公开(公告)号：CA2062478A1

公开(公告)日：1992-09-12

申请号：CA2062478

申请日：1992-03-06

Applicant: BELL ERIC L ,  REED KENNETH J ,  OLM MYRA T

Inventor： BELL ERIC L ,  REED KENNETH J ,  OLM MYRA T

IPC: G03C1/015 ,  G03C1/005 ,  G03C1/035 ,  G03C1/08 ,  G03C1/09 ,  G03C5/50 ,  G03C1/46

Abstract: IMPROVED TABULAR GRAIN EMULSIONS CONTAINING LAMINAR HALIDE STRATA Photographic emulsions are disclosed comprised of radiation sensitive silver iodobromide grains, at least 50 percent of the total projected area of said silver iodobromide grains being accounted for by tabular grains exhibiting a mean tabularity of greater than 5, at least 10 percent of which are comprised of two opposed parallel major crystal faces, a host stratum having an iodide content of at least 4 mole percent, and laminar strata containing less than 2 mole percent iodide interposed between said host stratum and said opposed major crystal faces. The emulsions are characterized in that each of the laminar strata is comprised of a surface layer forming one of the major surfaces and having a thickness in the range of from 20 to 350 .ANG. and a subsurface layer located immediately beneath and in contact with the surface layer containing a hexacoordination complex of a Group VIII period 4 or 5 metal and at least three cyanide ligands.

公开(公告)号：CA1090053A

公开(公告)日：1980-11-25

申请号：CA283085

申请日：1977-07-19

Applicant: REED KENNETH J

Inventor： LYTHGOE ALAN L ,  REED KENNETH J

IPC: D06P5/00 ,  B41M5/035 ,  D06P5/24 ,  D06P7/00 ,  D06Q1/00

Abstract: A heat transfer is disclosed which is primarily intended for application of designs to textiles. The transfer comprises a flexible carrier sheet bearing a transfer layer of a polymer composition which is rendered non-blocking at normal room temperatures by a pariculate solid dispersed therein. The particulate solid is selected so that at the melting temperature of the layer it is either removed completely by sublimation or is converted to a form which does not interfere with liquid phase transfer of the design to the textile.

公开(公告)号：WO2011112244A3

公开(公告)日：2011-11-10

申请号：PCT/US2011000429

申请日：2011-03-08

Applicant: CERION TECHNOLOGY INC ,  REED KENNETH J ,  DIFRANCISCO ALBERT GARY ,  HAILSTONE RICHARD K ,  PROK GARY R ,  ALLSTON THOMAS D

Inventor： REED KENNETH J ,  DIFRANCISCO ALBERT GARY ,  HAILSTONE RICHARD K ,  PROK GARY R ,  ALLSTON THOMAS D

IPC: B01J23/00 ,  B01J23/10

CPC classification number: B01J23/10 ,  B01J23/002 ,  B01J23/83 ,  B01J37/0221 ,  B01J37/031 ,  B01J37/035 ,  B82Y30/00 ,  B82Y40/00 ,  C01F17/0018 ,  C01F17/0043 ,  C01G49/00 ,  C01G49/009 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/45 ,  C01P2004/64 ,  C01P2004/84 ,  C10L1/1233 ,  C10L10/02 ,  C10M125/10 ,  C10M2201/062 ,  C10N2220/082 ,  C10N2250/12 ,  Y10S977/775 ,  Y10S977/811 ,  Y10S977/89 ,  Y10S977/902

Abstract: A method for forming a structured doped cerium oxide nanoparticle including the steps of forming a first aqueous cerium(lll) reaction mixture, with optional metal/s other than cerium, a base, and a stabilizer; introducing an oxidant to singly oxidize cerium (III), followed by thermal formation of a doped cerium oxide nanoparticle core; then providing a second reaction mixture of one or more metal ions other than cerium, and optionally cerium (III) ions and sufficient cerium (III) oxidant, followed by thermally converting the mixture into a shell around the doped cerium oxide nanoparticle core, wherein the ratio of metal ions in the core differs from the ratio of metal ions in the shell. The disclosed structured doped cerium oxide nanoparticle may exhibit cubic fluorite crystal structure and possess a diameter in the range 1 nm-20 nm. A dispersion of the developed nanoparticle may be used as a fuel additive.

