公开(公告)号：US3793203A

公开(公告)日：1974-02-19

申请号：US3793203D

申请日：1971-06-11

Applicant: SUN OIL CO

Inventor： DRISCOLL G ,  HASELTINE M

IPC: C10L1/30 ,  C10M171/00 ,  C10M1/24 ,  C10M1/26

CPC classification number: C10L10/08 ,  C10L1/308 ,  C10M171/002 ,  C10M2205/026 ,  C10M2205/028 ,  C10M2205/04 ,  C10M2227/083 ,  C10N2240/201 ,  C10N2240/202 ,  C10N2250/04

Abstract: Polyolefins, paraffins and polar compounds containing a gemstructured hydrocarbon ''''backbone'''' are useful as traction fluids or as components of traction fluids. For example, compositions, useful as additives to libricants (e.g., components of traction fluids), are produced by oxonolysis of polyolefins, particularly of polyisobutylene oligimers containing at least one pair of maximally crowded geminal methyl groups. For example, ozonolysis of the novel polyisobutylenes can produce oxygenated derivatives (ketones, esters, acids, aldehydes, alcohols, etc.) which are useful as components of traction fluids. Blends of the ketones or of mixtures of the acids and ketones with a base oil (e.g., a paraffinic lube, naphthenic lube, a hydrogenated naphthenic or paraffinic lube, polyolefins or hydrogenated polyolefins) are especially useful as traction fluids or as a lubricant for a friction drive or a limited slip differential. Other polar compounds, useful as additives to lubricants or other mineral oil products (e.g., rubber process oils) can be obtained by conversion of polyisobutylene oligimers to polar compounds containing such functional groups as amine, imine, thioketone, amide, thioester, phosphate esters of the alcohols, ether, oxime, acyl halide, acyl hydrazide, chloride, bromide and maleic anhydride adducts. Salts of the carboxylic acids can also be useful as lubricant additives. A tin complex can also be made which has antiwear properties.

Abstract translation: 含有宝石结构烃“骨架”的聚烯烃，链烷烃和极性化合物可用作牵引流体或作为牵引流体的组分。 例如，可用作绘图者（例如牵引流体的组分）的添加剂的组合物通过聚烯烃，特别是含有至少一对最大拥挤的孪生甲基的聚异丁烯聚合物的氧分解产生。 例如，新型聚异丁烯的臭氧分解可以产生可用作牵引流体组分的氧化衍生物（酮，酯，酸，醛，醇等）。 酮类或酸和酮的混合物与基础油（例如，链烷烃润滑剂，环烷润滑剂，氢化环烷烃或链烷烃润滑剂，聚烯烃或氢化聚烯烃）的共混物特别可用作牵引流体或作为润滑剂 摩擦传动或限滑差速器。 通过将聚异丁烯聚合物转化成含有胺，亚胺，硫酮，酰胺，硫酯，磷酸酯等官能团的极性化合物，可以获得用作润滑剂或其它矿物油产品（例如橡胶加工油）的添加剂的其它极性化合物 醇，醚，肟，酰卤，酰基酰肼，氯化物，溴化物和马来酸酐加成物。 羧酸的盐也可用作润滑剂添加剂。 也可以制成具有抗磨损性能的锡复合物。

公开(公告)号：US3715313A

公开(公告)日：1973-02-06

申请号：US3715313D

申请日：1971-05-17

Applicant: SUN OIL CO PENNSYLVANIA

Inventor： HASELTINE M ,  DRISCOLL G

IPC: C10L1/30 ,  C10M171/00 ,  C10M1/20

CPC classification number: C10M171/002 ,  C10L1/308 ,  C10M2205/026 ,  C10M2205/028 ,  C10M2205/04 ,  C10M2227/083 ,  C10N2240/201 ,  C10N2240/202 ,  C10N2250/04

Abstract: POLAR COMPOUNDS CONTAINING A GEM-STRUCTURED HYDROCARBON "BACKBONE" ARE USEFUL AS TRACTION FLUIDS OR AS COMPONENTS OF TRACTION FLUIDS. FOR EXAMPLE, COMPOSITIONS, USEFUL AS ADDITIVES TO LUBRICANTS (E.G., COMPONENTS OF TRACTION FLUIDS), ARE PRODUCED BY OZONOLYSIS OF POLYOLEFINS, PARTICULARLY OF POLYISOBUTYLENE OLIGIMERS CONTAINING AT LEAST ONE PAIR OF MAXIMALLY CROWDED GEMINAL METHYL GROUPS. FOR EXAMPLE, OZONOLYSIS OF THE NOVEL POLYISOBUTYLENES CAN PRODUCE OXYGENATED DERIVATIVES (KETONES, ESTERS, ACIDS, ALDEHYDES, ALCOHOHOLS, ETC.) WHICH ARE USEFUL AS COMPONENTS OF TRACTION FLUIDS. ONE SUCH ALCOHOL IS 1,1,3,3,5,5,7,7,-OCTAMETHYL-1-OCTANOL. OTHER COMPOUNDS ARE 4,4,6,6,8,8-HEXAMETHYL - 2 - NONANONE AND 2,2,6,6,8,8-HEXAMETHYL-4-NONANONE. BLENDS OF THE KETONES OR OF MIXTURES OF THE ACIDS AND KETONES WITH A BASE OIL (E.G., PARAFFINIC LUBE, NAPHTHENIC LUBE, A HYDROGENATED NAPHTHENIC OR PARAFFINIC LUBE, POLYOLEFINS OR HYDROGENATED POLYOLEFINS) ARE ESPECIALLY USEFUL AS TRACTION FLUIDS OR AS A LUBRICANT FOR A FRICTION DRIVE OR A LIMITED SLIP DIFFERENTIAL.