-inorganic TPV materials.

公开(公告)号：FR2931160A1

公开(公告)日：2009-11-20

申请号：FR0853177

申请日：2008-05-16

Applicant: MULTIBASE SA

Inventor： MILESI DANIEL ,  ROUSSEAU PIERRE

IPC: C08L23/20 ,  B29B9/12 ,  B29C48/32 ,  C08J3/24 ,  C08L23/02 ,  C08L53/00 ,  C08L83/05 ,  C08L83/07 ,  F16L11/04

Abstract: L'invention concerne un élastomère thermoplastique comprenant :A1) une matrice polymérique (a) constituée :d'un polymère thermoplastique obtenu par polymérisation ou copolymérisation d'un monomère de butène-1, oud'un mélange d'un polymère thermoplastique obtenu par homopolymérisation ou copolymérisation d'un monomère de butène-1, avec un ou plusieurs polymères thermoplastiques compatibles,B1) un polydiorganosiloxane réticulé (B1) obtenu par réticulation des composés (b) et (c) suivants :- un polydiorganosiloxane (b) ayant une plasticité de Williams d'au moins 30 déterminée par la méthode d'essai ASTM 926 et ayant une moyenne d'au moins 2 radicaux alcényles par molécule,- un composé organohydrido silicium (c) ayant une moyenne, par molécule, d'au moins 2 atomes de silicium liés directement à un atome d'hydrogène,en présence d'un catalyseur d'hydro sililation (d),le polydiorganosiloxane réticulé (B1) étant dispersé dans la matrice polymérique (a) et l'utilisation d'un tel élastomère pour la fabrication de conduits flexibles pour le transport de l'eau potable.

公开(公告)号：CA2685531A1

公开(公告)日：2008-11-13

申请号：CA2685531

申请日：2008-05-02

Applicant: MULTIBASE SA

Inventor： PRELE PATRICK ,  VON TSCHAMMER ALEXIS ,  MILESI DANIEL

IPC: C08K3/36 ,  C08J3/20 ,  C08K7/00 ,  C08L23/12

Abstract: A process is disclosed of obtaining a thermoplastic composition formed fr om a polyolefin matrix comprising a polypropylene with a fluidity index of f rom 2 to 100 g/10 minutes when measured at 230°C under 2.16 kg, and a minera l lamellar filler which is talc with a median diameter D50 of at least 1 .mu .m, as measured by Sedigraph, and a lamellarity index of at least 4 before i ntroduction into the matrix and at least 3 when measured in the thermoplasti c composition, by dispersing the lamellar talc in the polyolefin matrix in a viscoelastic state by means of at least on compounding extruder, which proc ess comprises (a) the formation of a viscoelastic mixture of the polypropyle ne matrix and the lamellar mineral talc particles by heating and kneading th e said composition at a temperature at least equal to the working temperatur e of the polypropylene, (b) the submission of the viscoelastic mixture to th ermo-mechanical work, (c) the elimination of volatile components from the vi scoelastic mixture, (d) the transformation of the viscoelastic mixture resul ting from step (c) into an industrially usable granulated material, characte rised in that, to obtain a controlled and homogenous dispersion and distribu tion of the lamellar mineral talc in the polypropylene matrix, while substan tially retaining initial morphological characteristics of the lamellar miner al talc particles, the viscoelastic mixture is subjected during steps (a) an d (b) to a weak and controlled rate of shearing of no more than 200s-1 and t he viscoelastic mixture is subjected in step (b) to at least one cycle of ex tension and relaxation in a dedicated zone which is at least 25% of the tota l length of the at least one screw of the compounding extruder. Also disclos ed is the use of thermoplastic compositions obtained by such process in the manufacture of products for the automotive industry, domestic appliance indu stry, electronic industry, building industry, construction industry, interna l design industry, sport and leisure industry, in packaging or in toys.

