Removing residual monomers from nitrile copolymer aq. suspension

    公开(公告)号:IT1166904B

    公开(公告)日:1987-05-06

    申请号:IT2552779

    申请日:1979-09-06

    Abstract: Residual monomer is steam extracted from an aq. suspension of a resin at 100-135 degrees C and 0.35-2.1 kg/cm2 pressure, the resin having been prepd. by free radical polymerisation of an aq. suspension of a mixt. of (A) \-50 wt. % of a nitrile monomer of formula CH2=C(R)CN, where R is H, 1-4C alkyl or halogen and (B) \-1 of (1) styrene, (2) esters of formula CH2=C(R1)COOR2 where R1 is H, 1-4C alkyl or halogen, and R2 is 1-6C alkyl, (3) alpha-olefins of formula CH2=C(R')(R"), where R' and R" are 1-7C alkyl, (4) vinyl ethers comprising (m)ethyl, propyl and butyl vinyl ethers, (5) vinyl acetate and (6) indene. Pref. (A) is acrylonitrile and (B) is styrene or methyl acrylate.

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