公开(公告)号：EP0627440B1

公开(公告)日：1999-08-18

申请号：EP94108449.3

申请日：1994-06-01

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Patsidis, Konstantinos ,  Alt, Helmut G. ,  Welch, Bruce M. ,  Schmid, Michael ,  Janzen, Jay

IPC: C07F17/00 ,  C08F10/00 ,  C07C13/567 ,  C08F4/60

CPC classification number: C07F17/00 ,  C07C13/567 ,  C07C2601/14 ,  C07C2603/18 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00

公开(公告)号：EP0685495B1

公开(公告)日：1998-04-08

申请号：EP95108349.2

申请日：1995-05-31

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Welch, M. Bruce ,  Alt, Helmut G. ,  Peifer, Bernd ,  Palackal, Syriac J. ,  Glass, Gary L. ,  Pettijohn, Ted M. ,  Hawley, Gil R. ,  Fahey, Darryl R.

IPC: C08F10/00

CPC classification number: C08J5/18 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08J2323/04 ,  C08F4/6492 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/14 ,  C08F2500/10 ,  C08F210/14 ,  C08F210/08

公开(公告)号：EP0628577A3

公开(公告)日：1995-10-25

申请号：EP94107774.5

申请日：1994-05-19

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Palackal, Syriac J. ,  Alt, Helmut G. ,  Patsidis, Konstantinos ,  Hill, Tara G. ,  Hawley, Gil R. ,  Chu, Peter P. ,  Welch, M. Bruce ,  Geerts, Rolf L.

IPC: C08F110/06 ,  C07F17/00 ,  C08F4/642

CPC classification number: C08F110/06 ,  B01J31/143 ,  B01J31/1608 ,  B01J31/2295 ,  B01J2531/40 ,  B01J2531/48 ,  C07C13/567 ,  C07C22/04 ,  C07C49/747 ,  C07C51/31 ,  C07C51/373 ,  C07C51/377 ,  C07C63/331 ,  C07C63/49 ,  C07C65/36 ,  C07C2601/10 ,  C07C2603/18 ,  C07F7/006 ,  C07F7/0809 ,  C07F7/0818 ,  C07F7/2212 ,  C07F17/00 ,  C08F4/63912 ,  C08F4/63922 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  Y02P20/52 ,  C08F2500/08 ,  C08F2500/15 ,  C08F2500/16 ,  C07C65/38 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/01 ,  C08F210/14

Abstract: Fluorenyl-containing silyl bridged metallocenes, the process of using such metallocenes to polymerize olefins, and the resulting unusual syndiotactic polypropylene are disclosed.

Abstract translation: 公开了含芴基的甲硅烷基桥连金属茂，使用这种茂金属聚合烯烃的方法，以及所得到的异常间同立构聚丙烯。

公开(公告)号：EP0627440A1

公开(公告)日：1994-12-07

申请号：EP94108449.3

申请日：1994-06-01

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Patsidis, Konstantinos ,  Alt, Helmut G. ,  Welch, Bruce M. ,  Schmid, Michael ,  Janzen, Jay

IPC: C07F17/00 ,  C08F10/00 ,  C07C13/567 ,  C08F4/60

CPC classification number: C07F17/00 ,  C07C13/567 ,  C07C2601/14 ,  C07C2603/18 ,  C08F4/65912 ,  C08F4/65925 ,  C08F10/00

Abstract: 9-substituted fluorenyl-containing metallocenes and their use in the polymerization of olefins is disclosed. In addition, novel 9-cyclohexylfluorenyl or 9-phenylfluorenyl compounds are disclosed. Also methods for preparing such 9-substituted fluorenyl compounds are presented.

Abstract translation: 9- substituiertem含芴基的金属茂及其烯烃的聚合在使用中游离缺失盘。 此外，新颖的9- cyclohexylfluorenyl或9-苯基芴基化合物是游离缺失盘。 因此，对于准备寻求9 substituiertem芴基化合物的方法介绍。

公开(公告)号：EP1304319A2

公开(公告)日：2003-04-23

申请号：EP03001223.1

申请日：1994-06-10

Applicant: Phillips Petroleum Company

Inventor： Alt, Helmut G. ,  Patsidis, Konstantinos ,  Welch, Bruce M. ,  Geerts, Rolf L. ,  Pfeiffer, Bernd ,  Palackal, Syriac J. ,  Fahey, Darryl R. ,  Deck, Harold R.

