STEAM FOAM METHODS FOR STEAM-ASSISTED GRAVITY DRAINAGE
    2.
    发明申请
    STEAM FOAM METHODS FOR STEAM-ASSISTED GRAVITY DRAINAGE 审中-公开
    用于蒸汽辅助排放的蒸汽泡沫方法

    公开(公告)号:WO2016028464A1

    公开(公告)日:2016-02-25

    申请号:PCT/US2015/043051

    申请日:2015-07-31

    Applicant: STEPAN COMPANY

    CPC classification number: E21B43/2408

    Abstract: Methods for making efficient use of steam in a steam-assisted gravity drainage (SAGD) process for recovering heavy oils from tar sands and similar petroleum deposits are disclosed. The methods utilize a surfactant to generate steam foam in ways that maximize efficient use of steam. In some aspects, steam foam is used in water layers or gas caps that reside above steam chambers 4 to prevent loss of steam 6 from the steam chamber 4. The predominant use of relatively dry steam in SAGD processes makes it challenging to find ways to introduce surfactants 5 and generate steam foam 8. However, decreasing the mobility of the steam 6 by converting at least some of it to foam 8 allows the wellbore and steam chambers 4 above the injection site to be more fully developed, provides for more effective heat transfer to the heavy oil and rock, improves production, and allows recovery of the heavy oil with a minimum amount of steam usage.

    Abstract translation: 公开了在用于从焦油砂和类似的石油沉积物中回收重油的蒸汽辅助重力排水(SAGD)方法中有效利用蒸汽的方法。 该方法利用表面活性剂产生蒸汽泡沫,以最大限度地有效利用蒸汽。 在一些方面,蒸气泡沫被用在位于蒸汽室4上方的水层或气帽中,以防止蒸汽室6蒸汽6的损失。在SAGD工艺中主要使用相对干燥的蒸汽使得探索如何引入 表面活性剂5并产生蒸汽泡沫8.然而,通过将其中的至少一些转化为泡沫8来降低蒸汽6的迁移率,允许更充分地开发注射部位上方的井筒和蒸汽室4,从而提供更有效的热传递 对重油和岩石,改善生产,并允许以最少量的蒸汽使用回收重油。

    POLYMERIC DISPERSANTS FROM ARALKYLATED PHENOLS

    公开(公告)号:WO2019074896A1

    公开(公告)日:2019-04-18

    申请号:PCT/US2018/054958

    申请日:2018-10-09

    Applicant: STEPAN COMPANY

    Abstract: Polymers useful in formulating dispersing agents for pigments are disclosed. One such polymer can be made from a glycidyl intermediate. A nucleophilic initiator can be reacted with epichlorohydrin to produce a glycidyl intermediate. This intermediate is reacted with an aralkylated phenol to give a hydroxy-functional hydrophobe. Alkoxylation of the hydrophobe gives the desired polymer. In an alternative, approach, the polymer is made by reacting the nucleophilic initiator with an aralkylated phenol glycidyl ether to give the hydroxy-functional hydrophobe, which is then alkoxylated. Pigments dispersions comprising the polymers are also disclosed. The polymers meet the growing needs of the industry with their ease of manufacture, diverse structures, and desirable performance attributes for dispersing a wide range of organic and inorganic pigments. Agricultural applications for the polymers are also disclosed.

    SURFACTANTS BASED ON MONOUNSATURATED FATTY ALCOHOL DERIVATIVES
    4.
    发明申请
    SURFACTANTS BASED ON MONOUNSATURATED FATTY ALCOHOL DERIVATIVES 审中-公开
    基于MONTHNSATURATED脂肪醇衍生物的表面活性剂

    公开(公告)号:WO2014164156A2

    公开(公告)日:2014-10-09

    申请号:PCT/US2014/020890

    申请日:2014-03-05

    Applicant: STEPAN COMPANY

    CPC classification number: C11D1/146 A01N25/00 A01N25/30 C07C305/10

    Abstract: Surfactant compositions comprising an alkoxylate, a sulfate, or ether sulfate of a C 10 -C 12 monounsaturated alcohol are disclosed. The alkoxylate, sulfate, or ether sulfate may derive from undecylenic acid or undecylenic alcohol. Compared with their saturated analogs, the monounsaturated alkoxylates, sulfates, and ether sulfates are less irritating, making them valuable for personal care, laundry, cleaners, and other household applications. Microscopy studies show that the alkoxylates, sulfates, and ether sulfates have favorable phase behavior over a wide range of actives levels, expanding opportunities for products with greater compaction. When combined with cationic surfactants, the alkoxylates, sulfates, and ether sulfates exhibit synergy, and they have improved solubility compared with their saturated analogs. The surfactants find value for the personal care, laundry and cleaning, emulsion polymerization, agricultural products, oilfield applications, and specialty foams industries.

