公开(公告)号：EP0101136A2

公开(公告)日：1984-02-22

申请号：EP83201177.9

申请日：1983-08-08

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Mink, Robert Ivan

IPC: C08F10/00 ,  C08F4/64

CPC classification number: C08F10/00 ,  C08F4/6565 ,  C08F4/695

Abstract: A novel catalytic system for polymerizing olefins comprises:

a) a cocatalytic component containing an organometallic compound of Groups I-III of the periodic table, and
b) a catalytic component containing titanium obtained by:
(i) copulverising a substantially anhydrous magnesium compound containing halogen or manganese compound containing halogen with: a phenol, an organic polymer containing silicon, a titanium halide and an electron-donor compound to produce a copulverized product, and
(ii) reacting the copulverized product with a liquid titanium compound containing halogen.

The invention also encompasses the novel catalytic component, processes for preparing the catalytic component containing titanium, and the use of the novel catalytic system for polymerizing olefins.

公开(公告)号：EP0101136A3

公开(公告)日：1984-09-26

申请号：EP83201177

申请日：1983-08-08

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Mink, Robert Ivan

IPC: C08F10/00 ,  C08F04/64

CPC classification number: C08F10/00 ,  C08F4/6565 ,  C08F4/695

Abstract: A novel catalytic system for polymerizing olefins comprises:
a) a cocatalytic component containing an organometallic compound of Groups I-III of the periodic table, and b) a catalytic component containing titanium obtained by: (i) copulverising a substantially anhydrous magnesium compound containing halogen or manganese compound containing halogen with: a phenol, an organic polymer containing silicon, a titanium halide and an electron-donor compound to produce a copulverized product, and (ii) reacting the copulverized product with a liquid titanium compound containing halogen. The invention also encompasses the novel catalytic component, processes for preparing the catalytic component containing titanium, and the use of the novel catalytic system for polymerizing olefins.

公开(公告)号：EP0132893A1

公开(公告)日：1985-02-13

申请号：EP84201080.3

申请日：1984-07-20

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Band, Elliot Isaac ,  Breen, Michael Joseph ,  Mink, Robert Ivan ,  Via, Francis Anthony

IPC: C08F10/00 ,  C08F4/64

CPC classification number: C08F10/00 ,  C08F4/6425

Abstract: @ Isotactic index improvement is achieved for C 3 and higher alpha olefins in systems containing a catalyst component comprising titanium supported on a magnesium halide support. The titanium component is formed by copulverizing the magnesium halide with one or more eletron donor followed by treatment with liquid titanium halide. The improvement is achieved by using a dialkylaluminum monohalide component with the trialkylaluminum cocatalyst normally used. In non- slurry polymerizatins improvements in both activity and isotactic index have been achieved. In slurry polymerizations, the isotactic index of the polymer has been improved. It is possible to achieve a variable melt flow index for polypropylene while maintaining good isotactic index. Isotactic index is retained at high levels even though the temperature and/or time of polymerization is varied.

Abstract translation: 在包含负载在卤化镁载体上的钛的催化剂组分的体系中，C3和更高级α-烯烃的全同立构指数得到改善。 钛组分通过使卤化镁与一种或多种电子给体共同形成，然后用液体卤化钛处理。 通过使用二烷基铝一卤化物与通常使用的三烷基铝助催化剂来实现改进。 在非淤浆聚合物中，活性和全同立构指数均有所改善。 在浆料聚合中，聚合物的全同立构指数得到改善。 可以实现聚丙烯的可变熔体流动指数，同时保持良好的全同立构指数。 即使温度和/或聚合时间变化，全同立构指数保持在高水平。