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    MAIN GROUP METAL COMPLEXES AS P-DOPANTS FOR ORGANIC ELECTRONIC MATRIX MATERIALS
    2.
    发明申请
    MAIN GROUP METAL COMPLEXES AS P-DOPANTS FOR ORGANIC ELECTRONIC MATRIX MATERIALS 审中-公开
    主要金属复合材料作为有机电子基质材料的P-DOPANTS

    公开(公告)号：US20150123047A1

    公开(公告)日：2015-05-07

    申请号：US14406041

    申请日：2013-05-14

    Applicant: SIEMENS AKTIENGESELLSCHAFT ,  OSRAM OLED GMBH

    Inventor： Anna Maltenberger ,  Marina A. Petrukhina ,  Guenter Schmid ,  Jan Hauke Wemken

    IPC: H01L51/00

    CPC classification number: H01L51/0077 ,  C07F9/94 ,  C09K11/06 ,  C09K2211/188 ,  H01L51/002 ,  H01L51/009 ,  H01L51/506 ,  Y02E10/549 ,  Y02P70/521

    Abstract: A metal complex of a metal from groups 13 to 16 uses a ligand of the structure (I), where R1 and R2 can independently be oxygen, sulfur, selenium, NH or NR4, where R4 an alkyl or aryl and can be connected to R3. R3 is an alkyl, long-chain alkyl, alkoxy, long-chain alkoxy, cycloalkyl, halogenalkyl, aryl, arylene, halogenaryl, heteroaryl, heteroarylene, heterocycloalkylene, heterocycloalkyl, halogenheteroaryl, alkenyl, halogenalkenyl, alkynyl, halogenalkynyl, ketoaryl, halogenketoaryl, ketoheteroaryl, ketoalkyl, halogenketoalkyl, ketoalkenyl, halogenketoalkenyl, where in suitable radicals, one or more non-adjacent CH2— groups can be substituted independently of one another by —O—, —S—, —NH—, —NRo—, —SiRoRoo—, —CO—, —COO—, —OCO—, —OCO—O—, —SO2—, —S—CO—, —CO—S—, —CY1=CY2 or —C═C—, specifically in such a way that O and/or S atoms are not connected directly to one another, are likewise optionally substituted with aryl- or heteroaryl preferably containing 1 to 30 C atoms, as a dopant for matrix materials in organic electronic components.

    Abstract translation: 来自组13至16的金属的金属络合物使用结构（I）的配体，其中R 1和R 2可以独立地为氧，硫，硒，NH或NR 4，其中R 4为烷基或芳基并且可以连接到R 3 。 R3是烷基，长链烷基，烷氧基，长链烷氧基，环烷基，卤代烷基，芳基，亚芳基，卤素芳基，杂芳基，亚杂芳基，杂环亚烷基，杂环烷基，卤代杂芳基，烯基，卤素链烯基，炔基，卤代炔基，酮基芳基，卤代烷基芳基，酮杂芳基 ，酮基烷基，卤代酮烷基，酮链烯基，卤素酮链烯基，其中在适当的基团中，一个或多个不相邻的CH 2 - 基团可以彼此独立地被-O - ， - S-，-NH-，-NRO - ， - ，-CO-，-COO-，-OCO-，-OCO-O-，-SO 2 - ，-S-CO-，-CO-S-，-CY 1 = CY 2或-C≡C- O和/或S原子不直接相互连接的方式同样可以任选地被优选含有1至30个C原子的芳基或杂芳基取代，作为有机电子部件中的基质材料的掺杂剂。

    Metal complexes as P-type dopants for organic electronic matrix materials
    4.
    发明授权
    Metal complexes as P-type dopants for organic electronic matrix materials 有权

    公开(公告)号：US09929362B2

    公开(公告)日：2018-03-27

    申请号：US14406307

    申请日：2013-05-14

    Applicant: SIEMENS AKTIENGESELLSCHAFT ,  OSRAM OLED GmbH

    Inventor： Anna Maltenberger ,  Sébastien Pecqueur ,  Guenter Schmid ,  Jan Hauke Wemken

    IPC: H01L51/42 ,  H01L51/00 ,  H01L51/50

    CPC classification number: H01L51/009 ,  H01L51/42 ,  H01L51/506 ,  Y02E10/549

    Abstract: A bi- or polynuclear metal complex of a metal of groups Vb/VIb/VIIb (IUPAC groups 5-7), has a ligand of the structure (a), wherein R1 and R2, independently of each other, can be oxygen, sulfur, selenium, NH, or NR4, wherein R4 is selected from alkyls and aryls and can be bonded to R3; and R3 is selected from alkyls, long-chain alkyls, alkoxys, long-chain alkoxys, cycloalkyls, haloalkyls, aryls, arylenes, haloaryls, heteroaryls, heteroarylenes, heterocycloalkylenes, heterocycloalkyls, haloheteroaryls, alkenyls, haloalkenyls, alkynyls, haloalkynyls, ketoaryls, haloketoaryls, ketoheteroaryls, ketoalkyls, haloketoalkyls, ketoalkenyls, haloketoalkenyls, where one or more non-adjacent CH2 groups can be replaced, independently, with (1) —O—, —S—, —NH—, —NR∘—, —SiR∘R∘∘—, —CO—, —COO—, —OCO—, —OCO—O—, —SO2-, —S—CO—, —CO—S—, —CY1=CY2, or —C≡O— in such a way that O and/or S atoms are not bonded directly to each other, or (2) aryls or heteroaryls containing 1 to 30 C atoms, as a p-type doping agent for matrix materials of electronic components.

