THE CATZLYST COMPOSITION FOR THE PREPARATION OF UNSATURATED ACID FROM UNSATURATED ALDEHYDES

    公开(公告)号:KR790001027B1

    公开(公告)日:1979-08-21

    申请号:KR760001973

    申请日:1976-08-13

    Inventor: WHITE J F REGE J R

    Abstract: Methacrylic acid was prepd. by the oxidn of methacrolein by air at 288-371≦̸C over mixed oxide catalysts A0.05 Rb0.5 Mo3 P0.33 Ox (A= one or more of As, K, Ca, Cd, V, U, Ce, W, Ni, Zr, Ba, Fe, In, Tl, Rh, Sn, Mn, Re, Ru, Co or Cu; x=a no. detd. by the valence and nox. of other atoms present). Total conversion, signale pass yields and selectivities were 47.7-100, 13.6-69.5 and 28.5-82.1% resp.. Thus, with In0.05 Rb1.5 Mo3 P0.33 On at 243≦̸C, total conversion of aldehyde was 85.5%, with a signal pass yield of 62.0% and selectivity to methacrylic acid of 71.3%

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