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公开(公告)号:CA2094063C
公开(公告)日:2004-09-28
申请号:CA2094063
申请日:1993-04-15
Applicant: PCR GROUP INC
Inventor: GIERKE MARK A , VIDAL CHRISTINE L , WILSON MICHAEL E
IPC: B01J13/00 , C04B41/49 , C04B41/64 , C08J3/03 , C08K5/54 , C08K5/5419 , C08L83/04 , C09D183/04 , C09K3/18 , C08J3/02
Abstract: There are provided aqueous emulsions useful for rendering porous substrates water repellent comprising a) a hydrolyzable silane and/or siloxane, b) an organopolysiloxane resin consisting of R3SiO0.5 siloxane units and SiO2 siloxane units, or R3SiO0.5 units, R2SiO units, and SiO2 siloxane units, c) a filler having a surface area of at least 40 m2/g, d) an emulsifying agent, and e) water. Such compositions are especially useful on masonry exposed to wind-driven rain.
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公开(公告)号:CA1330691C
公开(公告)日:1994-07-19
申请号:CA589166
申请日:1989-01-25
Applicant: PCR
Inventor: WILSON MICHAEL E
Abstract: There are provided aqueous emulsions useful for rendering porous substrates water repellent comprising (a) a hydrolyzable silane having a determinable pH-stable range, (b) an emulsifying agent having an HLB value of from 2 to 20, an effective amount of (c) a buffering compound to maintain the composition within the pH-stable range; and (d) water. Such buffered compositions are stable on long term storage and maintain high effective levels of active silane content even when they include biocides which may accelerate the hydrolysis of aqueous silane-containing compositions.
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公开(公告)号:DE3688837T2
公开(公告)日:1993-11-25
申请号:DE3688837
申请日:1986-12-11
Applicant: PCR GROUP INC
Inventor: DEPASQUALE RALPH J , WILSON MICHAEL E
Abstract: There is provided an aqueous emulsion of (a) a hydrolyzable silane having the general formula: Rn-Si-(R')4-n wherein R is a hydrocarbyl group containing from 1 to 20 carbon atoms, R' is a hydrolyzable group and n is 1 or 2, and oligomers thereof, e.g., dimers and trimers, and other oligomers, (b) an emulsifying agent having an HLB value of from 4 to 15, and (c) water.
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公开(公告)号:DE3688837D1
公开(公告)日:1993-09-09
申请号:DE3688837
申请日:1986-12-11
Applicant: PCR GROUP INC
Inventor: DEPASQUALE RALPH J , WILSON MICHAEL E
Abstract: There is provided an aqueous emulsion of (a) a hydrolyzable silane having the general formula: Rn-Si-(R')4-n wherein R is a hydrocarbyl group containing from 1 to 20 carbon atoms, R' is a hydrolyzable group and n is 1 or 2, and oligomers thereof, e.g., dimers and trimers, and other oligomers, (b) an emulsifying agent having an HLB value of from 4 to 15, and (c) water.
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公开(公告)号:AT78499T
公开(公告)日:1992-08-15
申请号:AT86903848
申请日:1986-05-16
Applicant: PCR GROUP INC
Inventor: DEPASQUALE RALPH J , WILSON MICHAEL E
IPC: C08G12/40 , C08G65/32 , C08G65/337 , C08G69/48 , C08G73/04 , C08G77/26 , C08G77/388 , C08G85/00
Abstract: There is provided a novel product having the formula: where "polymer" is an amine functional polymer, such as amine terminated polyethylene imine, amine terminated polyalkylene glycols, amine terminated anilineformaldehyde, amine terminated nylons, amine functional silicones; R1, R2, and R3 are C1-C8 monovalent hydrocarbyl radicals, m is 1 to 3 and n is 1 to 10.
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公开(公告)号:CA1277891C
公开(公告)日:1990-12-18
申请号:CA525997
申请日:1986-12-22
Applicant: PCR
Inventor: DE PASQUALE RALPH J , WILSON MICHAEL E
IPC: C04B41/62 , C04B41/49 , C04B41/82 , C04B41/84 , C08L83/06 , C09D201/00 , C09K3/18 , C09K3/00 , C09D4/00
Abstract: There is provided an aqueous emulsion of (a) a hydrolyzable silane having the general formula: Rn - Si - (R')4-n wherein R is a hydrocarbyl group containing from 1 to 20 carbon atoms, R' is a hydrolyzable group and n is 1 or 2, and oligomers thereof, e.g., dimers and trimers, and other oligomers, (b) an emulsifying agent having an HLB value of from 4 to 15, and (c) water. The emulsion is useful for rendering porous ceramic materials water repellant.
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公开(公告)号:DE3600714C2
公开(公告)日:1994-03-31
申请号:DE3600714
申请日:1986-01-13
Applicant: PCR INC N D GES D STAATES DELA
Inventor: DEPASQUALE RALPH J , WILSON MICHAEL E
Abstract: Polyhydroxyl silanes or siloxanes useful as vehicles for coatings applicable to metal, mineral or glass surfaces, are made by reacting a silane or siloxane having an amine terminated substituent attached to silicon with an aldonic acid lactone. Reaction occurs at temperatures below 80 DEG C. in alcohol solution under inert gas blanket. Products are water soluble and polymerizable at slightly elevated temperatures to hard, water insoluble tightly adhering films.
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公开(公告)号:AU6865787A
公开(公告)日:1987-08-20
申请号:AU6865787
申请日:1987-02-10
Applicant: PCR
Inventor: DEPASQUALE RALPH , WILSON MICHAEL E
Abstract: There is provided an aqueous emulsion of (a) a hydrolyzable silane having the general formula: Rn-Si-(R')4-n wherein R is a hydrocarbyl group containing from 1 to 20 carbon atoms, R' is a hydrolyzable group and n is 1 or 2, and oligomers thereof, e.g., dimers and trimers, and other oligomers, (b) an emulsifying agent having an HLB value of from 4 to 15, and (c) water.
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公开(公告)号:AU594426B2
公开(公告)日:1990-03-08
申请号:AU6865787
申请日:1987-02-10
Applicant: PCR
Inventor: DEPASQUALE RALPH , WILSON MICHAEL E
Abstract: There is provided an aqueous emulsion of (a) a hydrolyzable silane having the general formula: Rn-Si-(R')4-n wherein R is a hydrocarbyl group containing from 1 to 20 carbon atoms, R' is a hydrolyzable group and n is 1 or 2, and oligomers thereof, e.g., dimers and trimers, and other oligomers, (b) an emulsifying agent having an HLB value of from 4 to 15, and (c) water.
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公开(公告)号:DE3688837T3
公开(公告)日:1999-08-12
申请号:DE3688837
申请日:1986-12-11
Applicant: PCR GROUP INC
Inventor: DEPASQUALE RALPH J , WILSON MICHAEL E
Abstract: There is provided an aqueous emulsion of (a) a hydrolyzable silane having the general formula: Rn-Si-(R')4-n wherein R is a hydrocarbyl group containing from 1 to 20 carbon atoms, R' is a hydrolyzable group and n is 1 or 2, and oligomers thereof, e.g., dimers and trimers, and other oligomers, (b) an emulsifying agent having an HLB value of from 4 to 15, and (c) water.
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