公开(公告)号：WO2013162736A1

公开(公告)日：2013-10-31

申请号：PCT/US2013/031049

申请日：2013-03-13

Applicant: STEPAN COMPANY

Inventor： ALLEN, David, R. ,  ALONSO, Marcos ,  BEDDAOUI, Mary ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  DILLAVOU, Scott ,  DONG, Xue, Min ,  GORMAN, Wilma ,  HUTCHISON, John, C. ,  LUEBKE, Gary ,  LUKA, Renee ,  LUXEM, Franz ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  PENDLETON, Nicholas ,  RYKLIN, Irma ,  SKELTON, Patti ,  SOOK, Brian ,  SPAULDING, Chris ,  TURPIN, Krista ,  WALLACE, Gregory ,  WIESTER, Michael ,  WOLFE, Patrick Shane

IPC: C11D1/28

CPC classification number: C07C309/10 ,  A01N25/30 ,  A61K8/463 ,  A61K8/466 ,  A61K2800/10 ,  B01F17/0057 ,  B01F17/0092 ,  C04B38/10 ,  C07C29/147 ,  C07C41/06 ,  C07C303/14 ,  C07C303/32 ,  C07C309/08 ,  C09D7/63 ,  C11D1/143 ,  C11D1/146 ,  C11D1/29 ,  C11D1/37 ,  C11D1/66 ,  A01N37/34 ,  A01N43/40 ,  A01N43/56 ,  A01N43/653 ,  A01N43/70 ,  A01N47/30 ,  A01N51/00

Abstract: Sulfate and sulfonate derivatives of unsaturated fatty alcohols, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol composition is made by reducing a metathesis-derived monounsaturated alkyl ester. The fatty alcohol composition is then converted to a sulfate or sulfonate derivative by one or more of alkoxylation, sulfation, sulfonation, and sulfitation. Of particular interest are the sulfate and ether sulfate derivatives.

Abstract translation: 公开了不饱和脂肪醇的硫酸酯和磺酸酯衍生物，其制备方法及其使用方法。 在一个方面，单不饱和脂肪醇组合物通过还原来自复分解衍生的单不饱和烷基酯来制备。 然后通过烷氧基化，硫酸化，磺化和硫酸化中的一种或多种将脂肪醇组合物转化成硫酸盐或磺酸盐衍生物。 特别感兴趣的是硫酸盐和醚硫酸盐衍生物。

公开(公告)号：WO2020185513A1

公开(公告)日：2020-09-17

申请号：PCT/US2020/021189

申请日：2020-03-05

Applicant: STEPAN COMPANY

Inventor： BOEBEL, Timothy, A. ,  FARRIS, Samantha Michelle ,  LUEBKE, Gary ,  ROJAS, E., Carolina ,  SPAULDING, Chris ,  TERRY, Michael, R. ,  WOLFE, Patrick Shane ,  ZAUG, Julia

IPC: C07C41/03 ,  C07C67/08 ,  C07C303/28 ,  C07C319/14 ,  C07D295/088 ,  C07F9/12 ,  C08F2/26

Abstract: Processes for making reactive surfactants are disclosed. In one such process, a fatty epoxide, a glycidyl ether, or a combination thereof is reacted with an olefin-functional nucleophile to produce an olefin-functional hydrophobe. The olefin-functional hydrophobe is reacted with ethylene oxide, propylene oxide, butylene oxides, or a combination thereof to produce an alkoxylate. Optionally, the alkoxylate is converted to the corresponding sulfate, phosphate, or maleate. Surfactant compositions comprising the reactive surfactants made by these processes are also described. The invention includes polymerizable mixtures comprising an acrylic monomer and the surfactant compositions as well as aqueous acrylic latex emulsions and coatings produced from the emulsions. The reactive surfactants deliver stable latex emulsions with reduced tendency for surfactant migration or excessive foaming. Coatings from the emulsions have improved wet adhesion, scrub resistance, and water resistance.

公开(公告)号：WO2013162737A1

公开(公告)日：2013-10-31

申请号：PCT/US2013/031060

申请日：2013-03-13

Applicant: STEPAN COMPANY

Inventor： ALLEN, David, R. ,  ALONSO, Marcos ,  BEDDAOUI, Mary ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  DONG, Xue, Min ,  GORMAN, Wilma ,  HUTCHISON, John, C. ,  LUEBKE, Gary ,  LUKA, Renee ,  LUXEM, Franz ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  SPAULDING, Chris ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C08F18/20

CPC classification number: C07C309/10 ,  A01N25/30 ,  A61K8/463 ,  A61K8/466 ,  A61K2800/10 ,  B01F17/0057 ,  B01F17/0092 ,  C04B38/10 ,  C07C29/147 ,  C07C41/03 ,  C07C41/06 ,  C07C303/14 ,  C07C303/32 ,  C07C309/08 ,  C09D7/63 ,  C11D1/143 ,  C11D1/146 ,  C11D1/29 ,  C11D1/37 ,  C11D1/66 ,  A01N37/34 ,  A01N43/40 ,  A01N43/56 ,  A01N43/653 ,  A01N43/70 ,  A01N47/30 ,  A01N51/00 ,  C07C43/1785 ,  C07C33/025