Abstract translation: 一种用于形成结构掺杂的氧化铈纳米颗粒的方法，包括以下步骤：用除铈以外的任选金属，碱和稳定剂形成第一含水铈（III）反应混合物; 引入氧化剂以单独氧化铈（III），然后热成型掺杂的氧化铈纳米颗粒核心; 然后提供除铈以外的一种或多种金属离子和任选的铈（III）离子和足够的铈（III）氧化剂的第二反应混合物，随后将混合物热转化成掺杂的氧化铈纳米颗粒核周围的壳，其中 核中金属离子的比例与壳中金属离子的比例不同。 所公开的结构掺杂的氧化铈纳米颗粒可呈现立方萤石晶体结构，其直径范围为1nm-20nm。 所开发的纳米颗粒的分散体可以用作燃料添加剂。

公开(公告)号：WO2008030815A3

公开(公告)日：2009-01-08

申请号：PCT/US2007077545

申请日：2007-09-04

Applicant: CERION TECHNOLOGIES INC ,  DIFRANCESCO ALBERT GARY ,  HAILSTONE RICHARD K ,  LANGNER ANDREAS ,  REED KENNETH J

Inventor： DIFRANCESCO ALBERT GARY ,  HAILSTONE RICHARD K ,  LANGNER ANDREAS ,  REED KENNETH J

IPC: C01F17/00

CPC classification number: B01J23/10 ,  B01F3/0807 ,  B01F7/164 ,  B01J13/0047 ,  B01J13/0086 ,  B82Y30/00 ,  C10L1/10 ,  C10L1/103 ,  C10L1/1233 ,  C10L1/125 ,  C10L1/1258 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1811 ,  C10L1/1824 ,  C10L1/1881 ,  C10L1/1883 ,  C10L1/19 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/2437 ,  C10L10/02 ,  C10L10/08 ,  C10L10/12 ,  C10M2201/062 ,  C10N2230/06 ,  C10N2240/10 ,  Y02T50/678 ,  C10N2210/03 ,  C10N2220/082

Abstract: A method of making cerium dioxide nanoparticles includes: a) providing an aqueous reaction mixture having a source of cerous ion, a source of hydroxide ion, a nanoparticle stabilizer, and an oxidant at an initial temperature no higher than about 2O°C; b) mechanically shearing the mixture and causing it to pass through a perforated screen, thereby forming a suspension of cerium hydroxide nanoparticles; and c) raising the initial temperature to achieve oxidation of cerous ion to eerie ion and thereby form cerium dioxide nanoparticles having a mean diameter in the range of about 1 nm to about 15 nm. The cerium dioxide nanoparticles may be formed in a continuous process.

Abstract translation: 一种制备二氧化铈纳米颗粒的方法包括：a）提供在不高于约20℃的初始温度下具有铈离子源，氢氧根离子源，纳米颗粒稳定剂和氧化剂的含水反应混合物; b）机械剪切该混合物并使其通过多孔筛，由此形成氢氧化铈纳米颗粒的悬浮液; 和c）升高初始温度以实现铈离子氧化成阴离子并由此形成平均直径在约1nm至约15nm范围内的二氧化铈纳米颗粒。 二氧化铈纳米颗粒可以以连续工艺形成。

公开(公告)号：WO2008127395A2

公开(公告)日：2008-10-23

申请号：PCT/US2007083194

申请日：2007-10-31

Applicant: CERION TECHNOLOGIES INC ,  REED KENNETH J

Inventor： REED KENNETH J

IPC: H01L21/20

CPC classification number: C10M125/10 ,  C10M2201/062 ,  C10M2207/021 ,  C10M2207/122 ,  C10M2207/124 ,  C10M2215/04 ,  C10N2220/082 ,  C10N2230/06 ,  C10N2240/02 ,  C10N2240/10

Abstract: A lubricity additive composition includes a lubricating medium and, dispersed therein, cerium dioxide nanoparticles having a mean diameter of about 1 nm to about 15 nm. In a method for reducing friction between, or scarring, abrasion, or pitting of metal surfaces in relative motion with one another, at least one of the metal surfaces has been contacted with a lubricity additive composition that includes a lubricating medium and, dispersed therein, cerium dioxide nanoparticles whose mean diameter is about 1 nm to about 15 nm.