    METAL COMPLEXES AS P-TYPE DOPANTS FOR ORGANIC ELECTRONIC MATRIX MATERIALS
    5.
    发明申请
    METAL COMPLEXES AS P-TYPE DOPANTS FOR ORGANIC ELECTRONIC MATRIX MATERIALS 有权
    金属复合材料作为有机电子基质材料的P型掺杂剂

    公开(公告)号：US20150162534A1

    公开(公告)日：2015-06-11

    申请号：US14406307

    申请日：2013-05-14

    Applicant: SIEMENS AKTIENGESELLSCHAFT ,  OSRAM OLED GMBH

    Inventor： Anna Maltenberger ,  Sébastien Pecqueur ,  Guenter Schmid ,  Jan Hauke Wemken

    IPC: H01L51/00

    CPC classification number: H01L51/009 ,  H01L51/42 ,  H01L51/506 ,  Y02E10/549

    Abstract: A bi- or polynuclear metal complex of a metal of groups Vb/VIb/VIIb (IUPAC groups 5-7), has a ligand of the structure (a), wherein R1 and R2, independently of each other, can be oxygen, sulfur, selenium, NH, or NR4, wherein R4 is selected from alkyls and aryls and can be bonded to R3; and R3 is selected from alkyls, long-chain alkyls, alkoxys, long-chain alkoxys, cycloalkyls, haloalkyls, aryls, arylenes, haloaryls, heteroaryls, heteroarylenes, heterocycloalkylenes, heterocycloalkyls, haloheteroaryls, alkenyls, haloalkenyls, alkynyls, haloalkynyls, ketoaryls, haloketoaryls, ketoheteroaryls, ketoalkyls, haloketoalkyls, ketoalkenyls, haloketoalkenyls, where one or more non-adjacent CH2 groups can be replaced, independently, with (1) —O—, —S—, —NH—, —NR°—, —SiR°R°°—, —CO—, —COO—, —OCO—, —OCO—O—, —SO2-, —S—CO—, —CO—S—, —CY1=CY2, or —C≡O— in such a way that O and/or S atoms are not bonded directly to each other, or (2) aryls or heteroaryls containing 1 to 30 C atoms, as a p-type doping agent for matrix materials of electronic components.

    Abstract translation: Vb / VIb / VIIb族金属的双或多核金属络合物（IUPAC基团5-7）具有结构（a）的配体，其中R 1和R 2彼此独立地可以是氧，硫 ，硒，NH或NR4，其中R4选自烷基和芳基并且可以键合到R3; 并且R 3选自烷基，长链烷基，烷氧基，长链烷氧基，环烷基，卤代烷基，芳基，亚芳基，卤代芳基，杂芳基，杂芳基，杂环亚烷基，杂环烷基，卤代杂芳基，烯基，卤代烯基，炔基，卤代炔基，酮基芳基，卤代芳基 ，酮基芳基，酮基烷基，卤代烷基，酮链烯基，卤代烯基，其中一个或多个不相邻的CH 2基团可以独立地被（1）-O - ， - S - ， - NH - ， - NRO - ， - SiR R 0 - ， - CO-，-COO-，-OCO-，-OCO-O-，-SO2-，-S-CO-，-CO-S-，-CY1 = CY2或-C≡O- 使O和/或S原子彼此不直接键合，或（2）含有1至30个C原子的芳基或杂芳基作为电子元件基质材料的p型掺杂剂。

    Organic electronic component having a charge carrier generation layer and the use of a zinc complex as a P-type dopant in charge carrier generation layers
    6.
    发明授权
    Organic electronic component having a charge carrier generation layer and the use of a zinc complex as a P-type dopant in charge carrier generation layers 有权

    公开(公告)号：US10581001B2

    公开(公告)日：2020-03-03

    申请号：US15763068

    申请日：2016-09-27

    Applicant: OSRAM OLED GmbH

    Inventor： Dominik Pentlehner ,  Guenter Schmid ,  Anna Maltenberger ,  Sébastien Pecqueur ,  Florian Kessler ,  Stefan Regensburger

