公开(公告)号：EP3133057A4

公开(公告)日：2017-08-30

申请号：EP15780158

申请日：2015-04-14

Applicant: NOF CORP

Inventor： FUJITA HIROYA ,  OHARA SHINJI ,  MARUYAMA KEI-ICHI ,  IWATA TOMOKI

IPC: C07C51/60 ,  C07C53/42 ,  C07C57/66

CPC classification number: C07C51/60 ,  C07C53/42 ,  C07C57/66

Abstract: Provided is a fatty acid chloride which is manufactured by a simple method, which does not cloud and which has stable color over time. A fatty acid chloride is produced by causing a fatty acid with a carbon number of 8-22 and phosphorous trichloride in a proportion of one-third to two-thirds with respect to the fatty acid to react and removing phosphorous acid that appears as a byproduct to obtain a reaction product. Next, the reaction product is treated at a temperature of 10-60°C, a nitrogen flow rate of 1.0 × 10 -4 to 1.0 × 10 -2 m 3 /kg·hr, and a pressure of 133.3 X 10 -2 to 133.3 × 10 2 Pa, the unreacted phosphorous trichloride is caused to react with the fatty acid and the fatty acid chloride to produce an organic phosphorous compound, and the unreacted phosphorous trichloride is distilled to obtain the fatty acid chloride.

Abstract translation: 本发明提供一种通过简便的方法制造的不会变色且随着时间的推移色彩稳定的脂肪酰氯。 通过使相对于脂肪酸的碳原子数为8〜22的脂肪酸和三氯化磷的比例为三分之一至三分之二以反应并除去作为副产物出现的亚磷酸而生成脂肪酸氯化物 得到反应产物。 接着，在10〜60℃的温度，1.0×10 -4〜1.0×10 -2 m 3 / kg·hr的氮气流量，133.3×10 -2〜 133.3×10 2 Pa，使未反应的三氯化磷与脂肪酸和脂肪酰氯反应生成有机磷化合物，蒸馏未反应的三氯化磷得到脂肪酰氯。

公开(公告)号：EP3133056A4

公开(公告)日：2017-08-30

申请号：EP15779479

申请日：2015-04-14

Applicant: NOF CORP

Inventor： FUJITA HIROYA ,  OHARA SHINJI

IPC: C07C51/60 ,  C07C51/64 ,  C07C53/42

CPC classification number: C07C51/60 ,  C07C51/64 ,  C07C53/42

Abstract: Provided is a method for manufacturing, by a simple method, a fatty acid chloride that does not cloud and has stable color over time. A fatty acid chloride is produced by causing a fatty acid with a carbon number of 8-22 and one-third to two-thirds molar equivalent, with respect to the fatty acid, of phosphorous trichloride to react and, after static layer separation, removing byproduct phosphorous acid to obtain a reaction product. By refining this reaction product, obtained is a refined product in which the byproduct phosphorous acid is no more than 0.20% by weight as the phosphorous content. 0.03-0.07% by weight of the phosphorous trichloride, as phosphorous content, is added to this refined product.

Abstract translation: 本发明提供一种通过简单的方法制造不会变色且随着时间变化稳定的颜色的脂肪酸氯化物的方法。 脂肪酰氯是通过使具有8-22个碳数的和的三分之一到三分之二摩尔当量的脂肪酸，相对于所述脂肪酸，三氯化磷的反应和，静态层分离之后，除去所产生的 副产物亚磷酸以获得反应产物。 通过精制该反应产物，得到副产物亚磷酸含量不超过0.20重量％的精制产物。 作为磷含量，将0.03-0.07重量％的三氯化磷加入到该精炼产品中。

公开(公告)号：EP2756838A4

公开(公告)日：2015-06-24

申请号：EP12831242

申请日：2012-09-12

Applicant: NOF CORP

Inventor： FUJITA HIROYA ,  IWATA TOMOKI

IPC: A61K8/44 ,  A61K8/41 ,  A61K8/46 ,  A61K8/73 ,  A61Q5/02 ,  C11D1/10 ,  C11D1/90 ,  C11D3/37

CPC classification number: A61K8/466 ,  A61K8/44 ,  A61K8/442 ,  A61K8/731 ,  A61K8/737 ,  A61K8/817 ,  A61K2800/5426 ,  A61K2800/59 ,  A61Q5/02

