公开(公告)号：EP0164789A3

公开(公告)日：1986-01-02

申请号：EP85200788

申请日：1985-05-15

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Band, Elliot Isaac ,  Breen, Michael Joseph

IPC: C08F10/00 ,  C08F04/64

CPC classification number: C08F10/00 ,  C08F4/6425

Abstract: Isotactic index improvement is achieved for C 3 and higher alpha olefins in systems containing a catalyst component comprising titanium supported on a magnesium halide support. The titanium component is formed by copulverizing the magnesium halide with one or more electron donorsfollowed bytreatmentwith liquidtitanium halide. The improvement is achieved by using a dialkylaluminum alkyl phenoxide component with the trialkylaluminum co- catalyst normally used. In slurry polymerizations, the isotactic index of the polymer has been improved. It is possible to achieve a variable melt flow index for polypropylene while maintaining good isotactic index. Isotactic index is retained at high levels even though the temperature and/or time of polymerization is varied.

公开(公告)号：EP0113937A1

公开(公告)日：1984-07-25

申请号：EP83201813.9

申请日：1983-12-19

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Band, Elliot Isaac

IPC: C08F10/00 ,  C08F4/62

CPC classification number: C08F10/00 ,  C08F4/6348 ,  C08F4/6341 ,  C08F4/695

Abstract: An unmilled catalytic component for polymerizing olefins with high activity to yield polymers with high stereoregularity and a narrow particle size distribution with a low weight percentage of small particles comprises a solid, unmilled support containing magnesium-halogen bonds, a transition metal halide of a metal selected from Groups IVB and VB of the periodic table, and electron donors.
This catalytic component is obtained by steps comprising:

(a) contacting a Mg(OR) 2 and/or Mn(OR) 2 compound with a Ti(OR) 4 compound to comprise a liquid, where R is a hydrocarbyl or halogenated hydrocarbyl moiety containing 1 to 20 carbon atoms or a halogen,
(b) reacting the liquid with a fluid comprising a halogenating agent and treatment with an electron donor to form a treated solid, and
(c) post-treating the solid with a transition metal halide.

公开(公告)号：EP0164789A2

公开(公告)日：1985-12-18

申请号：EP85200788.9

申请日：1985-05-15

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Band, Elliot Isaac ,  Breen, Michael Joseph

IPC: C08F10/00 ,  C08F4/64

CPC classification number: C08F10/00 ,  C08F4/6425

Abstract: Isotactic index improvement is achieved for C 3 and higher alpha olefins in systems containing a catalyst component comprising titanium supported on a magnesium halide support. The titanium component is formed by copulverizing the magnesium halide with one or more electron donorsfollowed bytreatmentwith liquidtitanium halide. The improvement is achieved by using a dialkylaluminum alkyl phenoxide component with the trialkylaluminum co- catalyst normally used. In slurry polymerizations, the isotactic index of the polymer has been improved. It is possible to achieve a variable melt flow index for polypropylene while maintaining good isotactic index. Isotactic index is retained at high levels even though the temperature and/or time of polymerization is varied.

Abstract translation: 在包含负载在卤化镁载体上的钛的催化剂组分的体系中，C3和更高级α-烯烃的全同立构指数得到改善。 钛组分通过将卤化镁与一种或多种电子给体共混形成，然后用液体卤化钛处理。 通过使用通常使用的三烷基铝助催化剂的二烷基铝烷基酚盐组分来实现改进。 在浆料聚合中，聚合物的全同立构指数得到改善。 可以实现聚丙烯的可变熔体流动指数，同时保持良好的全同立构指数。 即使温度和/或聚合时间变化，全同立构指数保持在高水平。

公开(公告)号：EP0113936A1

公开(公告)日：1984-07-25

申请号：EP83201812.1

申请日：1983-12-19

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Band, Elliot Isaac

IPC: C08F10/00 ,  C08F4/62

CPC classification number: C08F10/00 ,  C08F4/6357 ,  C08F4/6346 ,  C08F4/636

Abstract: This invention comprises a catalytic component for polymerizing olefins comprising a solid support containing magnesium-halogen bonds, a transition metal halide of a metal selected from Groups IVB and VB of the periodic table, and an electron donor obtained by the steps comprising:

(a) reacting an organometallic compound whose metal comprise members of Groups I to III of the periodic table with an alcohol, ROH, where R is an alkyl, cycloalkyl, or arylalkyl moiety having 1 to 16 carbon atoms, a polysiloxane, and a transition metal halide to form a solid;
(b) treating the solid with a transition metal halide optionally int he presence of a polysiloxane to form a treated solid; and
(c) reacting the treated solid with an electron donor and a transition metal halide to form the component.

