公开(公告)号：US10596739B2

公开(公告)日：2020-03-24

申请号：US15559357

申请日：2016-02-04

Applicant: RIKEN TECHNOS CORPORATION

Inventor： Nozomu Washio ,  Taketo Hashimoto ,  Jun Fujimoto

IPC: B29C48/15 ,  C09D7/40 ,  B32B27/18 ,  C08J7/04 ,  B32B1/00 ,  B32B27/20 ,  B32B27/30 ,  C09D133/10 ,  C09D135/02 ,  B05D1/00 ,  B05D1/02 ,  B29L31/30

Abstract: One embodiment provides a molded body that includes a resin substrate and in which: a part or all of the surface of the substrate is coated with a hard coat; a first hard coat is formed from a coating material that does not contain inorganic particles and that contains (A) 100 parts by mass of a polyfunctional (meth)acrylate, (B) 0.01-7 parts by mass of a water-repelling agent, and (C) 0.01-10 parts by mass of a silane coupling agent; and a second hard coat is formed from a coating material containing (A) 100 parts by mass of the polyfunctional (meth)acrylate and (D) 50-300 parts by mass of fine inorganic particles having an average particle size of 1-300 nm. Another embodiment provides a molded body that includes a resin substrate and in which a part or all of the surface of the substrate is coated with a hard coat, a first hard coat is formed from a coating material that does not contain inorganic particles, a second hard coat is formed from a coating material containing inorganic particles, (i) the total light transmittance is 85% or more, and (ii) the pencil hardness of the surface of the first hard coat is 5H or more.

公开(公告)号：US10689530B2

公开(公告)日：2020-06-23

申请号：US15516312

申请日：2015-09-11

Applicant: RIKEN TECHNOS CORPORATION

Inventor： Jun Fujimoto ,  Nozomu Washio

IPC: C08J7/04 ,  C09D133/10 ,  B05D3/14 ,  C09D7/40 ,  B32B27/00 ,  B32B27/16 ,  C09J133/26 ,  C09D4/00 ,  C09J7/38 ,  B32B27/20 ,  B32B7/12 ,  B32B27/08 ,  B32B27/28 ,  C09J7/20 ,  C09J7/21 ,  B32B7/04 ,  C09J7/28 ,  C09J7/25 ,  C09J7/26 ,  B32B27/32 ,  B32B27/36 ,  B32B27/30 ,  C09J7/22

Abstract: Embodiments provide a pressure-sensitive adhesive film having (α) a poly(meth)acrylimide-based resin film layer and (γ) a pressure-sensitive adhesive agent layer in that order from the surface layer side and having a total light transmittance of 80% or higher. The pressure-sensitive adhesive film may further have (δ) a hard coat layer on the surface layer side of the poly(meth)acrylimide-based resin film layer (α). This hard coat layer (δ) may comprise an active energy ray-curable resin composition that contains (A) 100 parts by mass of a polyfunctional (meth)acrylate; (B) 0.2-4 parts by mass of a compound having an alkoxysilyl group and a (meth)acryloyl group; (C) 0.05-3 parts by mass of organic titanium; and (D) 5-100 parts by mass of fine particles having an average particle diameter of 1-300 nm. This active energy ray-curable resin composition may further contain (E) 0.01-7 parts by mass of a water-repelling agent.

公开(公告)号：US11065852B2

公开(公告)日：2021-07-20

申请号：US15559240

申请日：2016-02-01

Applicant: RIKEN TECHNOS CORPORATION

Inventor： Jun Fujimoto ,  Nozomu Washio ,  Taketo Hashimoto

IPC: B32B27/20 ,  B32B27/30 ,  B32B7/12 ,  B32B38/00 ,  B32B27/06 ,  B29C48/21 ,  B32B23/18 ,  B32B27/16 ,  B32B27/40 ,  B32B7/02 ,  B32B27/32 ,  B32B7/04 ,  B32B23/08 ,  B32B27/36 ,  B32B23/04 ,  B32B27/08 ,  B32B27/34 ,  B32B27/28 ,  C09D7/40