    IPC: H01L51/00 ,  C07F3/06 ,  H01L33/14 ,  H01L51/52 ,  H01L51/50

    Abstract: The invention relates to an organic electronic component (100) comprising at least one charge generation layer (5) which has an organically p-doped region (5a) that contains a zinc complex as a p-dopant, said zinc complex in turn containing at least one ligand L of the following structure: formula (I) wherein R1 and R2 can be oxygen, sulphur, selenium, NH or NR4 independently from one another, wherein R4 is selected from the group containing alkyl or aryl and which can be bonded to R3; and wherein R3 is selected from the group containing alkyl, long-chain alkyl, cycloalkyl, halogen alkyl, at least partially halogenated long-chain alkyl, halogen cycloalkyl, aryl, arylene, halogen aryl, heteroaryl, heteroarylene, heterocyclic alkylene, heterocycloalkyl, halogen heteroaryl, alkenyl, halogen alkenyl, alkynyl, halogen alkynyl, ketoaryl, halogen ketoaryl, ketoheteroaryl, ketoalkyl, halogen ketoalkyl, ketoalkenyl, halogen ketoalkenyl, halogen alkyl aryl, and halogen alkyl heteroaryl, wherein, for suitable groups, one or a number of non-adjacent CH2 groups can be replaced by —O—, —S—, —NH—, —NR∘∘∘—, —SiR∘R∘∘—, —CO—, —COO—, —COR∘OR∘∘—, —OCO—, —OCO—O—, —SO2-, —S—CO—, —CO—S—, —O—CS—, —CS—O—, —CY1=CY2 or —C≡C— independently from one another, and in such a way that O and/or S atoms are not directly bonded to one another, and are replaced optionally with aryl- or heteroaryl preferably containing between 1 and 30 C atoms (terminal CH3 groups are understood to be CH2 groups in the sense of CH2-H). The invention further relates to the use of a zinc complex as a p-dopant in charge generation layers.

    Main group metal complexes as p-dopants for organic electronic matrix materials
    7.
    发明授权
    Main group metal complexes as p-dopants for organic electronic matrix materials 有权

    公开(公告)号：US10305047B2

    公开(公告)日：2019-05-28

    申请号：US15383579

    申请日：2016-12-19

    Applicant: Siemens Aktiengesellschaft ,  OSRAM OLED GMBH

    Inventor： Anna Maltenberger ,  Marina A. Petrukhina ,  Guenter Schmid ,  Jan Hauke Wemken

    IPC: C08F4/20 ,  C08F36/16 ,  H01L51/00 ,  C07F9/94 ,  C09K11/06 ,  H01L51/50

    Abstract: A metal complex of a metal from groups 13 to 16 uses a ligand of the structure (I), where R.sup.1 and R.sup.2 can independently be oxygen, sulfur, selenium, NH or NR.sup.4, where R.sup.4 an alkyl or aryl and can be connected to R.sup.3. R.sup.3 is an alkyl, long-chain alkyl, alkoxy, long-chain alkoxy, cycloalkyl, halogenalkyl, aryl, arylene, halogenaryl, heteroaryl, heteroarylene, heterocycloalkylene, heterocycloalkyl, halogenheteroaryl, alkenyl, halogenalkenyl, alkynyl, halogenalkynyl, ketoaryl, halogenketoaryl, ketoheteroaryl, ketoalkyl, halogenketoalkyl, ketoalkenyl, halogenketoalkenyl, where in suitable radicals, one or more non-adjacent CH.sup.2-groups can be substituted independently of one another by —O—, —S—, —NH—, —NR.sup.o-, —SiR.sup.oR.sup.oo-, —CO—, —COO—, —OCO—, —OCO—O—, —SO.sub.2-, —S—CO—, —CO—S—, —CY1═CY2 or —C.dbd.C—, specifically in such a way that O and/or S atoms are not connected directly to one another, are likewise optionally substituted with aryl- or heteroaryl preferably containing 1 to 30 C atoms, as a dopant for matrix materials in organic electronic components.

    Organic electronic component, use of a zinc complex as a p-dopant for organic electronic matrix materials
    8.
    发明授权
    Organic electronic component, use of a zinc complex as a p-dopant for organic electronic matrix materials 有权

    公开(公告)号：US10256422B2

    公开(公告)日：2019-04-09

    申请号：US15515858

    申请日：2015-09-28

    Applicant: OSRAM OLED GmbH

    Inventor： Guenter Schmid ,  Anna Maltenberger ,  Sebastien Pecqueur ,  Florian Kessler ,  Stefan Regensburger

    IPC: H01L51/50 ,  H01L51/00

    Abstract: An organic electronic component and a method for making an organic electronic component with a p-dopant are disclosed. In an embodiment, the component includes a matrix containing a zinc complex as a p-dopant, the zinc complex containing at least one ligand L of the following structure: formula (I) wherein R1 and R2 can be oxygen, sulphur, selenium, NH or NR4 independently selected from one another, wherein R3 may comprise alkyl, long-chain alkyl, cycloalkyl, halogen-alkyl, aryl, arylene, halogen-aryl, heteroaryl, heteroarylene, heterocyclic-alkylene, heterocycloalkyl, halogen-heteroaryl, alkenyl, halogen-alkenyl, alkynyl, halogen-alkynyl, ketoaryl, halogen-ketoaryl, ketoheteroaryl, ketoalkyl, halogen-ketoalkyl, ketoalkenyl, halogen-ketoalkenyl, halogen-alkyl-aryl or halogen-alkyl-heteroaryl, and wherein R4 is selected from the group consisting of alkyl and aryl which can be bonded to R3.

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