Abstract translation: 本发明包括用于聚合烯烃的催化组分，其包含含有镁 - 卤键的固体载体，选自元素周期表第IVB和VB族的金属的过渡金属卤化物和通过以下步骤获得的电子供体：（a） 使其金属包含元素周期表第I至III族成员的有机金属化合物与醇ROH（其中R为具有1至16个碳原子的烷基，环烷基或芳烷基部分），聚硅氧烷和过渡金属卤化物反应以 形成坚实的; （b）任选在聚硅氧烷存在下用过渡金属卤化物处理固体以形成处理的固体; 和（c）使处理过的固体与电子供体和过渡金属卤化物反应以形成组分。

公开(公告)号：EP0132893A1

公开(公告)日：1985-02-13

申请号：EP84201080.3

申请日：1984-07-20

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Band, Elliot Isaac ,  Breen, Michael Joseph ,  Mink, Robert Ivan ,  Via, Francis Anthony

IPC: C08F10/00 ,  C08F4/64

CPC classification number: C08F10/00 ,  C08F4/6425

Abstract: @ Isotactic index improvement is achieved for C 3 and higher alpha olefins in systems containing a catalyst component comprising titanium supported on a magnesium halide support. The titanium component is formed by copulverizing the magnesium halide with one or more eletron donor followed by treatment with liquid titanium halide. The improvement is achieved by using a dialkylaluminum monohalide component with the trialkylaluminum cocatalyst normally used. In non- slurry polymerizatins improvements in both activity and isotactic index have been achieved. In slurry polymerizations, the isotactic index of the polymer has been improved. It is possible to achieve a variable melt flow index for polypropylene while maintaining good isotactic index. Isotactic index is retained at high levels even though the temperature and/or time of polymerization is varied.

Abstract translation: 在包含负载在卤化镁载体上的钛的催化剂组分的体系中，C3和更高级α-烯烃的全同立构指数得到改善。 钛组分通过使卤化镁与一种或多种电子给体共同形成，然后用液体卤化钛处理。 通过使用二烷基铝一卤化物与通常使用的三烷基铝助催化剂来实现改进。 在非淤浆聚合物中，活性和全同立构指数均有所改善。 在浆料聚合中，聚合物的全同立构指数得到改善。 可以实现聚丙烯的可变熔体流动指数，同时保持良好的全同立构指数。 即使温度和/或聚合时间变化，全同立构指数保持在高水平。

公开(公告)号：EP0113938A1

公开(公告)日：1984-07-25

申请号：EP83201814.7

申请日：1983-12-19

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Band, Elliot Isaac

IPC: C08F10/00 ,  C08F4/62

CPC classification number: C08F10/00 ,  C08F4/6581 ,  C08F4/6345

Abstract: A catalytic component for polymerizing olefins comprises a solid support containing magnesium-halogen or manganese-halogen bonds, a transition metal halide of a metal selected from Groups IVB and VB of the periodic table, and electron donors. This catalytic component is obtainable by steps comprising:

(a) contacting a mixture comprising a magnesium halide or manganese halide and at least one electron donor with a Ti(OR) 4 compound to form a solution, where R is a hydrocarbyl or halogenated hydrocarbyl moiety containing 1 to 20 carbon atoms or a halogen, and
(b) reacting the solution with a reagent comprising a transition metal halide selected from Groups IVB and VB of the periodic table,

whereby, with a suitable cocatalyst, polyolefin is formed with high activity, showing a high Isotactic Index, and with a narrow range of particle size distribution.