    Abstract translation: 公开了包含C10-C12单不饱和醇的烷氧基化物,硫酸盐或醚硫酸盐的表面活性剂组合物。 烷氧基化物,硫酸盐或醚硫酸盐可衍生自十一碳烯酸或十一碳烯醇。 与其饱和类似物相比,单不饱和烷氧基化物,硫酸盐和醚硫酸盐刺激性较小,使其对个人护理,洗衣,清洁剂和其他家用应用是有价值的。 显微镜研究表明,烷氧基化物,硫酸盐和醚硫酸盐在广泛的活性水平上具有良好的相位行为,扩大了具有更大压实度的产品的机会。 当与阳离子表面活性剂组合时,烷氧基化物,硫酸盐和醚硫酸盐表现出协同作用,并且与饱和类似物相比具有改善的溶解性。 表面活性剂可用于个人护理,洗衣和清洁,乳液聚合,农产品,油田应用和特种泡沫行业。

    SULFOMETHYLSUCCINATES, PROCESS FOR MAKING SAME AND COMPOSITIONS CONTAINING SAME

    公开(公告)号:WO2011109047A3

    公开(公告)日:2011-09-09

    申请号:PCT/US2010/055266

    申请日:2010-11-03

    Abstract: Sulfometh lsuccinates of the formula I, wherein R is an alkyi, alkenyl, alkynyl, alkoxylated alkyi, cycloalkyl, cycloalkenyl, cycloalkynyl, branched alkyi, branched alkenyl, branched alkynyl, branched alkoxylated alkyi, aromatic, substituted alkyi aromatic, substituted alkenyl aromatic or substituted alkoxylated aromatic group; M is a cation, hydrogen, amine or ammonium salt or combinations thereof, and each M may be the same as or different from the other; and n is from 1 to about 6. Processes for synthesizing the sulfomethylsuccinates are also provided. The sulfomethylsuccinates can be used as surfactants, emulsifiers, skin feel agents, film formers, rheological modifiers, solvents, release agents, lubrication agents, conditioners, and dispersants, etc.

    SYNERGISTIC SURFACTANT BLENDS
    7.
    发明申请

    公开(公告)号:WO2013162924A1

    公开(公告)日:2013-10-31

    申请号:PCT/US2013/036460

    申请日:2013-04-12

    Applicant: STEPAN COMPANY

    Abstract: Synergistic surfactant blends are disclosed. In one aspect, the blend comprises an anionic surfactant and a metathesis-based cationic surfactant comprising a quaternized derivative. The quaternized derivative is a quaternized fatty amine, quaternized fatty amidoamine, imidazoline quat, or esteramine quat made from a metathesis-derived C10-C17 monounsaturated acid or its ester derivative. Also disclosed are synergistic surfactant blends comprising a cationic surfactant and a metathesisbased anionic surfactant comprising a sulfonated derivative. The sulfonated derivative is a fatty ester sulfonate, fatty acid sulfonate, sulfoestolide, fatty amide sulfonate, sulfonated fatty ester alkoxylate, imidazoline quat sulfonate, sulfonated amidoamine oxide, or sulfonated amidoamine betaine. The synergistic blends have a negative value or a reduced interfacial tension (1FT) when compared with an expected 1FT value calculated from the individual surfactant components. Blends of the invention also exhibit surprisingly favorable solubility profiles.

    Abstract translation: 公开了协同表面活性剂共混物。 一方面,共混物包含阴离子表面活性剂和包含季铵化衍生物的基于复分解的阳离子表面活性剂。 季铵化衍生物是由复分解衍生的C10-C17单不饱和酸或其酯衍生物制成的季铵化脂肪胺,季铵化脂肪酰氨基胺,咪唑啉季铵盐或酯胺季铵盐。 还公开了包含阳离子表面活性剂和包含磺化衍生物的易位素阴离子表面活性剂的协同表面活性剂共混物。 磺化衍生物是脂肪酯磺酸盐,脂肪酸磺酸盐,磺基甲基醚,脂肪酰胺磺酸盐,磺化脂肪酸酯烷氧基化物,咪唑啉季磺酸盐,磺化酰氨基胺氧化物或磺化酰氨基胺甜菜碱。 与从各个表面活性剂组分计算的预期1FT值相比,协同混合物具有负值或降低的界面张力(1FT)。 本发明的共混物也表现出令人惊讶的有利的溶解度曲线。

