公开(公告)号：WO2015163083A1

公开(公告)日：2015-10-29

申请号：PCT/JP2015059418

申请日：2015-03-26

Applicant: SEKISUI PLASTICS

Inventor： TAKAYAMA MAYUMI ,  TAKENAKA TOSHIKI ,  KUSAKA AKIYOSHI ,  GOTO TAKASHI

IPC: C08F2/18 ,  C08L101/00 ,  C09D7/12 ,  C09D201/00

CPC classification number: C08L33/12 ,  C08F2/18 ,  C08F212/08 ,  C08F220/14 ,  C08F265/04 ,  C08F265/06 ,  C08G18/6225 ,  C08L1/284 ,  C08L101/00 ,  C08L2205/025 ,  C08L2205/03 ,  C09D7/40 ,  C09D101/284 ,  C09D133/12 ,  C09D175/04 ,  C09D201/00 ,  G02B1/04 ,  C08F2222/1013 ,  C08F2216/1475 ,  C08F2220/286 ,  C08F2/22 ,  C08F230/02 ,  C08L51/003 ,  C08L51/02

Abstract: Provided are: a method for producing particles by suspension polymerization, the method having exceptional monomer dispersion stability and also making it possible to simplify a cleaning step; composite particles that can be obtained by this production method; and the use of these composite particles. This method for producing composite particles includes a step for conducting the aqueous suspension polymerization of a monomer mixture containing a polymerizable vinyl monomer in the presence of small polymer particles having a volume-average particle size of 20-500 nm with water-soluble celluloses adsorbed to the surface, and obtaining composite particles that contain these small polymer particles and large polymer particles larger than these small polymer particles.

Abstract translation: 提供：通过悬浮聚合制备颗粒的方法，该方法具有独特的单体分散稳定性，并且还可以简化清洗步骤; 可以通过该制造方法获得的复合颗粒; 并使用这些复合颗粒。 该复合粒子的制造方法包括在体积平均粒径为20〜500nm的小聚合物粒子的存在下，将含有可聚合乙烯基单体的单体混合物进行水悬浮聚合的步骤，其中吸附有水溶性纤维素 并且获得含有这些小聚合物颗粒和大于这些小聚合物颗粒的大聚合物颗粒的复合颗粒。

公开(公告)号：EP3070106A4

公开(公告)日：2017-07-05

申请号：EP13897565

申请日：2013-11-13

Applicant: SEKISUI PLASTICS

Inventor： TAKENAKA TOSHIKI ,  TAKAYAMA MAYUMI ,  KUSAKA AKIYOSHI ,  NAKAMURA MASAAKI

IPC: C08F2/44 ,  C09D7/12 ,  C09D201/00

CPC classification number: C09D7/1216 ,  C08F2/18 ,  C08F2/44 ,  C08F220/14 ,  C08K3/36 ,  C09D7/40 ,  C09D7/61 ,  C09D133/12 ,  C09D201/00 ,  C08F2222/1013 ,  C08F2222/1026

Abstract: In a method for producing composite particles containing polymer particles and silica particles that adhere to the polymer particles, the composite particles are obtained by subjecting a polymerizable monomer to aqueous suspension polymerization in a presence of silica particles and a cellulose compound adsorbing onto the silica particles. The composite particles contain the polymer particles, the silica particles that adhere to surfaces of the polymer particles, and the water-soluble cellulose compound.

Abstract translation: 在生产含有聚合物颗粒和粘附到聚合物颗粒上的二氧化硅颗粒的复合颗粒的方法中，复合颗粒是通过使可聚合单体在二氧化硅颗粒和吸附在二氧化硅颗粒上的纤维素化合物存在下进行水悬浮聚合而获得的。 复合颗粒包含聚合物颗粒，附着于聚合物颗粒表面的二氧化硅颗粒和水溶性纤维素化合物。

公开(公告)号：JP2014181276A

公开(公告)日：2014-09-29

申请号：JP2013056276

申请日：2013-03-19

Applicant: Sekisui Plastics Co Ltd ,  積水化成品工業株式会社

Inventor： TAKAYAMA MAYUMI

IPC: C08L57/00 ,  C08F220/56 ,  C08K5/053 ,  C08L29/04

Abstract: PROBLEM TO BE SOLVED: To provide an elastic hydrogel having a high tensile strength.SOLUTION: The provided hydrogel includes a polymer matrix, a polyvinyl alcohol polymer, water, and a polyalcohol. The polymer matrix consists of a copolymer of a monofunctional monomer possessing one intramolecular polymerizable carbon-carbon double bond and a crosslinkable monomer possessing two or more intramolecular polymerizable carbon-carbon double bonds, whereas a liquid mixture including a polyvinyl alcohol polymer having a viscosity-average degree of polymerization of 200-1500, water, and at least one type of polyalcohol is retained within the polymer matrix. Moreover, the content of the polyvinyl alcohol polymer with respect to 100 pts.wt. of the polymer matrix is 35-70 pts.wt.

