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公开(公告)号:AT526358T
公开(公告)日:2011-10-15
申请号:AT04722422
申请日:2004-03-22
Applicant: SEKISUI PLASTICS
Inventor: MATSUMURA HIDEYASU , TSUTSUI YASUTAKA
Abstract: According to the present invention, there is provided expandable beads of a styrene-modified linear low-density polyethylene-based resin comprising a volatile blowing agent and a base resin, the base resin containing more than 50 to 1000 parts by weight of a polystyrene-based resin component relative to 100 parts by weight of a non-crosslinked linear low-density polyethylene-based resin component, wherein the base resin contains less than 2 wt% of a gel component comprising a graft polymer of the polystyrene-based resin component and the low-density polyethylene-based resin component.
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公开(公告)号:DE112011101173B4
公开(公告)日:2022-01-05
申请号:DE112011101173
申请日:2011-01-24
Applicant: SEKISUI PLASTICS
Inventor: TSUTSUI YASUTAKA , OZAWA MASAHIKO
Abstract: Expandierbare Verbund-Harzteilchen für die Gefrierlagerung, umfassend: Verbund-Harzteilchen aus einem Harz auf Polyolefinbasis und einem Harz auf Polystyrolbasis; 7,5 bis 11 Gew.% eines flüchtigen Blasmittels, das in den Verbund-Harzteilchen enthalten ist und Pentan umfasst; 0,5 bis 1,5 Gew.% Feuchtigkeit, die an den Oberflächen der Verbund-Harzteilchen anhaftet; und 0,05 bis 0,5 Gew.% interne Feuchtigkeit.
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公开(公告)号:AT550374T
公开(公告)日:2012-04-15
申请号:AT07831084
申请日:2007-10-25
Applicant: SEKISUI PLASTICS
Inventor: MORIOKA IKUO , TSUTSUI YASUTAKA , MATSUMURA HIDEYASU
Abstract: Expandable polystyrenic resin particles having superior resistance to cracking of a molded foam product, having superior retention of blowing agent and maintaining expandability over a long period of time, a production process thereof, and a molded foam product are provided. These expandable polystyrenic resin particles contain a volatile blowing agent in polystyrenic resin particles obtained by impregnating and polymerizing a styrenic monomer in polyolefin resin particles to form a polystyrenic resin, wherein together with the styrenic monomer being used at 140 to 600 parts by weight to 100 parts by weight of the polyolefin resin particles, the average thickness of the surface layer observed in scanning electron micrographs obtained by immersing sections cut into halves through the center from the surface of the resin particles in tetrahydrofuran followed by extracting the polystyrenic resin component and capturing cross-sections of said sections is 15 to 150 μm, and the volatile blowing agent is contained at 5.5 to 13.0% by weight.
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公开(公告)号:AT450561T
公开(公告)日:2009-12-15
申请号:AT04747876
申请日:2004-07-23
Applicant: SEKISUI PLASTICS
Inventor: INADA NAOKUNI , MATSUMURA HIDEYASU , TSUTSUI YASUTAKA , MORIOKA IKUO
Abstract: A pre-expanded beads of olefin-modified polystyrene-based resin comprising a pre-expanded beads of a polystyrene-based resin modified with a polyolefin-based resin, wherein a styrene-based monomer forming a polystyrene-based resin in the beads is used in the range of 100 to 1,000 parts by weight relative to 100 parts by weight of a polyolefin-based resin, a bulk density of each bead is 0.012 to 0.20 g/cm 3 , and an absorbance ratio at 698 cm -1 and 2850 cm -1 (D 698 /D 2850 ) obtained from an infrared absorption spectrum of each bead surface measured by ATR method infrared spectroscopy is in the range of 0.1 to 2.5.
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公开(公告)号:MY143770A
公开(公告)日:2011-07-15
申请号:MYPI20041069
申请日:2004-03-25
Applicant: SEKISUI PLASTICS
Inventor: MATSUMURA HIDEYASU , TSUTSUI YASUTAKA
Abstract: ACCORDING TO THE PRESENT INVENTION, THERE IS PROVIDED EXPANDABLE BEADS OF A STYRENE-MODIFIED LINEAR LOW-DENSITY POLYETHYLENE-BASED RESIN COMPRISING A VOLATILE BLOWING AGENT AND A BASE RESIN, THE BASE RESIN CONTAINING MORE THAN 50 TO 1000 PARTS BY WEIGHT OF A POLYSTYRENE-BASED RESIN COMPONENT RELATIVE TO 100 PARTS BY WEIGHT OF A NON-CROSSLINKED LINEAR LOW-DENSITY POLYETHYLENE-BASED RESIN COMPONENT, WHEREIN THE BASE RESIN CONTAINS LESS THAN 2 WT% OF A GEL COMPONENT COMPRISING A GRAFT POLYMER OF THE POLYSTYRENE-BASED RESIN COMPONENT AND THE LOW-DENSITY POLYETHYLENE-BASED RESIN COMPONENT.