公开(公告)号：EP1803800A4

公开(公告)日：2008-08-20

申请号：EP05785623

申请日：2005-09-16

Applicant: NOF CORP

Inventor： SHIMADA MASAHIKO ,  FUJITA HIROYA ,  IWAMA TAKASHI

IPC: C11D1/28 ,  C11D1/12 ,  C11D1/37

CPC classification number: A61Q19/10 ,  A61K8/442 ,  A61K8/466 ,  A61K2800/596 ,  A61Q5/02 ,  C11D1/10 ,  C11D1/126 ,  C11D1/18 ,  C11D1/28 ,  C11D1/29 ,  C11D1/37 ,  C11D10/042

Abstract: A detergent composition which contains a taurine derivative (a) represented by the formula (I) and at least one anionic surfactant (b) selected from the group consisting of anionic surfactants having a sulfuric acid group or sulfo group, acylamino acid type anionic surfactants, and C8-22 fatty acid salts, in a specific proportion. The detergent composition lathers well (even when an oily ingredient coexists) and the lather is creamy. When cleaning is conducted with a detergent comprising the composition, the detergent gives no slimy feeling during rinse and the lather can be eliminated rapidly. After cleaning (after drying), the detergent gives neither a stretched feeling nor a dry feeling to the skin. The detergent attains an excellent finishing of cleaning.

Abstract translation: 一种洗涤剂组合物，它含有由式（I）表示的牛磺酸衍生物（a）和至少一种选自具有硫酸基或磺基的阴离子表面活性剂的阴离子表面活性剂（b），酰基氨基酸型阴离子表面活性剂， 和C8-22脂肪酸盐，以特定的比例。 洗涤剂组合物泡沫良好（即使油性成分共存）并且泡沫是奶油状的。 当用包含该组合物的清洁剂进行清洁时，该清洁剂在清洗过程中不会感觉到粘腻感，并且可以迅速消除泡沫。 清洁后（干燥后），清洁剂不会给皮肤带来舒展感和干燥感。 洗涤剂达到极佳的清洁效果。

公开(公告)号：JP2014189530A

公开(公告)日：2014-10-06

申请号：JP2013068129

申请日：2013-03-28

Applicant: Nof Corp ,  日油株式会社

Inventor： MATSUO SATOSHI ,  FUJITA HIROYA

IPC: A61K8/36 ,  A61K8/44 ,  A61K8/46 ,  A61Q19/10 ,  C11D1/04 ,  C11D1/10 ,  C11D1/12 ,  C11D3/34

Abstract: PROBLEM TO BE SOLVED: To provide a skin cleanser composition which provides a moist feeling after using and has a small viscosity change due to temperature without providing a slimy feeling at the time of use.SOLUTION: There is provided a skin cleanser composition in which a ratio of a component (a) is 0.01 to 5 mass%, a ratio of a component (b) is 5 to 30 mass%, a ratio of a component (c) is 1.0 to 20 mass%, (b)/(c) is 1/2 to 20/1, the total ratio of the component (a), the component (b) and the component (c) is 10 to 50 mass% and the remainder is water. (a) a compound represented by the following formula (1); (b) an alkali metal salt, an ammonium salt or an organic ammonium salt of a fatty acid having 8 to 22 carbon atoms; (c) an acylamino acid-based anionic surfactant.

Abstract translation: 要解决的问题：提供一种皮肤清洁剂组合物，其在使用后提供湿润感，并且由于温度而具有小的粘度变化，而在使用时不会产生粘稠感。解决方案：提供一种皮肤清洁剂组合物，其中 成分（a）的比例为0.01〜5质量％，成分（b）的比例为5〜30质量％，成分（c）的比例为1.0〜20质量％，（b）/（c ）为1/2〜20/1，成分（a），成分（b）和成分（c）的总比例为10〜50质量％，余量为水。 （a）由下式（1）表示的化合物; （b）具有8-22个碳原子的脂肪酸的碱金属盐，铵盐或有机铵盐; （c）酰基氨基酸类阴离子表面活性剂。