IPC: C07C51/31 ,  C07F7/08 ,  C07F7/30 ,  C07F7/22 ,  C08F10/00 ,  C07F17/00 ,  C07C51/377 ,  C07F7/12 ,  B01J31/22

CPC classification number: C07F17/00 ,  B01J21/08 ,  B01J31/143 ,  B01J31/1616 ,  B01J31/1633 ,  B01J31/2295 ,  B01J2231/12 ,  B01J2231/52 ,  B01J2231/643 ,  B01J2231/72 ,  B01J2531/35 ,  B01J2531/36 ,  B01J2531/37 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/56 ,  C07B2200/11 ,  C07C13/567 ,  C07C22/04 ,  C07C49/747 ,  C07C51/31 ,  C07C51/373 ,  C07C51/377 ,  C07C63/331 ,  C07C63/49 ,  C07C65/36 ,  C07C2601/10 ,  C07C2603/18 ,  C07F7/0809 ,  C07F7/0818 ,  C07F7/0827 ,  C07F7/12 ,  C07F7/2212 ,  C07F7/2216 ,  C07F7/30 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/61927 ,  C08F4/63912 ,  C08F4/63922 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  Y10S526/943 ,  C07C65/38 ,  C08F2500/20 ,  C08F2500/01 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/08 ,  C08F210/14

Abstract: A method is provided for forming a supported cyclopentadiene-type compound comprising contacting a cyclopentadiene-type compound containing an active halogen with an inorganic support having surface hydroxyl group. Also there is provided a method of preparing a supported metallocene comprising reacting the supported cyclopentadiene-type compound with a transition metal compound under suitable conditions. There is also provided a process for producing bridged cyclopentadiene-type ligands having a bridge having branch that has a terminal vinyl group. Also metallocenes of these ligands are provided. Still further there is provided a process for producing bridged cyclopentadiene-type ligands having a bridge having a branch that has a terminal active halogen. The resulting new ligands and supported metallocenes produced therefrom are also provided. There is further provided supported metallocene catalysts wherein at least two metallocenes of differing effectiveness are both bonded to an inorganic support having surface hydroxy groups. Olefin polymerization employing the inventive bridged supported metallocenes is also provided, as well the resulting polymer products.

公开(公告)号：EP1123938A3

公开(公告)日：2001-12-05

申请号：EP01111297.6

申请日：1995-02-01

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Zenk, Roland ,  Alt, Helmut G. ,  Welch, M. Bruce

IPC: C07F17/00 ,  C08F10/00 ,  C08F4/64

CPC classification number: C07F17/00 ,  B01J31/143 ,  B01J31/2295 ,  B01J2531/40 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/50 ,  B01J2531/60 ,  C07C13/567 ,  C07C22/04 ,  C07C49/747 ,  C07C51/31 ,  C07C51/373 ,  C07C51/377 ,  C07C63/331 ,  C07C63/49 ,  C07C65/36 ,  C07C2601/10 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2603/18 ,  C07F7/006 ,  C07F7/0809 ,  C07F7/0818 ,  C08F4/63912 ,  C08F4/63922 ,  C08F4/65912 ,  C08F4/65922 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C07C65/38 ,  C08F2500/04 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/20 ,  C08F2500/01 ,  C08F2500/16 ,  C08F2500/08 ,  C08F2500/15 ,  C08F210/14

Abstract: Benzofluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.

Abstract translation: 公开含苯并芴基的茂金属与制备茂金属的方法一起公开。 还公开了使用茂金属作为聚合催化剂的方法。 另外，公开了由这种聚合产生的聚合物。

公开(公告)号：EP0745607A3

公开(公告)日：2001-03-28

申请号：EP96108514.9

申请日：1996-05-29

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Peifer, Bernd ,  Alt, Helmut G. ,  Welch, Bruce M.

IPC: C07F17/00 ,  C08F10/00 ,  C08F4/602

CPC classification number: C07F17/00 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/61922 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  Y10S526/943 ,  C08F2500/12 ,  C08F2500/07

Abstract: Double bound metallocenes, i.e. metallocenes having a cyclopentadienyl-containing radical that is bound to a transition metal both by a pi bond and by a sigma carbon bond of a substituent of that same cyclopentadienyl-containing radical can be prepared by reducing metallocenes having a cyclopentadienyl-containing radical having at least one an unsaturated substituent. Also a process for producing polymers comprising contacting at least one olefinic monomer under suitable polymerization conditions with such double bound metallocenes.

公开(公告)号：EP0810234A2

公开(公告)日：1997-12-03

申请号：EP97112513.3

申请日：1995-05-31

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Welch, M. Bruce ,  Alt, Helmut G. ,  Pfeifer, Bernd ,  Palackal, Syriac J. ,  Glass, Gary L. ,  Pettijohn, Ted M. ,  Hawley, Gil R. ,  Fahey, Darryl R.

