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公开(公告)号：CA2187414A1
公开(公告)日：1997-06-19
申请号：CA2187414
申请日：1996-10-08
Applicant: STANDARD OIL CO OHIO
Inventor： JORKASKY RICHARD J II , BALL LAWRENCE E , WU MUYEN M , UEBELE CURTIS E
Abstract: The present invention relates to fibers produced by melt spinning of high nitrile multipolymers. The fibers are prepared in a solventless, waterless, melt spinning process. The melt spun high nitrile fiber is made from a high nitrile melt processable multipolymer comprising about 50% to about 95% by weight polymerized acrylonitrile monomer and 5% to about 50% by weight of a polymerized olefinically unsaturated monomer. A process for the production of the fibers is disclosed which comprises (a) melt extruding a high nitrile multipolymer in the absence of a solvent and in the absence of water and (b) spinning the high nitrile polymer melt into a high nitrile filament at a temperature higher than the glass transition temperature of the multipolymer and (c) collecting the monofilament or the multiple filament as a fiber bundle.
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公开(公告)号：AU7532096A
公开(公告)日：1997-06-26
申请号：AU7532096
申请日：1996-12-12
Applicant: STANDARD OIL CO OHIO
Inventor： JORKASKY RICHARD J II , BALL LAWRENCE E , WU MUYEN M , UEBELE CURTIS E
Abstract: A process for the production of high nitrile fibres comprising 50-95% by weight polymerised acrylonitrile monomer and 5-50% by weight of at least one polymerised olefinically unsaturated monomer is disclosed, in which the high nitrile multipolymer is melt extruded in the absence of solvent and water, and the resultant melt spun into a high nitrile filament at a temperature higher than the glass transition temperature of the multipolymer, with the monofilament or multiple filaments being collected as a bundle, web or combinations thereof.
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公开(公告)号：CA1058795A
公开(公告)日：1979-07-17
申请号：CA241522
申请日：1975-12-11
Applicant: STANDARD OIL CO OHIO
Inventor： UEBELE CURTIS E , WARDLOW EDDIE JR
IPC: C08L33/00 , C08F279/02 , C08K5/1535 , C08K5/3417 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/02 , C08L33/18 , C08L51/00 , C08L51/02 , C08L51/04 , C08L101/00 , C08K5/00
Abstract: of the disclosure Nitrile copolymers and graft copolymers containing a high proportionate amount of olefinic nitrile are stabilized against thermal color degradation by inclusion into the polymer minor amounts of a compound having the formula: and/or wherein "X" may be oxygen; an imide groups, -NH? or an N-substituted imide group, -NR- wherein "R" may be an alkyl, or a phenyl alkyl group containing from 1 to 8 carbon atoms; "Y" may be an oxygen or a methylene group; and "Z" may be hydrogen or an alkyl group containing from 1 to 8 carbon atoms.
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公开(公告)号：TR9600945A2
公开(公告)日：1997-07-21
申请号：TR9600945
申请日：1996-11-27
Applicant: STANDARD OIL CO OHIO
Inventor： II RICHARD J JORKASKY , BALL LAWRENCE E , WU MUYEN M , UEBELE CURTIS E
CPC classification number: D01F6/40 , D01F6/18 , D01F6/38 , Y10T428/2904 , Y10T428/2913 , Y10T428/2933 , Y10T428/2967
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Patent Agency Ranking
公开(公告)号：TR199600945A2
公开(公告)日：1997-07-21
申请号：TR9600945
申请日：1996-11-27
Applicant: STANDARD OIL CO OHIO
Inventor： II RICHARD J JORKASKY , BALL LAWRENCE E , WU MUYEN M , UEBELE CURTIS E
Abstract: A process for the production of high nitrile fibres comprising 50-95% by weight polymerised acrylonitrile monomer and 5-50% by weight of at least one polymerised olefinically unsaturated monomer is disclosed, in which the high nitrile multipolymer is melt extruded in the absence of solvent and water, and the resultant melt spun into a high nitrile filament at a temperature higher than the glass transition temperature of the multipolymer, with the monofilament or multiple filaments being collected as a bundle, web or combinations thereof.
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公开(公告)号：CA1144696A
公开(公告)日：1983-04-12
申请号：CA366032
申请日：1980-12-03
Applicant: STANDARD OIL CO OHIO
Inventor： BENTON KENNETH C , UEBELE CURTIS E , WHITE JAMES F , WEINERT RAYMOND J JR
Abstract: This invention relates to a process for polymerizing alpha-olefins in the presence of a Ziegler-type catalyst wherein at least one of dichloroethane, dichloropropane and chlorine gas is added to the process after the polymerization has been initiated. This invention is especially useful when the olefin is propylene and the catalyst is a titanium trichloride complex.
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公开(公告)号：AU716405B2
公开(公告)日：2000-02-24
申请号：AU7532096
申请日：1996-12-12
Applicant: STANDARD OIL CO OHIO
Inventor： JORKASKY RICHARD J II , BALL LAWRENCE E , WU MUYEN M , UEBELE CURTIS E
Abstract: A process for the production of high nitrile fibres comprising 50-95% by weight polymerised acrylonitrile monomer and 5-50% by weight of at least one polymerised olefinically unsaturated monomer is disclosed, in which the high nitrile multipolymer is melt extruded in the absence of solvent and water, and the resultant melt spun into a high nitrile filament at a temperature higher than the glass transition temperature of the multipolymer, with the monofilament or multiple filaments being collected as a bundle, web or combinations thereof.
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公开(公告)号：CA1077187A
公开(公告)日：1980-05-06
申请号：CA245582
申请日：1976-02-12
Applicant: STANDARD OIL CO OHIO
Inventor： UEBELE CURTIS E , VALUS RONALD J
IPC: C08F279/00 , C08F279/04
Abstract: IMPACT-RESISTANT ACRYLONITRILE COPOLYMER PROCESS The process for copolymerization of styrene and acrylonitrile in the presence of a diolefin elastomer in high conversion to polymers having superior impact resistance and other excellent physical properties by the careful control of the percent unrealized total solids during the early stages of the copolymerization is described.
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公开(公告)号：CA964789A
公开(公告)日：1975-03-18
申请号：CA116284
申请日：1971-06-22
Applicant: STANDARD OIL CO OHIO
Inventor： UEBELE CURTIS E , GRIFFITH RUSSELL K , ROSEN IRVING
IPC: C08F2/22 , C08F279/02
Abstract: 1352437 Graft polymers STANDARD OIL CO 24 June 1971 [22 Sept 1970] 29631/71 Heading C3G A resinous polymer is produced by polymerization of 100 parts by weight of (A) an olefinically unsaturated nitrile of structure wherein R represents hydrogen, a C 1 to C 4 -alkyl group or a halogen, (B) 0À5 to 10 moles per mole of (A) of a vinyl or vinylidene aromatic monomer and (C) 0À2 to 2À5 moles per mole of (A) of maleimide in the presence of from 1 to 20 parts of a conjugated diolefin elastomer. Examples are given in which styrene, acrylonitrile and maleimide are polymerized in an aqueous emulsion containing polybutadiene or butadienestyrene copolymer.
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