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公开(公告)号:AT526358T
公开(公告)日:2011-10-15
申请号:AT04722422
申请日:2004-03-22
Applicant: SEKISUI PLASTICS
Inventor: MATSUMURA HIDEYASU , TSUTSUI YASUTAKA
Abstract: According to the present invention, there is provided expandable beads of a styrene-modified linear low-density polyethylene-based resin comprising a volatile blowing agent and a base resin, the base resin containing more than 50 to 1000 parts by weight of a polystyrene-based resin component relative to 100 parts by weight of a non-crosslinked linear low-density polyethylene-based resin component, wherein the base resin contains less than 2 wt% of a gel component comprising a graft polymer of the polystyrene-based resin component and the low-density polyethylene-based resin component.
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公开(公告)号:DE69926268T2
公开(公告)日:2006-05-24
申请号:DE69926268
申请日:1999-12-10
Applicant: SEKISUI PLASTICS
Inventor: HIRAI TAKAAKI , FUJISHIMA MINORU , UENO HIROYUKI , MATSUMURA HIDEYASU , MORIOKA IKUO , ARAMOMI YUKIO , YAMAGATA HIROYUKI
Abstract: The present invention provides a process for producing a molded foam article of a crystalline aromatic polyester resin. The process is characterized by heating the surface temperature of a mold for cavity-molding to the temperature within a range of from ( Tg + 35 ) to ( Tg + 57 ) DEG C (Tg is a glass transition temperature of the crystalline aromatic polyester resin prepuffs), thereby tomoldprepuffs, and cooling the surface of the mold to a temperature not lowered than Tg for at least 20 seconds.
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公开(公告)号:DE69927615D1
公开(公告)日:2006-02-16
申请号:DE69927615
申请日:1999-12-10
Applicant: SEKISUI PLASTICS
Inventor: HIRAI TAKAAKI , FUJISHIMA MINORU , UENO HIROYUKI , MATSUMURA HIDEYASU , MORIOKA IKUO , NAKAYAMA SHINPEI
Abstract: The present invention provides a crystalline aromatic polyester resin prepuff which is superior in foaming fusion during cavity-molding, and a molded foam article and a-laminated molded foam article, using the prepuff, wherein its fusion ratio and mechanical strength are particulary improved. The prepuff is formed from a crystalline aromatic polyester resin, wherein a bulk density is from 0.01 to 1.0 g/cm and a crystallization' peak temperature is from 130 to 180 DEG C. The molded foam article is prepared by molding further expanding and fusing the prepuffs in a mold cavity, while the laminated molded foam article is formed by laminating the molded foam article directory to the film or sheet of the aromatic polyester resin.
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公开(公告)号:DE69927615T2
公开(公告)日:2006-07-06
申请号:DE69927615
申请日:1999-12-10
Applicant: SEKISUI PLASTICS
Inventor: HIRAI TAKAAKI , FUJISHIMA MINORU , UENO HIROYUKI , MATSUMURA HIDEYASU , MORIOKA IKUO , NAKAYAMA SHINPEI
Abstract: The present invention provides a crystalline aromatic polyester resin prepuff which is superior in foaming fusion during cavity-molding, and a molded foam article and a-laminated molded foam article, using the prepuff, wherein its fusion ratio and mechanical strength are particulary improved. The prepuff is formed from a crystalline aromatic polyester resin, wherein a bulk density is from 0.01 to 1.0 g/cm and a crystallization' peak temperature is from 130 to 180 DEG C. The molded foam article is prepared by molding further expanding and fusing the prepuffs in a mold cavity, while the laminated molded foam article is formed by laminating the molded foam article directory to the film or sheet of the aromatic polyester resin.
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公开(公告)号:DE69926268D1
公开(公告)日:2005-08-25
申请号:DE69926268
申请日:1999-12-10
Applicant: SEKISUI PLASTICS
Inventor: HIRAI TAKAAKI , FUJISHIMA MINORU , UENO HIROYUKI , MATSUMURA HIDEYASU , MORIOKA IKUO , ARAMOMI YUKIO , YAMAGATA HIROYUKI
Abstract: The present invention provides a process for producing a molded foam article of a crystalline aromatic polyester resin. The process is characterized by heating the surface temperature of a mold for cavity-molding to the temperature within a range of from ( Tg + 35 ) to ( Tg + 57 ) DEG C (Tg is a glass transition temperature of the crystalline aromatic polyester resin prepuffs), thereby tomoldprepuffs, and cooling the surface of the mold to a temperature not lowered than Tg for at least 20 seconds.
