PROCESS FOR THE PREPARATION OF CROSS-LINKED POLYURETHANES

    公开(公告)号:DE2964773D1

    公开(公告)日:1983-03-24

    申请号:DE2964773

    申请日:1979-03-03

    Applicant: STAMICARBON

    Abstract: The invention concerns the production of crosslinked polyurethane, obtained by reacting one or more polyols and at least one trifunctional crosslinking hydroxyl compound with a polyisocyanate. Products of improved quality, especially strength and heat resistance, are obtained by using tris( beta -hydroxypropyl)isocyanurate or its ethoxylated derivative as crosslinking compound and at least one polymeric polyol, with optionally also a low molecular weight diol, as the other hydroxy compounds. Elastomers as well as foams can be prepared. The process can be carried out by reacting all components together or by prereacting the polyisocyanate with part of the hydroxyl compounds and next adding the remainder.

    PREPARATION OF TRIS-(BETA-HYDROXYPROPYL) ISOCYANURATE

    公开(公告)号:DE2967033D1

    公开(公告)日:1984-07-12

    申请号:DE2967033

    申请日:1979-01-20

    Applicant: STAMICARBON

    Abstract: The invention concerns a process for the preparation of tris-( beta -hydroxypropyl)-isocyanurate through reaction of propylene oxide with cyanuric acid. According to the invention the reaction is effected in a polyol, which is liquid under the process conditions and in which tris-( beta -hydroxypropyl)-isocyanurate is soluble or miscible, in the absence of a catalyst. Preferably a polyol is used which may be used in admixture with tris-( beta -hydroxypropyl)-isocyanurate in polyurethane synthesis. The advantages of the process are that the propoxylation does not proceed too far, and that there is no need to remove catalyst residues or solvent.

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