Abstract translation: 润滑添加剂组合物包括润滑介质，并分散在其中，具有约1nm至约15nm的平均直径的二氧化铈纳米颗粒。 在减少相对运动的金属表面之间的摩擦或疤痕，磨损或点蚀的方法中，金属表面中的至少一个已经与包括润滑介质并分散在其中的润滑添加剂组合物接触， 平均直径为约1nm至约15nm的二氧化铈纳米颗粒。

公开(公告)号：WO2011142834A8

公开(公告)日：2012-07-12

申请号：PCT/US2011000858

申请日：2011-05-13

Applicant: CERION TECHNOLOGY INC ,  REED KENNETH J ,  DIFRANCISCO ALBERT GARY ,  PROK GARY R ,  HAILSTONE RICHARD K

Inventor： REED KENNETH J ,  DIFRANCISCO ALBERT GARY ,  PROK GARY R ,  HAILSTONE RICHARD K

IPC: C01F17/00 ,  C01G25/00 ,  C01G49/00 ,  C10L1/12 ,  C10L10/00

CPC classification number: C10L1/1233 ,  B01J13/0034 ,  B01J13/0047 ,  B82Y30/00 ,  C01F17/00 ,  C01F17/0043 ,  C01G25/00 ,  C01G25/02 ,  C01G49/0054 ,  C01G49/009 ,  C01G49/02 ,  C01G55/00 ,  C01P2002/30 ,  C01P2002/52 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2004/51 ,  C01P2004/52 ,  C01P2004/64 ,  C01P2006/90 ,  C10G25/02 ,  C10L1/10 ,  C10L1/1881 ,  C10L10/02 ,  C10L10/06 ,  C10L2200/0222 ,  C10L2200/024 ,  C10L2200/0245 ,  C10L2200/0254 ,  C10L2230/22 ,  C10L2250/06 ,  C10L2270/026 ,  Y10T428/2982

Abstract: A process for making cerium-containing oxide nanoparticles includes providing an aqueous reaction mixture containing a source of cerous ion, optionally a source of one or more metal ions (M) other than cerium, a source of hydroxide ion, at least one monoether carboxylic acid nanoparticle stabilizer wherein the molar ratio of said monoether carboxylic acid nanoparticle stabilizers to total metal ions is greater than 0.2, and an oxidant at an initial temperature in the range of about 20°C to about 95°C. Temperature conditions are provided effective to enable oxidation of cerous ion to ceric ion, thereby forming a product dispersion of cerium-containing oxide nanoparticles, optionally containing one or more metal ions (M), Ce1-xMxO2-d, wherein "x" has a value from about 0.0 to about 0.95. The nanoparticles may have a mean hydrodynamic diameter from about 1 nm to about 50 nm, and a geometric diameter of less than about 45 nm.

Abstract translation: 制备含铈氧化物纳米颗粒的方法包括提供含有铈离子源的水性反应混合物，任选地除了铈以外的一种或多种金属离子（M）的源，氢氧根离子源，至少一种单醚羧酸 纳米粒子稳定剂，其中所述单醚羧酸纳米粒子稳定剂与总金属离子的摩尔比大于0.2，氧化剂在约20℃至约95℃范围内的初始温度。 提供温度条件有效地使铈离子氧化成铈离子，从而形成含铈氧化物纳米颗粒的产品分散体，任选地含有一种或多种金属离子（M），Ce1-xMxO2-d，其中“x”具有 值为约0.0至约0.95。 纳米颗粒可以具有约1nm至约50nm的平均流体动力学直径和小于约45nm的几何直径。

公开(公告)号：WO2008030815A4

公开(公告)日：2009-03-05

申请号：PCT/US2007077545

申请日：2007-09-04

Applicant: CERION TECHNOLOGIES INC ,  DIFRANCESCO ALBERT GARY ,  HAILSTONE RICHARD K ,  LANGNER ANDREAS ,  REED KENNETH J