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公开(公告)号:AT299789T
公开(公告)日:2005-08-15
申请号:AT99959786
申请日:1999-12-10
Applicant: SEKISUI PLASTICS
Inventor: HIRAI TAKAAKI , FUJISHIMA MINORU , UENO HIROYUKI , MATSUMURA HIDEYASU , MORIOKA IKUO , ARAMOMI YUKIO , YAMAGATA HIROYUKI
Abstract: The present invention provides a process for producing a molded foam article of a crystalline aromatic polyester resin. The process is characterized by heating the surface temperature of a mold for cavity-molding to the temperature within a range of from ( Tg + 35 ) to ( Tg + 57 ) DEG C (Tg is a glass transition temperature of the crystalline aromatic polyester resin prepuffs), thereby tomoldprepuffs, and cooling the surface of the mold to a temperature not lowered than Tg for at least 20 seconds.
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公开(公告)号:AT550374T
公开(公告)日:2012-04-15
申请号:AT07831084
申请日:2007-10-25
Applicant: SEKISUI PLASTICS
Inventor: MORIOKA IKUO , TSUTSUI YASUTAKA , MATSUMURA HIDEYASU
Abstract: Expandable polystyrenic resin particles having superior resistance to cracking of a molded foam product, having superior retention of blowing agent and maintaining expandability over a long period of time, a production process thereof, and a molded foam product are provided. These expandable polystyrenic resin particles contain a volatile blowing agent in polystyrenic resin particles obtained by impregnating and polymerizing a styrenic monomer in polyolefin resin particles to form a polystyrenic resin, wherein together with the styrenic monomer being used at 140 to 600 parts by weight to 100 parts by weight of the polyolefin resin particles, the average thickness of the surface layer observed in scanning electron micrographs obtained by immersing sections cut into halves through the center from the surface of the resin particles in tetrahydrofuran followed by extracting the polystyrenic resin component and capturing cross-sections of said sections is 15 to 150 μm, and the volatile blowing agent is contained at 5.5 to 13.0% by weight.
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公开(公告)号:AT498639T
公开(公告)日:2011-03-15
申请号:AT05772816
申请日:2005-08-19
Applicant: SEKISUI PLASTICS
Inventor: MATSUMURA HIDEYASU , MATSUGASHITA TATSUYA
IPC: C08F255/02 , C08F285/00 , C08J9/16 , C08J9/18 , C08L23/06 , C08L23/08 , C08L25/06
Abstract: A method for producing styrene-modified polyethylene-based resin beads, including the steps of: dispersing 100 parts by weight of polyethylene-based resin beads which contain an inorganic nucleating agent and have a melting point of 95 C to 115 C, 20 parts by weight or more and less than 300 parts by weight of a styrene-based monomer and a polymerization initiator into an aqueous suspension containing a dispersant; impregnating the polyethylene-based resin beads with the styrene-based monomer under heating the resulting dispersion at such a temperature that the styrene-based monomer does not substantially polymerize; and performing polymerization of the styrene-based monomer at a temperature of (T) C to (T+25) C (where T C is a melting point of the polyethylene-based resin beads.)
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公开(公告)号:AT450561T
公开(公告)日:2009-12-15
申请号:AT04747876
申请日:2004-07-23
Applicant: SEKISUI PLASTICS
Inventor: INADA NAOKUNI , MATSUMURA HIDEYASU , TSUTSUI YASUTAKA , MORIOKA IKUO
Abstract: A pre-expanded beads of olefin-modified polystyrene-based resin comprising a pre-expanded beads of a polystyrene-based resin modified with a polyolefin-based resin, wherein a styrene-based monomer forming a polystyrene-based resin in the beads is used in the range of 100 to 1,000 parts by weight relative to 100 parts by weight of a polyolefin-based resin, a bulk density of each bead is 0.012 to 0.20 g/cm 3 , and an absorbance ratio at 698 cm -1 and 2850 cm -1 (D 698 /D 2850 ) obtained from an infrared absorption spectrum of each bead surface measured by ATR method infrared spectroscopy is in the range of 0.1 to 2.5.
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公开(公告)号:AU1685000A
公开(公告)日:2000-07-03
申请号:AU1685000
申请日:1999-12-10
Applicant: SEKISUI PLASTICS
Inventor: HIRAI TAKAAKI , FUJISHIMA MINORU , UENO HIROYUKI , MATSUMURA HIDEYASU , MORIOKA IKUO , NAKAYAMA SHINPEI
Abstract: The present invention provides a crystalline aromatic polyester resin prepuff which is superior in foaming fusion during cavity-molding, and a molded foam article and a-laminated molded foam article, using the prepuff, wherein its fusion ratio and mechanical strength are particulary improved. The prepuff is formed from a crystalline aromatic polyester resin, wherein a bulk density is from 0.01 to 1.0 g/cm and a crystallization' peak temperature is from 130 to 180 DEG C. The molded foam article is prepared by molding further expanding and fusing the prepuffs in a mold cavity, while the laminated molded foam article is formed by laminating the molded foam article directory to the film or sheet of the aromatic polyester resin.
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