    SOAP BAR COMPOSITIONS COMPRISING ALPHA SULFONATED FATTY ACID ALKYL ESTERS AND POLYHYDRIDIC ALCOHOLS AND PROCESS FOR PRODUCING SAME
    9.
    发明申请
    SOAP BAR COMPOSITIONS COMPRISING ALPHA SULFONATED FATTY ACID ALKYL ESTERS AND POLYHYDRIDIC ALCOHOLS AND PROCESS FOR PRODUCING SAME 审中-公开
    包含ALPHA硫酸脂肪酸酯和多糖醇的皂条组合物及其生产方法

    公开(公告)号:WO2003063819A1

    公开(公告)日:2003-08-07

    申请号:PCT/US2003/002861

    申请日:2003-01-31

    Abstract: Disclosed are improved cleaning compositions comprising soap&com ma; fatty acid, synthetic detersive surfactant, salt and a polyhydridic alcohol, which are suitable for formation into precursor cleansing/laundry bar "soap noodles," personal cleansing bars and laundry detergent bars. The compositions comprise: (a) from about 58 % to about 93 % by weight of an approximately 70 % aqueous soap slurry; (b) from about 1 % to about 15 % by weight of a fatty acid; (c) from about 2 % to about 30 % by weight of an approximately 55 % aqueous mixture of anionic surfactants comprising i) an alpha sulfonated alkyl ester; and ii) a sulfonated fatty acid or salts thereof, wherein the ratio of i) to ii) is from about 10:1 to about 1:10; (d) from about 0.5 % to about 2 % by weight of a salt; (e) from about 0.5% to about 5 % by weight of a 25 polyhydridic alcohol; and (f) from 0 to about 10% by weight of an alkanolamide of the formula O CH 3 (CH2) n C NH(CH 2 ) y OH wherein n = 6-16, and y is 2-4; The invention additionally relates to an improved process for producing both precursor cleansing/laundry bar "soap noodles" and personal cleansing/laundry detergent bars 35 comprising combining (a) - (e) to form a liquid mixture at a temperature of about 65 °C to about 105 °C, removing from about 50% to about 90% by weight of the water from the liquid mixture, by heating up to 150 °C under vacuum conditions or 105 °C at normal conditions to form a thickened mixture, extruding the thickened mixture to form flaked solid or semi-solid pellets or noodles, and optionally, plodding the flaked solid or semi-solid pellets or noodles to form plodded pellets or noodles,f extruding the plodded pellets or noodles to form a billet, cutting the billet, and stamping the cut billet to yield a personal cleansing/laundry detergent bar.

    Abstract translation: 公开了改进的清洁组合物,其包含皂 脂肪酸,合成去污表面活性剂,盐和多元醇,其适于形成前体清洁/洗衣条“肥皂面”,个人清洁条和洗衣用洗涤剂条。 组合物包含:(a)约58%至约93%重量的约70%含水皂浆; (b)约1%至约15%重量的脂肪酸; (c)约2%至约30%重量的约55%的阴离子表面活性剂混合物,其包含i)α磺化烷基酯; 和ii)磺化脂肪酸或其盐,其中i)与ii)的比例为约10:1至约1:10; (d)约0.5%至约2%重量的盐; (e)约0.5重量%至约5重量%的25多元醇; 和(f)0至约10重量%的式O CH 3(CH 2)n S n NH 3的链烷醇酰胺(CH 2 s / s) >)其中n = 6-16,y为2-4; 本发明还涉及用于生产前体清洁/洗衣条“肥皂面”和个人清洁/洗衣洗涤剂条35的改进方法,其包括将(a) - (e)组合在约65℃的温度下形成液体混合物 至约105℃,通过在正常条件下在真空条件下或105℃下加热至150℃,从液体混合物中除去约50%至约90%的水,形成增稠的混合物,挤出 增稠的混合物以形成片状固体或半固体颗粒或面条,并且任选地,将片状固体或半固体颗粒或面条铺上以形成带状的颗粒或面条,f挤出步态颗粒或面条以形成坯料,切割坯料 并冲压切割的坯料以产生个人清洁/洗涤洗涤剂条。

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