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公开(公告)号：US3875220A
公开(公告)日：1975-04-01
申请号：US40530973
申请日：1973-10-11
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
IPC: B01J23/28 , B01J23/30 , B01J23/31 , B01J23/88 , B01J23/887 , B01J23/888 , B01J27/199 , C07C51/25 , C07C57/055 , C07C57/04 , C07C51/30
CPC classification number: B01J23/8878 , B01J23/002 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/8877 , B01J23/8885 , B01J27/199 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/51 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/67 , B01J2523/14 , B01J2523/847 , B01J2523/24 , B01J2523/397 , B01J2523/845 , B01J2523/28 , B01J2523/54 , B01J2523/822 , B01J2523/3712 , B01J2523/53 , B01J2523/18 , B01J2523/17 , B01J2523/43
Abstract: Catalysts containing phosphorus, vanadium and molybdenum have been found to be especially effective for the oxidation of methacrolein with molecular oxygen to obtain methacrylic acid. The catalysts may be optionally promoted with Bi, As, B, Ce, Cr, Ag, Fe, W, Pb, Mn, Tl, Te, Ni, Nb, B, Sn and/or Cu.
Abstract translation: 已经发现含有磷，钒和钼的催化剂对于用分子氧氧化甲基丙烯醛特别有效，以获得甲基丙烯酸。 可以任选地用Bi，As，B，Ce，Cr，Ag，Fe，W，Pb，Mn，Tl，Te，Ni，Nb，B，Sn和/或Cu来促进催化剂。
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公开(公告)号：AT357510B
公开(公告)日：1980-07-10
申请号：AT583076
申请日：1976-08-05
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
IPC: B01J27/18 , B01J21/16 , B01J23/16 , B01J23/88 , B01J27/00 , B01J27/186 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/04 , C07C57/055 , C07C67/00
Abstract: Catalysts containing the oxides of molybdenum and phosphorus promoted with rubidium and at least one element selected from the group consisting of As, Cd, In, Sn, Tl, K, Ca, V, U, Ce, W, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co, and Cu have been found to be especially desirable in the vapor phase oxidation of acrolein and methacrolein with molecular oxygen to yield acrylic acid and methacrylic acid respectively. The reaction of methacrolein gives an especially pure product in high yields and selectivities of methacrylic acid.
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公开(公告)号：ATA582976A
公开(公告)日：1980-05-15
申请号：AT582976
申请日：1976-08-05
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
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公开(公告)号：CS196317B2
公开(公告)日：1980-03-31
申请号：CS532676
申请日：1976-08-16
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
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5.发明专利
公开(公告)号：PT65454B
公开(公告)日：1978-02-10
申请号：PT6545476
申请日：1976-08-09
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
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Patent Agency Ranking
公开(公告)号：RO69968A
公开(公告)日：1981-06-26
申请号：RO8721776
申请日：1976-08-05
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
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公开(公告)号：CS196318B2
公开(公告)日：1980-03-31
申请号：CS532776
申请日：1976-08-16
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
IPC: B01J27/18 , B01J21/16 , B01J23/16 , B01J23/88 , B01J27/00 , B01J27/186 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/04 , C07C57/055 , C07C67/00 , C07C57/05
Abstract: Catalysts containing the oxides of molybdenum and phosphorus promoted with rubidium and at least one element selected from the group consisting of As, Cd, In, Sn, Tl, K, Ca, V, U, Ce, W, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co, and Cu have been found to be especially desirable in the vapor phase oxidation of acrolein and methacrolein with molecular oxygen to yield acrylic acid and methacrylic acid respectively. The reaction of methacrolein gives an especially pure product in high yields and selectivities of methacrylic acid.
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公开(公告)号：CA1059532A
公开(公告)日：1979-07-31
申请号：CA258069
申请日：1976-07-29
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
IPC: B01J23/24 , B01J27/00 , B01J27/19 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C57/04
Abstract: PROCESS FOR THE PREPARATION OF UNSATURATED ACIDS FROM UNSATURATED ALDEHYDES Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, and promoted with chromium or at least one element selected from the group consisting of thallium, rubidium, cesium, potassium, titanium and arsenic, or a mixture thereof, wherein at least part of the molybdenum employed in the preparation of the catalyst is supplied in the form of molybdenum trioxide. The oxidation of methacrolein in the presence of a catalyst wherein all the molybdenum employed in the preparation of the catalyst has been supplied by molybdenum trioxide gives especially desirable high yields and selectivities to methacrylic acid.
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公开(公告)号：CS199275B2
公开(公告)日：1980-07-31
申请号：CS198276
申请日：1976-03-26
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R , GRAESSELLI ROBERT K , SURESH DEV DHANARAJ
IPC: B01J27/198 , B01J23/30 , B01J23/34 , B01J23/652 , B01J23/68 , B01J23/88 , B01J23/888 , B01J27/00 , B01J27/199 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C57/04
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公开(公告)号：CA1072072A
公开(公告)日：1980-02-19
申请号：CA258778
申请日：1976-08-10
Applicant: STANDARD OIL CO OHIO
Inventor： WHITE JAMES F , REGE JAMES R
IPC: B01J27/18 , B01J21/16 , B01J23/16 , B01J23/88 , B01J27/00 , B01J27/186 , C07B61/00 , C07C51/00 , C07C51/25 , C07C57/04 , C07C57/055 , C07C67/00 , B01J23/00
Abstract: Catalysts containing the oxides of molybdenum and phosphorus promoted with rubidium and at least one element selected from the group consisting of As, Cd, In, Sn, Tl, K, Ca, V, U, Ce, W, Ni, Zr, Ba, Fe, Rh, Mn, Re, Ru, Co, and Cu have been found to be especially desirable in the vapor phase oxidation of acrolein and methacrolein with molecular oxygen to yield acrylic acid and methacrylic acid respectively. The reaction of methacrolein gives an especially pure product in high yields and selectivities of methacrylic acid.
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