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公开(公告)号:EP0848692A4
公开(公告)日:1999-07-21
申请号:EP96930734
申请日:1996-09-06
Applicant: SOUTHERN CLAY PROD INC , AKZO NOBEL INC
Inventor: GADBERRY JAMES F , HOEY MICHAEL , POWELL CLOIS E
CPC classification number: C04B33/04
Abstract: Organoclay compositions which comprise the reaction product of a smectite-type clay having an ion exchange capacity of at least 50 meq. wt. per 100 g. clay (active basis), and an alkoxylated quaternary ammonium compound having one or two alkoxylated chains containing 0-10 moles ethylene oxide and 3-15 moles of propylene or butylene oxide residues are useful thixotropic materials, especially for the preparation of aqueous systems.
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公开(公告)号:EP0848728A4
公开(公告)日:1999-01-27
申请号:EP96929938
申请日:1996-09-06
Applicant: SOUTHERN CLAY PROD INC
Inventor: BAUER CARL J , BOOTHE JOHN D , DENNIS HARRY RYAN , POWELL CLOIS E , ORTIZ JOE A
CPC classification number: C01B33/44 , C01P2006/22 , C09C1/42 , C09D5/04
Abstract: Organoclay compositions which comprise the reaction product of a smectite-type clay having an ion exchange capacity of at least 50 meq. wt. per 100 g. clay (active basis), and an alkoxylated quaternary ammonium compound having one or two alkoxylated chains containing 0-10 moles ethylene oxide and 3-15 moles of propylene or butylene oxide residues are useful thixotropic materials, especially for the preparation of aqueous systems such as latex paint formulations.
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3.
公开(公告)号:AU776809B2
公开(公告)日:2004-09-23
申请号:AU1339801
申请日:2000-10-20
Applicant: SOUTHERN CLAY PROD INC
Inventor: POWELL CLOIS E , GADBERRY JAMES F , HOEY MICHAEL
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公开(公告)号:AU1966397A
公开(公告)日:1997-09-10
申请号:AU1966397
申请日:1997-02-21
Applicant: DOW CHEMICAL CO , SOUTHERN CLAY PROD INC
Inventor: GONZALES ANTONIO , NICHOLS KEVIN L , POWELL CLOIS E , THILL BRUCE P
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5.
公开(公告)号:AU1339801A
公开(公告)日:2001-04-30
申请号:AU1339801
申请日:2000-10-20
Applicant: SOUTHERN CLAY PROD INC
Inventor: POWELL CLOIS E , GADBERRY JAMES F , HOEY MICHAEL
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公开(公告)号:CA2230587A1
公开(公告)日:1997-03-13
申请号:CA2230587
申请日:1996-09-06
Applicant: SOUTHERN CLAY PROD INC , AKZO NOBEL INC
Inventor: GADBERRY JAMES F , HOEY MICHAEL , POWELL CLOIS E
Abstract: Organoclay compositions which comprise the reaction product of a smectite-type clay having an ion exchange capacity of at least 50 meq. wt. per 100 g. clay (active basis), and an alkoxylated quaternary ammonium compound having one or two alkoxylated chains containing 0-10 moles ethylene oxide and 3-15 moles of propylene or butylene oxide residues are useful thixotropic materials, especially for the preparation of aqueous systems.
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7.
公开(公告)号:GB2371044A
公开(公告)日:2002-07-17
申请号:GB0208990
申请日:2000-10-20
Applicant: SOUTHERN CLAY PROD INC
Inventor: POWELL CLOIS E , GADBERRY JAMES F , HOEY MICHAEL
Abstract: Organoclays based on specific types of ester quats may be remarkably effective for use in preparing nanocomposites. These organoclays may comprise the reaction product of a smectite clay and a quaternary ammonium compound (or "quat") which may comprise two esterified radicals (hereinafter called a "diester quat"). The diester quat may be present in admixture with further quaternary ammonium compounds having esterified radicals, especially compounds having three esterified radicals (hereinafter "triester quats"); or compounds having a single esterified radical (hereinafter "monoester quats"). Where such a mixture of quats is used, the reaction is between the smectite clay and the quat mixture. The diester quat may be present at greater than 55 wt.% of the quaternary mixture; and any triester quat may be less than 25 wt.%, with the fatty acids corresponding to the esters in the mixture having a degree of unsaturation such that the iodine value may be from about 20 to about 90.
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8.
公开(公告)号:CA2388462A1
公开(公告)日:2001-04-26
申请号:CA2388462
申请日:2000-10-20
Applicant: SOUTHERN CLAY PROD INC
Inventor: GADBERRY JAMES F , POWELL CLOIS E , HOEY MICHAEL
Abstract: Organoclays based on specific types of ester quats may be remarkably effecti ve for use in preparing nanocomposites. These organoclays may comprise the reaction product of a smectite clay and a quaternary ammonium compound (or "quat") which may comprise two esterified radicals (hereinafter called a "diester quat"). The diester quat may be present in admixture with further quaternary ammonium compounds having esterified radicals, especially compoun ds having three esterified radicals (hereinafter "triester quats"); or compound s having a single esterified radical (hereinafter "monoester quats"). Where su ch a mixture of quats is used, the reaction is between the smectite clay and th e quat mixture. The diester quat may be present at greater than 55 wt.% of the quaternary mixture; and any triester quat may be less than 25 wt.%, with the fatty acids corresponding to the esters in the mixture having a degree of unsaturation such that the iodine value may be from about 20 to about 90.
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公开(公告)号:CA2230585A1
公开(公告)日:1997-03-13
申请号:CA2230585
申请日:1996-09-06
Applicant: SOUTHERN CLAY PROD INC
Inventor: ORTIZ JOE A , POWELL CLOIS E , BAUER CARL J , BOOTHE JOHN D , DENNIS HARRY RYAN
Abstract: Organoclay compositions which comprise the reaction product of a smectite-type clay having an ion exchange capacity of at least 50 meq. wt. per 100 g. clay (active basis), and an alkoxylated quaternary ammonium compound having one or two alkoxylated chains containing 0-10 moles ethylene oxide and 3-15 moles of propylene or butylene oxide residues are useful thixotropic materials, especially for the preparation of aqueous systems such as latex paint formulations.
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公开(公告)号:GB2408048A
公开(公告)日:2005-05-18
申请号:GB0423609
申请日:2004-10-25
Applicant: SOUTHERN CLAY PROD INC
Inventor: POWELL CLOIS E
IPC: C08C4/00 , C08J3/24 , C08J3/28 , C08J5/10 , C08K3/34 , C08K5/17 , C08K9/04 , C08K9/10 , C08K11/00 , C08L9/02 , C08L15/00 , C08L21/00
Abstract: A method of preparing rubbers containing organoclays comprises curing an organoclay-rubber composition in which the organoclay is dispersed in a rubber polymer, the composition being substantially free of carbon black, silica, and silica-treated carbon black. The rubber may be nitrile rubber and the organoclay may be montmorillonite, hectorite, saponite, attapulgite, beidellite, stevensite, sauconite, nontronite, sepiolite, or Laponite (RTM). The organoclay-rubber composition may be formed by combining a clay with a rubber polymer, which is then combined with an onium ion. The onium ion may be a multi-charged ion or may comprise an ammonium ion. Activators, accelerators, and vulcanising agents may also be included in the composition. A rubber formed by the method is also disclosed.
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