公开(公告)号：KR810000516B1

公开(公告)日：1981-05-25

申请号：KR770002412

申请日：1977-10-08

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW W ,  WHITE J

IPC: C07C51/145 ,  C07C57/04

Abstract: Olefinic aldehydes were oxidized to olefinic acids such as methacrolein, acrolein to methacrylic acid acrylic acid, at 200-500≦̸C over mixed oxide catalysts contg. Mo, P, As and Cu. Thus, a 1:5.7:4.6:8.6 (molar) mixt. of methacrolein, air, N, and steam was passed at a 2-sec-residence time through a tube heated at 354≦̸C and contg. the mixed oxide catalyst on an Alundum support to give methacrylic acid in 93.8% yield.

公开(公告)号：KR800001329B1

公开(公告)日：1980-10-28

申请号：KR770001516

申请日：1977-06-30

Applicant: STANDARD OIL CO OHIO

Inventor： APPLEQUIST M ,  WHITE J

IPC: C07C51/32

Abstract: Methacrolein or acrolein was oxidized to methacrylic and acrylic acid at 200-500≦̸C under vapor atm. with a total conversion of aldehyde

公开(公告)号：KR800001473B1

公开(公告)日：1980-12-17

申请号：KR760000667

申请日：1976-03-19

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI R ,  WHITE J ,  REGE J

IPC: C07C57/04

Abstract: Acrylic acid and methacrylic acid were prepd. by catalytic oxdn. by O2 of acrolein and methacrolein at 200-600↿C over WaPbVcMo12Ox catalyst (a,c = 0.1-12; b =

公开(公告)号：KR800000622B1

公开(公告)日：1980-07-07

申请号：KR770002413

申请日：1977-10-18

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE J ,  APPLEQUIST M ,  SHAW W

IPC: B01J27/18

Abstract: Metharylic acid (I) was prepd. from methacrolein(II) by oxidn. with mo1. 0 at 200-600≦̸C in the presence of a catalyst contg. an oxide of W,P,U,Mo, and Co, Rn, Cd, Sr. An aq. slurry of MoO3 86.2, 85 % H3Po4 7.7, V2O3 7.5, and NH4 paratungstate 10.8 was refluxed overnight, evapd., and dried overnight at 120≦̸C to prepare a catalyst giving 65.9 % conversion and 45.4 % selectivity in the oxidn. of II to I at 355≦̸C and contact time 4.8s.

公开(公告)号：IN144956B

公开(公告)日：1978-08-05

申请号：IN366CA1976

申请日：1976-02-27

Applicant: STANDARD OIL CO OHIO

Inventor： SURESH DEV DHANARAJ ,  REGE J ,  WHITE J ,  GRASSELLI R

IPC: B01J27/198 ,  B01J23/30 ,  B01J23/34 ,  B01J23/652 ,  B01J23/68 ,  B01J23/88 ,  B01J23/888 ,  B01J27/00 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

公开(公告)号：IN145503B

公开(公告)日：1978-10-28

申请号：IN1301CA1976

申请日：1976-07-20

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE J ,  REGE J

IPC: B01J23/24 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C51/16 ,  C07C57/04