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    IONICALLY POLYMER-BOUND TRANSITION METAL COMPLEX FOR PHOTOCHEMICAL CONVERSION OF LIGHT ENERGY
    3.
    发明专利
    IONICALLY POLYMER-BOUND TRANSITION METAL COMPLEX FOR PHOTOCHEMICAL CONVERSION OF LIGHT ENERGY 未知

    公开(公告)号：CA1251771A

    公开(公告)日：1989-03-28

    申请号：CA484295

    申请日：1985-06-18

    Applicant: STANDARD OIL CO OHIO

    Inventor： GIORDANO PAUL J JR ,  SMIERCIAK RICHARD C

    IPC: B01J31/22 ,  B01J19/12 ,  B01J31/08 ,  B01J31/16 ,  B01J31/18 ,  C07C5/31 ,  C09K9/00 ,  B01J31/06 ,  F24J2/00

    Abstract: \\ Novel catalyst for the photochemical conversion and storage of radiant energy through the conversion of strained cyclic non-conjugated carbon containing compounds to their corresponding conjugated forms comprises ionically bonding a transition metal complex having a square planar geometry and multiple sites of coordination with an anionexchange resin. A method is provided for the preparation of the novel catalyst and comprises forming an acid salt derivative of the transition metal complex and mixing it together with an anion-exchange resin. A process wherein the novel catalyst is added to a strained cyclic non-con-jugated carbon containing compound resulting in the release of heat energy through the conversion of the non-conjugated carbon containing compound to its conjugated form. A process and sealed container means wherein the nonconjugated carbon containing compound and the catalyst are in compartments and are separated until heat energy is required. The means of separation is then broken and the non-conjugated carbon containing compound is converted to the conjugated form with the release of heat energy. A process and apparatus wherein the conjugated carbon containing compound is exposed to radiant energy and is converted to the non-conjugated form. The non-conjugated form is then combined with the catalyst described hereinabove, converting the non-conjugated form to the conjugated form and resulting in the release of heat energy which is collected.

    PROCESS FOR MAKING AN ACRYLONITRILE/METHACRYLONITRILE COPOLYMER
    8.
    发明专利
    PROCESS FOR MAKING AN ACRYLONITRILE/METHACRYLONITRILE COPOLYMER 未知

    公开(公告)号：CA2134825A1

    公开(公告)日：1995-05-11

    申请号：CA2134825

    申请日：1994-11-01

    Applicant: STANDARD OIL CO OHIO

    Inventor： SMIERCIAK RICHARD C ,  WARDLOW EDDIE JR ,  BALL LAWRENCE E

    IPC: C08F220/44

    Abstract: Title: A PROCESS FOR MAKING AN ACRYLONITRILE/METHACRYLONITRILE COPOLYMER A process for making acrylonitrile/methacrylonitrile copolymer, comprising polymerizing a mixture of acrylonitrile monomer and methacrylonitrilemonomer in which the rate of addition of the comonomers is at by the sate of polymerization so that the concentration of unreacted acrylonitrile monomer and unreacted methacrylonitrile monomer is low and the polymerization process is in a starved condition.

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