公开(公告)号：MX2009011689A

公开(公告)日：2010-01-29

申请号：MX2009011689

申请日：2008-05-02

Applicant: MULTIBASE SA

Inventor： MILESI DANIEL ,  PRELE PATRICK ,  TSCHAMMER ALEXIS VON

IPC: C08K3/36 ,  B29B7/90 ,  B29B9/12 ,  B60J5/00 ,  B60K37/00 ,  B60R19/03 ,  C08J3/20 ,  C08J3/22 ,  C08K3/34 ,  C08K7/00 ,  C08L23/10 ,  C08L23/12 ,  C08L23/16

Abstract: Se describe un proceso para la obtención de una composición termoplástica formada a partir de una matriz poliolefínica que comprende un polipropileno con un índice de fluidez desde 2 hasta 100 g/l0 minutos cuando se mide a 230ºC, bajo 2.16 kg; y un relleno mineral laminar el cual es talco con un diámetro medio D50 de al menos 1 mum, como se midió con un Sedigraph; y un índice laminar de al menos 4 antes de la introducción dentro de la matriz y de al menos 3 cuando se mide en la composición termoplástica, por dispersión del talco laminar en la matriz poliolefínica en un estado viscoelástico por medio de al menos sobre el extrusor de composición, dicho proceso comprende (a) la formación de una mezcla viscoelástica de la matriz de polipropileno y las partículas del talco laminar mineral por calentamiento y al amasar dicha composición a una temperatura de al menos igual a la temperatura de trabajo del polipropileno, (b) la sumisión de la mezcla viscoelástica a trabajo termo-mecánico, (c) la eliminación de componentes volátiles de la mezcla viscoelástica, (d) la transformación de la mezcla viscoelástica resultante del paso (c) dentro de un material granulado utilizable industrialmente, caracterizado en que, para obtener una dispersión y distribución homogénea y controlada del talco laminar mineral en la matriz de polipropileno, mientras que retiene sustancialmente las características morfológicas iniciales de las partículas de talco laminar mineral, la mezcla viscoelástica esta sujeta durante los pasos (a) y (b) a una frecuencia débil y controlada de corte de no mas de 200 s y la mezcla viscoelástica esta sujeta en el paso (b) a al menos un ciclo de extensión y relajación en una zona dedicada la cual es al menos del 25% de la longitud total de al menos un tornillo del extrusor de composición. También se describe el uso de las composiciones termoplásticas obtenidas por tal proceso en la fabricación de productos para la industria automotriz, industria de electrodomésticos, industria electrónica, industria de la construcción, industria del diseño interno, industria deportiva y recreativa, en empaques y en juguetes.

公开(公告)号：DE602005017823D1

公开(公告)日：2009-12-31

申请号：DE602005017823

申请日：2005-12-22

Applicant: MULTIBASE SA

Inventor： VON TSCHAMMER ALEXIS ,  MILESI DANIEL

IPC: C08L23/14

Abstract: Elastomeric polyolefinic thermoplastic composition (A), (for the formation of a part of the insert type cap for placing a safety air cushion in a motor vehicle), comprises an olefinic polymer (I) comprising propylene, a copolymer (II) containing alpha -olefin ethylene (IIa), a cross linking agent (III) and a free radical generating agent (IV), where (A) further comprises a thermoplastic elastomer and optionally a high density polyethylene. Elastomeric polyolefinic thermoplastic composition (A) (partially cross linked), (for the formation of a part of the insert type cap for placing a safety air cushion in a motor vehicle), comprises an olefinic polymer (I) comprising propylene, a copolymer (II) containing alpha -olefin ethylene (IIa), a cross linking agent (III) and a free radical generating agent (IV), where (I) is a copolymers of propylene/ethylene or propylene/alpha olefin or a compound having a shock resistance of at least 30 kJ/m 2> (measured according to the standard of ISO 180 and lzod notched at 23[deg]C), (II) has density of 0.870 g/cm 3> (measured according to the standard of ISO 1183), and (A) further comprises a thermoplastic elastomer and optionally a high density polyethylene. An independent claim is also included for a molded cap produced from (A) for housing a safety air cushion (which will be opened by controlled tear to spread the cushion at the time of the firing of the pyrotechnical system without fragmenting at the time of bursting at low temperature) of a motor vehicle.