IPC: C08F4/642 ,  C08F4/651

CPC classification number: C08J5/18 ,  C07F17/00 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F4/65927 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08J2323/04 ,  C08F4/6492 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/14 ,  C08F2500/10 ,  C08F210/14 ,  C08F210/08

Abstract: A method for preparing a solid catalyst system comprising at least one metallocene, which at least one metallocene is 5-(9-fluorenyl)-5-(cyclopentadienyl)-hexene-1 zirconium dichloride, the method comprising

(a) combining an organoaluminoxane and said at least one metallocene in a liquid to form a liquid catalyst system,
(b) conducting prepolymerization of at least one olefin in the presence of said liquid catalyst system to produce a prepolymerized solid catalyst, and
(c) separating the resulting solid from the liquid and components dissolved in said liquid.

Abstract translation: 一种制备包含至少一种茂金属的固体催化剂体系的方法，其至少一种茂金属是5-（9-芴基）-5-（环戊二烯基） - 己烯-1锆二氯化锆，所述方法包括（a）将有机铝氧烷和 所述至少一种茂金属在液体中以形成液体催化剂体系，（b）在所述液体催化剂体系的存在下进行至少一种烯烃的预聚合以产生预聚合的固体催化剂，和（c）将所得固体与 液体和溶解在所述液体中的组分。

公开(公告)号：EP0672675A1

公开(公告)日：1995-09-20

申请号：EP95101359.8

申请日：1995-02-01

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Zenk, Roland ,  Alt, Helmut G. ,  Welch, M. Bruce

IPC: C07F17/00 ,  C08F10/00 ,  C08F4/642

CPC classification number: C07F17/00 ,  B01J31/143 ,  B01J31/2295 ,  B01J2531/40 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/50 ,  B01J2531/60 ,  C07C13/567 ,  C07C22/04 ,  C07C49/747 ,  C07C51/31 ,  C07C51/373 ,  C07C51/377 ,  C07C63/331 ,  C07C63/49 ,  C07C65/36 ,  C07C2601/10 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2603/18 ,  C07F7/006 ,  C07F7/0809 ,  C07F7/0818 ,  C08F4/63912 ,  C08F4/63922 ,  C08F4/65912 ,  C08F4/65922 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C07C65/38 ,  C08F2500/04 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/20 ,  C08F2500/01 ,  C08F2500/16 ,  C08F2500/08 ,  C08F2500/15 ,  C08F210/14

Abstract: Benzofluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.

Abstract translation: 公开含有苯并芴基的金属茂以及制备金属茂的方法。 还公开了使用金属茂作为聚合催化剂的方法。 此外，公开了由这种聚合产生的聚合物。

公开(公告)号：EP0666267A3

公开(公告)日：1995-08-30

申请号：EP94119735.2

申请日：1994-12-14

Applicant: PHILLIPS PETROLEUM COMPANY

Inventor： Alt, Helmut G. ,  Palackal, Syriac J. ,  Zenk, Roland, Lab. für Anorganische Chemie ,  Welch, M. Bruce ,  Schmid, Michael, Lab. für Anorganische Chemie

IPC: C07F17/00 ,  C08F10/00 ,  C08F4/642 ,  C07C13/567

CPC classification number: C08F210/16 ,  B01J31/143 ,  B01J31/2295 ,  B01J2531/40 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/50 ,  B01J2531/60 ,  C07C13/567 ,  C07C22/04 ,  C07C49/747 ,  C07C51/31 ,  C07C51/373 ,  C07C51/377 ,  C07C63/331 ,  C07C63/49 ,  C07C65/36 ,  C07C2601/10 ,  C07C2601/14 ,  C07C2601/16 ,  C07C2603/18 ,  C07F7/006 ,  C07F7/0809 ,  C07F7/0818 ,  C07F17/00 ,  C08F4/63912 ,  C08F4/63922 ,  C08F4/65912 ,  C08F4/65922 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  Y10S526/943 ,  C08F2500/20 ,  C08F2500/01 ,  C08F2500/04 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/16 ,  C07C65/38 ,  C08F2500/08 ,  C08F2500/15 ,  C08F210/14

Abstract: Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.

Abstract translation: 公开含芴基的茂金属以及制备茂金属的方法。 还公开了使用茂金属作为聚合催化剂的方法。 另外，公开了由这种聚合产生的聚合物。