Abstract: Unsaturated fatty alcohol alkoxylates, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol alkoxylate is made by reducing a metathesis-derived monounsaturated alkyl ester, followed by alkoxylation of the resulting monounsaturated alcohol. Microscopy reveals that the monounsaturated alkoxylates have isotropic and lamellar phases over a wider range of actives levels compared with their saturated analogs. This attribute expands formulating latitude for many end-use applications. The unsaturated fatty alcohol alkoxylates are valuable in, for example, agricultural solvents, nonionic emulsifiers for agricultural compositions, hard surface cleaners, laundry detergents, specialty foams, additives or surfactants for paints or coatings, and surfactant compositions for enhanced oil recovery.

Abstract translation: 公开了不饱和脂肪醇烷氧基化物，其制备方法及其使用方法。 在一个方面，单不饱和脂肪醇烷氧基化物是通过还原衍生的单不饱和烷基酯，然后将所得的单不饱和醇进行烷氧基化来制备的。 显微镜显示，与其饱和类似物相比，单不饱和烷氧基化物在更广泛的活性水平范围内具有各向同性和层状相。 该属性扩展了许多最终用途应用程序的自由度。 不饱和脂肪醇烷氧基化物在例如农用溶剂，用于农业组合物的非离子乳化剂，硬表面清洁剂，衣物洗涤剂，特种泡沫，用于油漆或涂料的添加剂或表面活性剂以及用于提高油采收率的表面活性剂组合物中是有价值的。

公开(公告)号：EP4431532A3

公开(公告)日：2024-12-25

申请号：EP24192851.4

申请日：2020-03-05

Applicant: Stepan Company

Inventor： BOEBEL, Timothy A. ,  FARRIS, Samantha Michelle ,  LUEBKE, Gary ,  ROJAS, Carolina E. ,  SPAULDING, Chris ,  TERRY, Michael R. ,  WOLFE, Patrick Shane ,  ZAUG, Julia

IPC: C07C41/03 ,  C07C67/08 ,  C07C303/28 ,  C07C319/14 ,  C07D295/088 ,  C07F9/12 ,  C08F2/26

Abstract: Processes for making reactive surfactants are disclosed. In one such process, an alkyl- or alkenylsuccinic anhydride is reacted with an olefin-functional nucleophile to produce an olefin-functional succinate monoester. Surfactant compositions comprising the reactive surfactants made by these processes are also described. The invention includes polymerizable mixtures comprising an acrylic monomer and the surfactant compositions as well as aqueous acrylic latex emulsions and coatings produced from the emulsions. The reactive surfactants deliver stable latex emulsions with reduced tendency for surfactant migration or excessive foaming. Coatings from the emulsions have improved wet adhesion, scrub resistance, and water resistance.

公开(公告)号：EP3935038A1

公开(公告)日：2022-01-12

申请号：EP20714824.8

申请日：2020-03-05

Applicant: Stepan Company

Inventor： BOEBEL, Timothy, A. ,  FARRIS, Samantha Michelle ,  LUEBKE, Gary ,  ROJAS, E., Carolina ,  SPAULDING, Chris ,  TERRY, Michael, R. ,  WOLFE, Patrick Shane ,  ZAUG, Julia

IPC: C07C41/03 ,  C07C67/08 ,  C07C303/28 ,  C07C319/14 ,  C07D295/088 ,  C07F9/12 ,  C08F2/26

公开(公告)号：EP2841468A1

公开(公告)日：2015-03-04

申请号：EP13781311.9

申请日：2013-03-13

Applicant: Stepan Company

Inventor： ALLEN, David, R. ,  ALONSO, Marcos ,  BEDDAOUI, Mary ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  DONG, Xue, Min ,  GORMAN, Wilma ,  HUTCHISON, John, C. ,  LUEBKE, Gary ,  LUKA, Renee ,  LUXEM, Franz ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  SPAULDING, Chris ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C08F18/20

Abstract: Unsaturated fatty alcohol alkoxylates, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol alkoxylate is made by reducing a metathesis-derived monounsaturated alkyl ester, followed by alkoxylation of the resulting monounsaturated alcohol. Microscopy reveals that the monounsaturated alkoxylates have isotropic and lamellar phases over a wider range of actives levels compared with their saturated analogs. This attribute expands formulating latitude for many end-use applications. The unsaturated fatty alcohol alkoxylates are valuable in, for example, agricultural solvents, nonionic emulsifiers for agricultural compositions, hard surface cleaners, laundry detergents, specialty foams, additives or surfactants for paints or coatings, and surfactant compositions for enhanced oil recovery.