Abstract: An embodiment provides an adhesive film having, in order from the surface layer side, a first hard coat, a second hard coat, a transparent resin film layer, and an adhesive layer. The first hard coat is formed from a coating that does not include inorganic particles. The second hard coat is formed from a coating that includes inorganic particles. The adhesive film satisfies the following conditions: (i) the total light transmittance is at least 85%; and (vii) the pencil hardness of the first hard coat surface is at least 5H. Another embodiment provides an adhesive film having, in order from the surface layer side, a first hard coat, a second hard coat, a transparent resin film layer, and an adhesive layer. The first hard coat is formed from a coating that does not include inorganic particles. The second hard coat is formed from a coating that includes inorganic particles. The adhesive film satisfies the following conditions: (i) the total light transmittance is at least 85%; (iv) the water contact angle at the first hard coat surface is at least 100 degrees; and (v) the water contact angle at the first hard coat surface after 20,000 reciprocal cotton rubs is at least 100 degrees.

公开(公告)号：US11512176B2

公开(公告)日：2022-11-29

申请号：US16930243

申请日：2020-07-15

Applicant: RIKEN TECHNOS CORPORATION

Inventor： Jun Fujimoto ,  Nozomu Washio ,  Taketo Hashimoto

IPC: C08J7/046 ,  C08J7/043 ,  C09D7/40 ,  B32B27/30 ,  C08J7/04 ,  G02B1/111

Abstract: One embodiment provides a hard coat laminated film, comprising, in order from a surface layer side, a first hard coat, a second hard coat, and a transparent resin film layer, where the first hard coat is formed of a coating material including: (A) 100 parts by mass of a polyfunctional (meth)acrylate; (B) 0.01 to 7 parts by mass of a water repellent; (C) 0.01 to 10 parts by mass of a silane coupling agent; and (D) 0.1 to 10 parts by mass of resin microparticles having an average particle diameter of 0.5 to 10 μm, and containing no inorganic particles, and where the second hard coat is formed of a coating material containing inorganic particles. Another embodiment provides a hard coat laminated film having, in order from a surface layer side, a first hard coat, a second hard coat, and a resin film layer. The first hard coat includes a coating material that does not include inorganic particles. The second hard coat includes a coating material including inorganic particles. The adhesive film fulfills the conditions: (i) a total light transmission rate of at least 85%; (ii) a pencil hardness for the first hard coat surface of at least 5H; and (iii) a Y value for an XYZ color system of 1.5%-4.2%.

公开(公告)号：US10809418B2

公开(公告)日：2020-10-20

申请号：US15559383

申请日：2016-02-04

Applicant: RIKEN TECHNOS CORPORATION

Inventor： Jun Fujimoto ,  Nozomu Washio ,  Taketo Hashimoto

IPC: G02B1/111 ,  C09D7/40 ,  C08J7/04 ,  B32B27/30

Abstract: One embodiment provides a hard coat laminated film having, in order from a surface layer side, a first hard coat and a transparent resin film layer. The first hard coat includes a coating material not including inorganic particles and including: (A) 100 parts by mass polyfunctional (meth) acrylate; (B) 0.01-7 parts by mass water repellent; (C) 0.01-10 parts by mass silane coupling agent; and (D) 0.1-10 parts by mass resin microparticles having an average particle diameter of 0.5-10 μm. Another embodiment provides a hard coat laminated film having, in order from a surface layer side, a first hard coat, a second hard coat, and a resin film layer. The first hard coat includes a coating material that does not include inorganic particles. The second hard coat includes a coating material including inorganic particles. The adhesive film fulfills the conditions: (i) a total light transmission rate of at least 85%; (ii) a pencil hardness for the first hard coat surface of at least 5H; and (iii) a Y value for an XYZ color system of 1.5%-4.2%.