公开(公告)号：JP2014208921A

公开(公告)日：2014-11-06

申请号：JP2014003304

申请日：2014-01-10

Applicant: 日油株式会社 ,  Nof Corp

Inventor： YAMANAKA AIKO ,  FUJITA HIROYA ,  MARUYAMA KEIICHI

IPC: D21H21/22 ,  A47K10/16 ,  D21H17/06 ,  D21H17/24

CPC classification number: A47K10/16 ,  D21H17/06 ,  D21H17/24 ,  D21H21/22

Abstract: 【課題】長期にわたる低湿度環境下においても衛生紙に柔らかさを付与することができ、経時的な臭気発生を抑えることができる衛生紙用柔軟剤の提供。【解決手段】(A)グリセリン、および(B)還元性物質の含量が0.20質量%未満であって、炭素数10〜22のアシル基を有するショ糖脂肪酸エステルを含有し、(A)成分と(B)成分の質量比が(A)/(B)=95/5〜99.9/0.1である衛生紙用柔軟剤。【選択図】なし

Abstract translation: 要解决的问题：提供一种卫生纸柔软剂，即使在长期低湿度环境下也能赋予卫生纸的柔软性，并且随着时间的推移抑制气味的发展。解决方案：用于卫生纸的柔软剂含有（A）甘油和（B ）具有10-22C酰基的小于0.20质量％的还原物质含量的蔗糖脂肪酸酯，以（A）成分（B）的成分（B）的质量比（A）/（B） 95/5至99.9 / 0.1。

公开(公告)号：JP2010105969A

公开(公告)日：2010-05-13

申请号：JP2008281118

申请日：2008-10-31

Applicant: Nof Corp ,  日油株式会社

Inventor： FUJITA HIROYA ,  SHINDO KAKU ,  MIZUTA MOTONARI ,  MASUMOTO TAKENORI

IPC: A61K8/39 ,  A61K8/34 ,  A61K8/37 ,  A61K8/44 ,  A61K8/86 ,  A61Q1/14 ,  C11D1/74 ,  C11D1/88 ,  C11D3/20

Abstract: PROBLEM TO BE SOLVED: To provide a cleansing agent that gives refreshing and moisture feeling after use and good spread free of stickiness during use and is excellent in cleansing capability, rinsability and preservation stability as well as can be easily removed.
SOLUTION: The cleansing agent contains a compound (A) represented by formula: RC00(C
4 H
8 O)
n H, a compound (B) represented by formula (2): M
1 OCOR
2 -NR
1 -R
3 COOM
2 and a polyhydric alcohol(C) of 2 to 4 hydroxy units having a molecular weight of 500 or less. The ratio a/(b+c) is 1/100 to 1/4; b/c is 1/19 to 1/1; and the sum a+b+c is 100 parts by weight, wherein a, b and c are each a part by weight of (A), (B) and (C) respectively. In formula (2), R
1 indicates 10 to 18C alkyl or alkenyl; R
2 and R
3 indicate each 1 to 3C alkylene; M
1 and M
2 indicate each hydrogen, an alkali metal, alkaline-earth metal, ammonium or organic ammonium.
COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供使用后提供清爽和湿润感的清洁剂，在使用期间良好的无粘性的涂抹，并且清洗能力，漂洗性和保存稳定性以及易于除去。 解决方案：清洁剂含有由下式表示的化合物（A）：RC00（C 4 8 O） 由式（2）表示的化合物（B）：M 1 COOM＆lt; SP＆gt; 2＆gt;和分子量为500以下的2〜4个羟基单元的多元醇（C）。 比率a /（b + c）为1/100至1/4; b / c为1/19〜1/1; 和a + b + c之和为100重量份，其中a，b和c分别为（A），（B）和（C）的重量份。 式（2）中，R SP 1表示10〜18个碳原子的烷基或烯基; R 2 和R 3 表示每1至3个亚烷基; M 1 和M 2 表示每个氢，碱金属，碱土金属，铵或有机铵。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2006306908A