公开(公告)号：EP2841541B1

公开(公告)日：2020-11-11

申请号：EP13780515.6

申请日：2013-03-13

Applicant: Stepan Company

Inventor： ALLEN, David R. ,  ALONSO, Marcos ,  BEDDAOUI, Mary ,  BERNHARDT, Randal J. ,  BROWN, Aaron ,  DILLAVOU, Scott ,  DONG, Xue Min ,  GORMAN, Wilma ,  HUTCHISON, John C. ,  LUEBKE, Gary ,  LUKA, Renee ,  LUXEM, Franz ,  MALEC, Andrew D. ,  MASTERS, Ronald A. ,  MURPHY, Dennis S. ,  PENDLETON, Nicholas ,  RYKLIN, Irma ,  SKELTON, Patti ,  SOOK, Brian ,  SPAULDING, Chris ,  TURPIN, Krista ,  WALLACE, Gregory ,  WIESTER, Michael ,  WOLFE, Patrick Shane

IPC: C11D1/29

公开(公告)号：EP2841468B1

公开(公告)日：2020-08-26

申请号：EP13781311.9

申请日：2013-03-13

Applicant: Stepan Company

Inventor： ALLEN, David, R. ,  ALONSO, Marcos ,  BEDDAOUI, Mary ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  DONG, Xue, Min ,  GORMAN, Wilma ,  HUTCHISON, John, C. ,  LUEBKE, Gary ,  LUKA, Renee ,  LUXEM, Franz ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  SPAULDING, Chris ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C08F18/20

公开(公告)号：EP4431532A2

公开(公告)日：2024-09-18

申请号：EP24192851.4

申请日：2020-03-05

Applicant: Stepan Company

Inventor： BOEBEL, Timothy A. ,  FARRIS, Samantha Michelle ,  LUEBKE, Gary ,  ROJAS, Carolina E. ,  SPAULDING, Chris ,  TERRY, Michael R. ,  WOLFE, Patrick Shane ,  ZAUG, Julia

IPC: C08F2/26

CPC classification number: C07C41/03 ,  C07C67/08 ,  C07D295/088 ,  C08F2/26 ,  C07F9/091 ,  C07C319/18

Abstract: Processes for making reactive surfactants are disclosed. In one such process, an alkyl- or alkenylsuccinic anhydride is reacted with an olefin-functional nucleophile to produce an olefin-functional succinate monoester. Surfactant compositions comprising the reactive surfactants made by these processes are also described. The invention includes polymerizable mixtures comprising an acrylic monomer and the surfactant compositions as well as aqueous acrylic latex emulsions and coatings produced from the emulsions. The reactive surfactants deliver stable latex emulsions with reduced tendency for surfactant migration or excessive foaming. Coatings from the emulsions have improved wet adhesion, scrub resistance, and water resistance.

公开(公告)号：EP2841541A1

公开(公告)日：2015-03-04

申请号：EP13780515.6

申请日：2013-03-13

Applicant: Stepan Company

Inventor： ALLEN, David R. ,  ALONSO, Marcos ,  BEDDAOUI, Mary ,  BERNHARDT, Randal J. ,  BROWN, Aaron ,  DILLAVOU, Scott ,  DONG, Xue Min ,  GORMAN, Wilma ,  HUTCHISON, John C. ,  LUEBKE, Gary ,  LUKA, Renee ,  LUXEM, Franz ,  MALEC, Andrew D. ,  MASTERS, Ronald A. ,  MURPHY, Dennis S. ,  PENDLETON, Nicholas ,  RYKLIN, Irma ,  SKELTON, Patti ,  SOOK, Brian ,  SPAULDING, Chris ,  TURPIN, Krista ,  WALLACE, Gregory ,  WIESTER, Michael ,  WOLFE, Patrick Shane

IPC: C11D1/28

CPC classification number: C07C309/10 ,  A01N25/30 ,  A61K8/463 ,  A61K8/466 ,  A61K2800/10 ,  B01F17/0057 ,  B01F17/0092 ,  C04B38/10 ,  C07C29/147 ,  C07C41/06 ,  C07C303/14 ,  C07C303/32 ,  C07C309/08 ,  C09D7/63 ,  C11D1/143 ,  C11D1/146 ,  C11D1/29 ,  C11D1/37 ,  C11D1/66 ,  A01N37/34 ,  A01N43/40 ,  A01N43/56 ,  A01N43/653 ,  A01N43/70 ,  A01N47/30 ,  A01N51/00

Abstract: Sulfate and sulfonate derivatives of unsaturated fatty alcohols, processes for making them, and methods of using them are disclosed. In one aspect, a monounsaturated fatty alcohol composition is made by reducing a metathesis-derived monounsaturated alkyl ester. The fatty alcohol composition is then converted to a sulfate or sulfonate derivative by one or more of alkoxylation, sulfation, sulfonation, and sulfitation. Of particular interest are the sulfate and ether sulfate derivatives.