Inventor： DIFRANCESCO ALBERT GARY ,  HAILSTONE RICHARD K ,  LANGNER ANDREAS ,  REED KENNETH J

IPC: C01F17/00

CPC classification number: B01J23/10 ,  B01F3/0807 ,  B01F7/164 ,  B01J13/0047 ,  B01J13/0086 ,  B82Y30/00 ,  C10L1/10 ,  C10L1/103 ,  C10L1/1233 ,  C10L1/125 ,  C10L1/1258 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1811 ,  C10L1/1824 ,  C10L1/1881 ,  C10L1/1883 ,  C10L1/19 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/2437 ,  C10L10/02 ,  C10L10/08 ,  C10L10/12 ,  C10M2201/062 ,  C10N2230/06 ,  C10N2240/10 ,  Y02T50/678 ,  C10N2210/03 ,  C10N2220/082

Abstract: A method of making cerium dioxide nanoparticles includes: a) providing an aqueous reaction mixture having a source of cerous ion, a source of hydroxide ion, a nanoparticle stabilizer, and an oxidant at an initial temperature no higher than about 2O°C; b) mechanically shearing the mixture and causing it to pass through a perforated screen, thereby forming a suspension of cerium hydroxide nanoparticles; and c) raising the initial temperature to achieve oxidation of cerous ion to eerie ion and thereby form cerium dioxide nanoparticles having a mean diameter in the range of about 1 nm to about 15 nm. The cerium dioxide nanoparticles may be formed in a continuous process.

Abstract translation: 制备二氧化铈纳米颗粒的方法包括：a）在不高于约20℃的初始温度下，提供具有铈离子源，氢氧根离子源，纳米颗粒稳定剂和氧化剂的水性反应混合物; b）机械剪切混合物并使其通过穿孔筛网，从而形成氢氧化铈纳米颗粒的悬浮液; 和c）提高初始温度以实现铈离子氧化为奇异离子，从而形成平均直径在约1nm至约15nm范围内的二氧化铈纳米颗粒。 二氧化铈纳米颗粒可以以连续的方法形成。

公开(公告)号：WO2008030810A3

公开(公告)日：2008-12-24

申请号：PCT/US2007077540

申请日：2007-09-04

Applicant: CERION TECHNOLOGIES INC ,  REED KENNETH J

Inventor： REED KENNETH J

IPC: F01N3/00

CPC classification number: B01J23/10 ,  B01F3/0807 ,  B01F7/164 ,  B01J13/0047 ,  B01J13/0086 ,  B82Y30/00 ,  C10L1/10 ,  C10L1/103 ,  C10L1/1233 ,  C10L1/125 ,  C10L1/1258 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1811 ,  C10L1/1824 ,  C10L1/1881 ,  C10L1/1883 ,  C10L1/19 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/2437 ,  C10L10/02 ,  C10L10/08 ,  C10L10/12 ,  C10M2201/062 ,  C10N2230/06 ,  C10N2240/10 ,  Y02T50/678 ,  C10N2210/03 ,  C10N2220/082

Abstract: A lubricity additive composition includes a lubricating medium and, dispersed therein, cerium dioxide nanoparticles having a mean hydrodynamic diameter of about 1 nm to about 15 nm. In a method for reducing friction between, or scarring, abrasion, or pitting of metal surfaces in relative motion with one another, at least one of the metal surfaces has been contacted with a lubricity additive composition that includes a lubricating medium and, dispersed therein, cerium dioxide nanoparticles whose mean hydrodynamic diameter is about 1 nm to about 15 nm.

Abstract translation: 润滑性添加剂组合物包含润滑介质和分散于其中的平均流体动力学直径为约1nm至约15nm的二氧化铈纳米颗粒。 在减少相互之间的相对运动中的金属表面之间的摩擦或疤痕，磨损或点蚀的方法中，至少一个金属表面已经与润滑添加剂组合物接触，润滑添加剂组合物包含润滑介质， 其平均流体力学直径为约1nm至约15nm的二氧化铈纳米颗粒。