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公开(公告)号:WO2019074878A1
公开(公告)日:2019-04-18
申请号:PCT/US2018/054934
申请日:2018-10-09
Applicant: STEPAN COMPANY
Inventor: BOEBEL, Timothy A. , DONG, Xue Min , ROJAS, Carolina E. , LUKA, Renee , LUEBKE, Gary , KNOX, Paul W.
Abstract: Copolymers comprising recurring units of a phenyl glycidyl ether and alkylene oxides are disclosed. Some of the copolymers comprise a di- or polyfunctional nucleophilic initiator and recurring units of the phenyl glycidyl ether and an alkylene oxide. The di- or polyfunctional nucleophilic initiator is an alcohol, phenol, amine, thiol, thiophenol, sulfinic acid, or deprotonated species thereof. Other copolymers comprise a monofunctional nucleophilic initiator selected from thiols, thiophenols, aralkylated phenols, sulfinic acids, secondary amines, C10-C20 terpene alcohols, and deprotonated species thereof. Pigments dispersions comprising the copolymers are also disclosed. The copolymers meet the growing needs of the industry with their ease of manufacture, diverse structures, and desirable performance attributes for dispersing a wide range of organic and inorganic pigments. Agricultural applications for the copolymers are also disclosed.
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公开(公告)号:WO2020018356A1
公开(公告)日:2020-01-23
申请号:PCT/US2019/041520
申请日:2019-07-12
Applicant: STEPAN COMPANY
Inventor: MASTERS, Ronald A. , KNOCK, Mona Marie , WOLFE, Patrick Shane , BOEBEL, Timothy A. , DONG, Xue Min , MURPHY, Dennis S.
Abstract: Dilutable concentrates useful for hard surface cleaners with improved film/streak performance on high-energy surfaces are disclosed. The concentrates comprise a nonionic alkoxylated surfactant and a polyetheramine. A relatively minor proportion of a polyetheramine can resolve film/streak issues that characterize hard surface cleaners formulated with nonionic surfactants. The efficacy of polyetheramines for improving film/streak performance of hard surface cleaners formulated with nonionic alkoxylated surfactants far exceeds the benefits available from known improvements, such as the use of hydrotropes. Other inventive dilutable concentrates and hard surface cleaners comprise an amine-functional hydrophobe and an auxiliary surfactant. Still other dilutable concentrates or hard surface cleaners comprise a nonionic alkoxylated surfactant and lactic acid. An improved method for measuring film/streak properties of hard surface cleaners is also disclosed.
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公开(公告)号:EP4290224A2
公开(公告)日:2023-12-13
申请号:EP23205413.0
申请日:2019-07-12
Applicant: Stepan Company
Inventor: MASTERS, Ronald A. , KNOCK, Mona Marie , WOLFE, Patrick Shane , BOEBEL, Timothy A. , DONG, Xue Min , MURPHY, Dennis S.
IPC: G01N21/94
Abstract: Dilutable concentrates useful for hard surface cleaners with improved film/streak performance on high-energy surfaces are disclosed. The concentrates comprise a nonionic alkoxylated surfactant and a polyetheramine. A relatively minor proportion of a polyetheramine can resolve film/streak issues that characterize hard surface cleaners formulated with nonionic surfactants. The efficacy of polyetheramines for improving film/streak performance of hard surface cleaners formulated with nonionic alkoxylated surfactants far exceeds the benefits available from known improvements, such as the use of hydrotropes. Other inventive dilutable concentrates and hard surface cleaners comprise an amine-functional hydrophobe and an auxiliary surfactant. Still other dilutable concentrates or hard surface cleaners comprise a nonionic alkoxylated surfactant and lactic acid. An improved method for measuring film/streak properties of hard surface cleaners is also disclosed.
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公开(公告)号:EP4431532A2
公开(公告)日:2024-09-18
申请号:EP24192851.4
申请日:2020-03-05
Applicant: Stepan Company
Inventor: BOEBEL, Timothy A. , FARRIS, Samantha Michelle , LUEBKE, Gary , ROJAS, Carolina E. , SPAULDING, Chris , TERRY, Michael R. , WOLFE, Patrick Shane , ZAUG, Julia
IPC: C08F2/26
CPC classification number: C07C41/03 , C07C67/08 , C07D295/088 , C08F2/26 , C07F9/091 , C07C319/18
Abstract: Processes for making reactive surfactants are disclosed. In one such process, an alkyl- or alkenylsuccinic anhydride is reacted with an olefin-functional nucleophile to produce an olefin-functional succinate monoester. Surfactant compositions comprising the reactive surfactants made by these processes are also described. The invention includes polymerizable mixtures comprising an acrylic monomer and the surfactant compositions as well as aqueous acrylic latex emulsions and coatings produced from the emulsions. The reactive surfactants deliver stable latex emulsions with reduced tendency for surfactant migration or excessive foaming. Coatings from the emulsions have improved wet adhesion, scrub resistance, and water resistance.