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公开(公告)号:MY136268A
公开(公告)日:2008-09-30
申请号:MYPI20041070
申请日:2004-03-25
Applicant: SEKISUI PLASTICS
Inventor: MATSUMURA HIDEYASU , TSUTSUI YASUTAKA
Abstract: ACCORDING TO THE PRESENT INVENTION, THERE IS PROVIDED EXPANDABLE BEADS OF A STYRENE-MODIFIED LINEAR LOW-DENSITY POLYETHYLENE-BASED RESIN COMPRISING A VOLATILE BLOWING AGENT AND A BASE RESIN, THE BASE RESIN CONTAINING MORE THAN 300 PARTS BY WEIGHT AND LESS THAN 1000 PARTS BY WEIGHT OF A POLYSTYRENE-BASED RESIN COMPONENT RELATIVE TO 100 PARTS BY WEIGHT OF A NON-CROSSLINKED LINEAR LOW-DENSITY POLYETHYLENE-BASED RESIN COMPONENT, WHEREIN THE BASE RESIN CONTAINS 2 TO 40 WT% OF A GEL COMPONENT COMPRISING A GRAFT COPOLYMER OF THE POLYSTRENE-BASED RESIN COMPONENT AND THE LOW-DENSITY POLYETHYLENE-BASED RESIN COMPONENT.
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公开(公告)号:BRPI0718499A2
公开(公告)日:2014-07-08
申请号:BRPI0718499
申请日:2007-10-25
Applicant: SEKISUI PLASTICS
Inventor: MORIOKA IKUO , TSUTSUI YASUTAKA , MATSUMURA HIDEYASU
Abstract: Expandable polystyrenic resin particles having superior resistance to cracking of a molded foam product, having superior retention of blowing agent and maintaining expandability over a long period of time, a production process thereof, and a molded foam product are provided. These expandable polystyrenic resin particles contain a volatile blowing agent in polystyrenic resin particles obtained by impregnating and polymerizing a styrenic monomer in polyolefin resin particles to form a polystyrenic resin, wherein together with the styrenic monomer being used at 140 to 600 parts by weight to 100 parts by weight of the polyolefin resin particles, the average thickness of the surface layer observed in scanning electron micrographs obtained by immersing sections cut into halves through the center from the surface of the resin particles in tetrahydrofuran followed by extracting the polystyrenic resin component and capturing cross-sections of said sections is 15 to 150 μm, and the volatile blowing agent is contained at 5.5 to 13.0% by weight.
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公开(公告)号:DE112011101173T5
公开(公告)日:2013-01-10
申请号:DE112011101173
申请日:2011-01-24
Applicant: SEKISUI PLASTICS
Inventor: OZAWA MASAHIKO , TSUTSUI YASUTAKA
IPC: C08J9/18 , B29C44/00 , B29K23/00 , B29K25/00 , B29K105/04
Abstract: Expandierbare Verbund-Harzteilchen für die Gefrierlagerung, umfassend: Verbund-Harzteilchen aus einem Harz auf Polyolefinbasis und einem Harz auf Polystyrolbasis; 7,5 bis 11 Gew.-% eines flüchtigen Blasmittels, das in den Verbund-Harzteilchen enthalten ist und Pentan umfasst, und 0,5 bis 1,5 Gew.-% Feuchtigkeit, die an den Oberflächen der Verbund-Harzteilchen anhaftet.
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公开(公告)号:DE602004024415D1
公开(公告)日:2010-01-14
申请号:DE602004024415
申请日:2004-07-23
Applicant: SEKISUI PLASTICS
Inventor: INADA NAOKUNI , MATSUMURA HIDEYASU , TSUTSUI YASUTAKA , MORIOKA IKUO
Abstract: A pre-expanded beads of olefin-modified polystyrene-based resin comprising a pre-expanded beads of a polystyrene-based resin modified with a polyolefin-based resin, wherein a styrene-based monomer forming a polystyrene-based resin in the beads is used in the range of 100 to 1,000 parts by weight relative to 100 parts by weight of a polyolefin-based resin, a bulk density of each bead is 0.012 to 0.20 g/cm 3 , and an absorbance ratio at 698 cm -1 and 2850 cm -1 (D 698 /D 2850 ) obtained from an infrared absorption spectrum of each bead surface measured by ATR method infrared spectroscopy is in the range of 0.1 to 2.5.
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公开(公告)号:MY140435A
公开(公告)日:2009-12-31
申请号:MYPI20043527
申请日:2004-08-28
Applicant: SEKISUI PLASTICS
Inventor: INADA NAOKUNI , MATSUMURA HIDEYASU , TSUTSUI YASUTAKA , MORIOKA IKUO
Abstract: A PRE-EXPANDED BEADS OF OLEFIN-MODIFIED POLYSTYRENE-BASED RESIN COMPRISING A PRE-EXPANDED BEADS OF A POLYSTYRENE-BASED RESIN MODIFIED WITH A POLYOLEFIN-BASED RESIN, WHEREIN A STYRENE-BASED MONOMER FORMING A POLYSTYRENE-BASED RESIN IN THE BEADS IS USED IN THE RANGE OF 100 TO 1,000 PARTS BY WEIGHT RELATIVE TO 100 PARTS BY WEIGHT OF A POLYOLEFIN-BASED RESIN, A BULK DENSITY OF EACH BEAD IS 0.012 TO 0.20 G/CM³, AND AN ABSORBANCE RATIO AT 698 CM-1 AND 2850 cm-¹(D698/D2850) OBTAINED FROM AN INFRARED ABSORPTION APECTRUM OF EACH BEAD SURFACE MEASURED BY ATR METHOD INFRARED SPECTROSCOPY IS IN THE RANGE OF 0.1 TO 2.5.
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