Abstract translation: 要解决的问题：提供具有高拉伸强度的弹性水凝胶。溶液：所提供的水凝胶包括聚合物基质，聚乙烯醇聚合物，水和多元醇。 聚合物基质由具有一个分子内可聚合碳 - 碳双键的单官能单体和具有两个或更多个分子内可聚合碳 - 碳双键的可交联单体的共聚物组成，而包含具有粘均分子量的聚乙烯醇聚合物 200-1500的聚合度，水和至少一种类型的多元醇保留在聚合物基体内。 此外，聚乙烯醇聚合物的含量相对于100重量份 的聚合物基质为35-70重量份

公开(公告)号：JP2013112689A

公开(公告)日：2013-06-10

申请号：JP2011257219

申请日：2011-11-25

Applicant: Sekisui Plastics Co Ltd ,  積水化成品工業株式会社

Inventor： FUJIWARA YASUHIRO ,  SATO KAORI ,  TAKAYAMA MAYUMI

IPC: C09J201/00 ,  C09J133/04 ,  C09J133/24

Abstract: PROBLEM TO BE SOLVED: To provide a self-restoring adhesive whose adhesive force to an adherend is reduced by heating and which thereby is easily peeled from the adherend without damaging the adherend and which is excellent in repetitive usability.SOLUTION: The self-restoring adhesive 1 is obtained by forming a shape having at least one of projections and recesses 1a on an adhesive polymer material, which has such a shape self-restoring property that the adhesive polymer material restores a shape before compressive deformation when it is heated after compressively deformed under heating and then cooled so that the adhesive force may be reduced when the self-restoring adhesive 1 restores a shape before compressive deformation by heating after it is compressively deformed and then cooled.

Abstract translation: 要解决的问题：提供一种自粘合剂，其通过加热减少对被粘物的粘合力，从而容易地从被粘物上剥离而不损坏被粘物，并且其重复使用性优异。 解决方案：通过在粘合剂聚合物材料上形成具有凸起和凹陷1a中的至少一个的形状来获得自恢复粘合剂1，其具有使粘合剂聚合物材料恢复形状的形状自恢复性 当在加热下被压缩变形后被加热并随后冷却时的压缩变形，使得当自恢复粘合剂1在压缩变形之后通过加热而变形然后冷却后恢复形状时，粘合力可能降低。 版权所有（C）2013，JPO＆INPIT

公开(公告)号：JP2014019753A

公开(公告)日：2014-02-03

申请号：JP2012157635

申请日：2012-07-13

Applicant: Sekisui Plastics Co Ltd ,  積水化成品工業株式会社

Inventor： TAKAYAMA MAYUMI ,  SATO KAORI

IPC: C08J5/18 ,  C08F299/06

Abstract: PROBLEM TO BE SOLVED: To provide a self-absorption polymer sheet having no adhesiveness and excellent in self-absorption property and detachability to an adherend.SOLUTION: A self-absorption polymer sheet contains a polymer of monomer mixture that contains at least (A) polyfunctional urethane(meth)polyacrylate having two or more (meth)acryloyl groups in a molecule and rigidity of 10 to 70 when cured alone and (B) polyfunctional urethane(meth)polyacrylate having two or more (meth)acryloyl groups in a molecule and rigidity of 80 to 100 when cured alone, and a 90° peel force of the self-absorption polymer sheet to a borosilicate glass is 0.3 N/20 mm or less and a vertical peel force of the self-absorption polymer sheet to the borosilicate glass is 8 to 30 N.

Abstract translation: 要解决的问题：提供一种自吸收聚合物片材，其具有粘合性，并且具有优异的自吸收性和对被粘物的剥离性。溶解性：自吸收聚合物片材含有至少包含（A）的单体混合物的聚合物， 分子中具有2个以上（甲基）丙烯酰基的多官能氨基甲酸酯（甲基）丙烯酸酯，单独固化时的刚性为10〜70，（B）分子中具有2个以上（甲基）丙烯酰基的多官能氨基甲酸酯（甲基） 单独固化时的刚性为80〜100，自吸收聚合物片对硼硅酸盐玻璃的剥离力为90°，为0.3N / 20mm以下，自吸收性聚合物片与硼硅酸盐玻璃的垂直剥离力 是8到30 N.

公开(公告)号：JP2013181127A

公开(公告)日：2013-09-12

申请号：JP2012046957

申请日：2012-03-02

Applicant: Sekisui Plastics Co Ltd ,  積水化成品工業株式会社

Inventor： FUJIWARA YASUHIRO ,  TAKAYAMA MAYUMI

IPC: C08L55/00 ,  C08L71/02 ,  C09J7/00 ,  C09J133/04 ,  C09J171/00 ,  C09J175/04

Abstract: PROBLEM TO BE SOLVED: To provide a polymer gel and a polymer gel sheet, which have sufficient tackiness (pastability) to an adherend such as glass or metal plates, can easily be peeled off the adherend and reutilized, and have sufficient pastability and reworkability.SOLUTION: A polymer gel contains a polymer of an urethane (meth)acrylate having two or more methacryloyl groups in one molecule, and a polyol compound, and has dynamic viscoelasticity in which the value of a dynamic loss elastic modulus G" at 25°C measured in a temperature dispersion at a frequency of 1 Hz is in the range of 1.0×10to 1.0×10Pa, and the loss tangent tanδ is

Abstract translation: 要解决的问题：为了提供对粘合剂如玻璃或金属板具有足够的粘合性（粘合性）的聚合物凝胶和聚合物凝胶片，可以容易地从被粘物上剥离并再利用，并且具有足够的耐湿性和再加工性。 解决方案：聚合物凝胶包含一分子中具有两个或多个甲基丙烯酰基的氨基甲酸酯（甲基）丙烯酸酯和多元醇化合物的聚合物，并且具有动态粘弹性，其中25℃下的动态损耗弹性模量G“ 以1Hz的频率测量的温度分布在1.0×10〜1.0×10Pa的范围内，损耗角正切tanδ<0.05。