公开(公告)号：EP0243972A2

公开(公告)日：1987-11-04

申请号：EP87106297.2

申请日：1987-04-30

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Baker, Don Robert ,  Brownell, Keith Harvey ,  Kezerian, Charles

IPC: C07D213/82 ,  C07D405/12 ,  A01N53/00

CPC classification number: C07D213/75 ,  A01N53/00 ,  C07D213/76 ,  C07D405/12 ,  C07F7/10

Abstract: Novel fungicidal pyridyl cyclopropane carboxamides having the general structural formula
wherein Z is
R is selected from the group consisting of cycloalkyl, preferably cyclopropyl, hydrogen, alkyl, haloalkyl, substituted alkyl, aryl, substituted aryl, heteroalkyl, alkenyl, OR 1 , SR, and
wherein n is 0-10, preferably 0-2, ad R 1 is C 1 -C 4 alkyl; R 2 is selected from the group consisting of halogen such as chlorine, fluorine and bromine, preferably chlorine, C 1 -C 3 alkoxy such as propoxy ethoxy and methoxy, preferably methoxy and C 1 -C 3 haloalkoxy; R 3 is selected from the group consisting of hydrogen and methyl; X is oxygen or sulfur and Y is oxygen or sulfur; or Z is SR 9 wherein R 9 is selected from the group consisting of haloalkyl, preferably C 1 -C 3 haloalkyl, C 1 -C 8 alkyl, aryl, substituted aryl, and arylalkyl wherein the preferred aryl is phenyl, the alkyl is C 1 -C 3 alkyl and the preferred substitutions are Cl, Br, F and nitro, alkanoyl, preferably C 1 -C 4 alkanoyl,
wherein R 4 and R 5 can be alkyl, alkanoyl, alkoxycarbonyl, benzyl, pyridyl and substituted pyridyl; provided that when Z is -SR 9 Y is oxygen; and fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.

Abstract translation: 具有通式结构式的新型杀真菌吡啶基环丙烷甲酰胺，其中Z为-R; R选自环烷基，优选环丙基，氢，烷基，卤代烷基，取代的烷基，芳基，取代的芳基，杂烷基，烯基，OR 1，SR 1和 - （CH 2）n R OR 1，其中n为0-10， 优选0-2，并且R 1是C 1 -C 4烷基; R 2选自卤素如氯，氟和溴，优选氯，C 1 -C 3烷氧基如丙氧基乙氧基和甲氧基，优选甲氧基和C 1 -C 3卤代烷氧基; R3选自氢和甲基; X是氧或硫，Y是氧或硫; 或Z是SR 9，其中R 9选自卤代烷基，优选C 1 -C 3卤代烷基，C 1 -C 8烷基，芳基，取代的芳基和芳烷基，其中优选的芳基是苯基，所述烷基是C 1 -C 3烷基，优选的 取代基是Cl，Br，F和硝基，烷酰基，优选C 1 -C 4烷酰基，其中R 4和R 5可以是烷基，烷酰基，烷氧基羰基，苄基，吡啶基和取代的吡啶基; 条件是当Z为-SR 9时，Y为氧; 及其杀真菌可接受的有机和无机盐，它们是用作预防和治疗性杀真菌剂的高效杀真菌剂。

公开(公告)号：EP0146238A1

公开(公告)日：1985-06-26

申请号：EP84307255.4

申请日：1984-10-22

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Kezerian, Charles ,  Ahle, James Leroy

IPC: A01N57/20

CPC classification number: A01N57/20 ,  A01N43/40 ,  A01N39/02 ,  A01N2300/00

Abstract: Synergistic herbicidal activity is demonstrated by composition comprising the following two components:

(a) an herbicidally effective amount of N-phosphonomethylglycine and agriculturally acceptable salts thereof; and
(b) an an herbicidally effective amount of an aryloxyphenoxy pentanoic acid ester of the formula
wherein A is CH or nitrogen, Y is hydrogen or chlorine, Z is selected from a member of the group consisting of
and R is hydrogen or a straight or branched chain lower alkyl group having from 1 to 4 carbon atoms.

Abstract translation: 通过包含以下两种组分的组合物证明协同除草活性：（a）除草有效量的N-膦酰基甲基 - 甘氨酸及其农业上可接受的盐; 和（b）除草有效量的式CHEM的芳氧基苯氧基戊酸酯，其中A是CH或氮，Y是氢或氯，Z选自和R 是氢或具有1至4个碳原子的直链或支链低级烷基。

公开(公告)号：EP0144137A1

公开(公告)日：1985-06-12

申请号：EP84307254.7

申请日：1984-10-22

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Kezerian, Charles ,  Ahle, James Leroy

IPC: A01N57/20

CPC classification number: A01N57/20 ,  A01N43/40 ,  A01N39/02 ,  A01N2300/00

Abstract: Synergistic herbicidal activity is demonstrated by composition comprising the following two components:

(a) N-phosphonomethylglycine and agriculturally acceptable salts thereof; and
(b) an aryloxyphenoxy propionic acid ester of the formula
wherein A is CH or nitrogen, Y is hydrogen or chlorine and R is hydrogen or a straight or branched chain lower alkyl group having from 1 to 4 carbon atoms.

Abstract translation: 通过包含以下两种组分的组合物证明协同除草活性：（a）N-膦酰基甲基甘氨酸及其农业上可接受的盐; 和（b）式CHEM的芳氧基苯氧基丙酸酯，其中A是CH或氮，Y是氢或氯，R是氢或具有1至4个碳原子的直链或支链低级烷基。

公开(公告)号：EP0243972A3

公开(公告)日：1989-03-22

申请号：EP87106297.2

申请日：1987-04-30

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Baker, Don Robert ,  Brownell, Keith Harvey ,  Kezerian, Charles

IPC: C07D213/82 ,  C07D405/12 ,  A01N53/00

CPC classification number: C07D213/75 ,  A01N53/00 ,  C07D213/76 ,  C07D405/12 ,  C07F7/10

Abstract: Novel fungicidal pyridyl cyclopropane carboxamides having the general structural formula
wherein Z is
R is selected from the group consisting of cycloalkyl, preferably cyclopropyl, hydrogen, alkyl, haloalkyl, substituted alkyl, aryl, substituted aryl, heteroalkyl, alkenyl, OR 1 , SR, and
wherein n is 0-10, preferably 0-2, ad R 1 is C 1 -C 4 alkyl; R 2 is selected from the group consisting of halogen such as chlorine, fluorine and bromine, preferably chlorine, C 1 -C 3 alkoxy such as propoxy ethoxy and methoxy, preferably methoxy and C 1 -C 3 haloalkoxy; R 3 is selected from the group consisting of hydrogen and methyl; X is oxygen or sulfur and Y is oxygen or sulfur; or Z is SR 9 wherein R 9 is selected from the group consisting of haloalkyl, preferably C 1 -C 3 haloalkyl, C 1 -C 8 alkyl, aryl, substituted aryl, and arylalkyl wherein the preferred aryl is phenyl, the alkyl is C 1 -C 3 alkyl and the preferred substitutions are Cl, Br, F and nitro, alkanoyl, preferably C 1 -C 4 alkanoyl,
wherein R 4 and R 5 can be alkyl, alkanoyl, alkoxycarbonyl, benzyl, pyridyl and substituted pyridyl; provided that when Z is -SR 9 Y is oxygen; and fungicidally acceptable organic and inorganic salts thereof which are highly effective fungicides for use both as preventive and curative fungicides are disclosed herein.