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公开(公告)号:EP3824056A1
公开(公告)日:2021-05-26
申请号:EP19746283.1
申请日:2019-07-12
Applicant: Stepan Company
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公开(公告)号:EP4509545A1
公开(公告)日:2025-02-19
申请号:EP24192847.2
申请日:2018-10-09
Applicant: Stepan Company
Inventor: BOEBEL, Timothy A. , DONG, Xue Min , ROJAS, Carolina E. , LUKA, Renee , LUEBKE, Gary , KNOX, Paul W.
Abstract: Copolymers comprising recurring units of a phenyl glycidyl ether and alkylene oxides are disclosed. The copolymers comprise a monofunctional nucleophilic initiator selected from thiols, thiophenols, aralkylated phenols, sulfinic acids, secondary amines, C 10 -C 20 terpene alcohols, and deprotonated species thereof. Pigments dispersions comprising the copolymers are also disclosed. The copolymers meet the growing needs of the industry with their ease of manufacture, diverse structures, and desirable performance attributes for dispersing a wide range of organic and inorganic pigments. Agricultural applications for the copolymers are also disclosed.
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公开(公告)号:EP3694904A1
公开(公告)日:2020-08-19
申请号:EP18797245.0
申请日:2018-10-09
Applicant: Stepan Company
Inventor: BOEBEL, Timothy A. , DONG, Xue Min , ROJAS, E. Carolina , LUKA, Renee , LUEBKE, Gary , KNOX, Paul W.
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公开(公告)号:EP4431532A3
公开(公告)日:2024-12-25
申请号:EP24192851.4
申请日:2020-03-05
Applicant: Stepan Company
Inventor: BOEBEL, Timothy A. , FARRIS, Samantha Michelle , LUEBKE, Gary , ROJAS, Carolina E. , SPAULDING, Chris , TERRY, Michael R. , WOLFE, Patrick Shane , ZAUG, Julia
IPC: C07C41/03 , C07C67/08 , C07C303/28 , C07C319/14 , C07D295/088 , C07F9/12 , C08F2/26
Abstract: Processes for making reactive surfactants are disclosed. In one such process, an alkyl- or alkenylsuccinic anhydride is reacted with an olefin-functional nucleophile to produce an olefin-functional succinate monoester. Surfactant compositions comprising the reactive surfactants made by these processes are also described. The invention includes polymerizable mixtures comprising an acrylic monomer and the surfactant compositions as well as aqueous acrylic latex emulsions and coatings produced from the emulsions. The reactive surfactants deliver stable latex emulsions with reduced tendency for surfactant migration or excessive foaming. Coatings from the emulsions have improved wet adhesion, scrub resistance, and water resistance.
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公开(公告)号:EP4290224A3
公开(公告)日:2024-05-22
申请号:EP23205413.0
申请日:2019-07-12
Applicant: Stepan Company
Inventor: MASTERS, Ronald A. , KNOCK, Mona Marie , WOLFE, Patrick Shane , BOEBEL, Timothy A. , DONG, Xue Min , MURPHY, Dennis S.
CPC classification number: C11D1/722 , C11D1/72 , C11D1/74 , C11D1/82 , C11D3/3723 , C11D3/2086 , G01N2021/94520130101 , C11D2111/1820240101
Abstract: Dilutable concentrates useful for hard surface cleaners with improved film/streak performance on high-energy surfaces are disclosed. The concentrates comprise a nonionic alkoxylated surfactant and a polyetheramine. A relatively minor proportion of a polyetheramine can resolve film/streak issues that characterize hard surface cleaners formulated with nonionic surfactants. The efficacy of polyetheramines for improving film/streak performance of hard surface cleaners formulated with nonionic alkoxylated surfactants far exceeds the benefits available from known improvements, such as the use of hydrotropes. Other inventive dilutable concentrates and hard surface cleaners comprise an amine-functional hydrophobe and an auxiliary surfactant. Still other dilutable concentrates or hard surface cleaners comprise a nonionic alkoxylated surfactant and lactic acid. An improved method for measuring film/streak properties of hard surface cleaners is also disclosed.
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公开(公告)号:EP3694901A1
公开(公告)日:2020-08-19
申请号:EP18807743.2
申请日:2018-10-09
Applicant: Stepan Company
Inventor: BOEBEL, Timothy A. , DONG, Xue Min , ROJAS, E. Carolina , LUKA, Renne , LUEBKE, Gary
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