公开(公告)日：2006-11-09

申请号：JP2005127667

申请日：2005-04-26

Applicant: Nof Corp ,  日本油脂株式会社

Inventor： SHIMADA MASAHIKO ,  FUJITA HIROYA

IPC: C11D1/10 ,  A61K8/00 ,  A61Q5/02 ,  A61Q19/10 ,  C11D1/12

Abstract: PROBLEM TO BE SOLVED: To provide a detergent composition which gives creamy lather, does not get slimy, washes well and exhibits rapid breaking of lather upon rinsing and lathers well, when an oily component coexists.
SOLUTION: The detergent composition contains (a) an acylamino acid salt having a 6-10C acyl group and (b) an anionic surfactant having a sulfuric acid group or a sulfonic acid group. The composition contains 0.05-30 mass% of the acylamino acid salt (a) and 1-50 mass% of the anionic surfactant (b). The mass ratio of the acylamino acid salt (a) to the anionic surfactant (b) is 1/100-1/1.
COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供一种洗发剂组合物，其在油性成分共存时，可以很好地洗涤和起泡，得到乳状泡沫，不会变得粘稠，洗涤性好，并且表现出快速的泡沫破裂。 溶液：洗涤剂组合物含有（a）具有6-10C酰基的酰基氨基酸盐和（b）具有硫酸基或磺酸基的阴离子表面活性剂。 该组合物含有0.05-30质量％的酰氨基酸盐（a）和1-50质量％的阴离子表面活性剂（b）。 酰氨基酸盐（a）与阴离子表面活性剂（b）的质量比为1 / 100-1 / 1。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2004067707A

公开(公告)日：2004-03-04

申请号：JP2002224433

申请日：2002-08-01

Applicant: Nof Corp ,  日本油脂株式会社

Inventor： FUJITA HIROYA ,  KOBAYASHI JUNJI

IPC: C11D1/722 ,  C11D1/52 ,  C11D17/08

Abstract: PROBLEM TO BE SOLVED: To provide a liquid detergent composition for kitchens which exhibits an excellent detgergency against staining due to fats and oils, has a suitable fluidity even when highly concentrated, and is excellent in low-temperature storage stability. SOLUTION: The liquid detergent composition contains (a) a nonionic surfactant represented by formula (1): R 1 O(AO) x (BO) y (AO) z H (wherein R 1 is an 8-24C alkyl, alkenyl, or acyl group; AO is oxyethylene group; BO is oxybutylene group; and x, y, and z are each an average number of addition moles, provided 0≤x≤10, 1≤y≤5, 5≤z≤20, and 6≤x+z≤20) and (b) an alkanolamide-type nonionic surfactant with a total weight of (a+b) of 10-100 wt.% and in a wt. ratio of (a/b) of (1/5)-(10/1). COPYRIGHT: (C)2004,JPO

公开(公告)号：JP2003226900A

公开(公告)日：2003-08-15

申请号：JP2002026218

申请日：2002-02-04

Applicant: NOF CORP

Inventor： AZUMA TAKAYA ,  FUJITA HIROYA

IPC: C11D17/08 ,  C11D1/04 ,  C11D1/12 ,  C11D1/722

Abstract: PROBLEM TO BE SOLVED: To obtain a liquid detergent composition having excellent permeability into fibers, realizing excellent detergency even when mechanical force is small, obtaining excellent texture after washing and having excellent storage stability. SOLUTION: This liquid detergent composition is characterized by comprising (a). a sulfated unsaturated fatty acid salt or a fatty acid salt, (b). a nonionic surfactant represented by formula (1), wherein the EO (ethylene oxide) content in the molecule of formula (1) is 10-35 wt.%, (c). a nonionic surfactant represented by formula (2), wherein the EO content in the molecule of formula (2) is 50-70 wt.%, wherein (a) is 1-20 wt.%, (b+c) is 10-50 wt.%, (b/c) is 1/15 to 10/1. formula (1): R 1 (BO)p(EO)q (wherein, R 1 is an 8-24C alkyl, alkenyl or acyl; BO is butylene oxide; EO is ethylene oxide; (p) and (q) are each an average additional moler number and (p) is 1-5 and (q) is 1-5.) formula (2): R 2 (BO)x(EO)y (wherein, R 2 is a 8-24C alkyl, alkenyl or acyl; BO is butylene oxide; EO is ethylene oxide; and (x) and (y) are each an average additional molecular number, and (x) is 1-5 and (y) is 6-20.). COPYRIGHT: (C)2003,JPO