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    Metallocene preparation and use
    8.
    发明公开
    Metallocene preparation and use 失效
    Metallocenverbindungen，deren Herstellung und Verwendung

    公开(公告)号：EP0745607A2

    公开(公告)日：1996-12-04

    申请号：EP96108514.9

    申请日：1996-05-29

    Applicant: PHILLIPS PETROLEUM COMPANY

    Inventor： Peifer, Bernd ,  Alt, Helmut G. ,  Welch, Bruce M.

    IPC: C07F17/00 ,  C08F10/00 ,  C08F4/602

    CPC classification number: C07F17/00 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/61922 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  Y10S526/943 ,  C08F2500/12 ,  C08F2500/07

    Abstract: Double bound metallocenes, i.e. metallocenes having a cyclopentadienyl-containing radical that is bound to a transition metal both by a pi bond and by a sigma carbon bond of a substituent of that same cyclopentadienyl-containing radical can be prepared by reducing metallocenes having a cyclopentadienyl-containing radical having at least one an unsaturated substituent. Also a process for producing polymers comprising contacting at least one olefinic monomer under suitable polymerization conditions with such double bound metallocenes.

    Abstract translation: 双键金属茂，即具有含有环戊二烯基的自由基的金属茂可以通过还原具有环戊二烯基的基团的金属茂来制备，所述基团通过π键和通过相同含环戊二烯基的自由基的取代基的σ碳键与过渡金属结合， 含有至少一个不饱和取代基的基团。 还有一种生产聚合物的方法，包括使合适的聚合条件下的至少一种烯属单体与这种双键结合的金属茂接触。

    Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use
    9.
    发明公开
    Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use 失效
    Polymergebundene Liganten，聚合物茂金属茂金属，Katalysatorsysteme，und deren Herstellung und Verwendung

    公开(公告)号：EP0690076A1

    公开(公告)日：1996-01-03

    申请号：EP95110160.9

    申请日：1995-06-29

    Applicant: PHILLIPS PETROLEUM COMPANY

    Inventor： Peifer, Bernd ,  Alt, Helmut G. ,  Welch, Bruce M. ,  Palackal, Syriac J.

    IPC: C08F10/00 ,  C08F8/42 ,  C08F4/642

    CPC classification number: C08F8/42 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/61922 ,  C08F10/00 ,  C08F12/00

    Abstract: A polymer bound ligand represented by the formula QM(R) m and process for preparing same are provided, wherein Q is a polystyrene, M is Si, C, Ge, Sn, P, or N, each R is a that at least one R is a cyclopentadienyl-type compound, and m is 2 or 3, said process comprising reacting a metallated polystyrene and an organohalide compound, wherein the polystyrene is metallated with an alkali metal, and wherein said organohalide compound is represented by the formula XM(R) m wherein X is a halide. Other aspects of the present invention include a polymer bound metallocene represented by the formula QM(R) m ZY n and a process for preparing same, wherein Z is a transition metal, Y is a halide, methyl, hydrogen, or a cyclopentadienyl-type group, and n is 2 or 3. Other aspects of the present invention include a catalyst system comprising the polymer bound metallocene and an organoaluminoxane, a method for preparing same, and a polymerization process employing the catalyst system.

    Abstract translation: 制备方法。 的用作茂金属催化剂组分的聚合物结合的配体。 该方法包括使金属化聚苯乙烯与有机卤化物cpd反应。聚苯乙烯用碱金属进行金属化。 有机卤化物cpd 具有下式：XM（R）m X =卤化物; M = Si，C，Ge，Sn，P或N; 并且每个R =烃基gp。 选自（环）烷基，芳基和环戊二烯基型gps。 contg。 1-36个C原子，条件是：至少一个R gp。 =环戊二烯基型gp，其中环戊二烯基型gps。 是环戊二烯基选择。 子代 茚基，芴基选择。 subd。，其中的位置。 包括1-12C烃基gps，1-12C烷氧基gps或卤化物，m是2或3.还要求保护的是如上形成的聚合物结合的配体。

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