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    Free radical polymerization process
    1.
    发明专利
    Free radical polymerization process 审中-公开
    自由基聚合方法

    公开(公告)号：JP2005320549A

    公开(公告)日：2005-11-17

    申请号：JP2005149799

    申请日：2005-05-23

    Applicant: Symyx Technologies Inc ,  サイミックス テクノロジーズ、インク

    Inventor： CHARMOT DOMINIQUE ,  CHANG HAN TING ,  LI YUNXIAO ,  HUEFNER PETER

    IPC: C07D231/10 ,  C07C337/02 ,  C07C337/04 ,  C07D285/125 ,  C08F2/00 ,  C08F2/38 ,  C08F4/00 ,  C08F4/04 ,  C08F8/00

    CPC classification number: C08F2/38

    Abstract: PROBLEM TO BE SOLVED: To provide a new material which promotes the polymerization of a monomer in a living-type free radical polymerization and to provide a polymerization process using it. SOLUTION: In this process, a mixture comprising at least one monomer, at least one free radical source, and a controlling agent having a thiocarbonyl group is polymerized and a post-treatment such as removing its thio part from the polymer and the like is carried out. The controlling agent is expressed as R 1 -D-C(=S)-N(R 4 )NR 2 R 3 (wherein R 1 is an alkyl, an aryl which can be substituted or the like; R 2 , R 3 and R 4 are H, a hydrocarbyl which can be substituted or the like; D is one of S, Se and Te). By this, a living-type free radical polymerization is enabled for various monomers. COPYRIGHT: (C)2006,JPO&NCIPI

    Abstract translation: 要解决的问题：提供促进活性自由基聚合中单体聚合的新材料，并提供使用它的聚合方法。 解决方案：在该方法中，将包含至少一种单体，至少一种自由基源和具有硫代羰基的控制剂的混合物聚合，并进行后处理，例如从聚合物中除去其硫代部分， 喜欢进行。 控制剂表示为R 1 -DC（= S）-N（R 4 ）NR 2 R 3 SP>（其中R 1 是烷基，可被取代的芳基等; R 2 SP，R SP 3和R SP > 4 是H，可以被取代的烃基等; D是S，Se和Te之一）。 由此可以实现各种单体的活性自由基聚合。 版权所有（C）2006，JPO＆NCIPI

    CONTROLLED FREE RADICAL EMULSION AND WATER-BASED POLYMERIZATIONS AND SEEDED METHODOLOGIES
    3.
    发明申请
    CONTROLLED FREE RADICAL EMULSION AND WATER-BASED POLYMERIZATIONS AND SEEDED METHODOLOGIES 审中-公开
    控制免费的立体乳液和水基聚合和种子方法

    公开(公告)号：WO0053640B1

    公开(公告)日：2000-12-14

    申请号：PCT/US0006176

    申请日：2000-03-08

    Applicant: SYMYX TECHNOLOGIES INC

    Inventor： KLAERNER GERRIT ,  SAFIR ADAM ,  NIELSEN RALPH B ,  JANDELEIT BERND ,  HUEFNER PETER ,  LI YUNXIAO

    IPC: C08F2/22 ,  C08F2/28 ,  C08F2/38 ,  C08F4/00 ,  C08F220/58 ,  G01N33/543

    CPC classification number: C08F220/58 ,  C08F4/00 ,  G01N33/54353

    Abstract: Nitroxides having an alpha-carbon atom with a destabilizing moiety are effective control agents for emulsion and water-based polymerizations, including the formation of block copolymers from a wide range of monomers. The nitroxide radicals may be used as a free radical or as an adduct with a residue from the initiator. The emulsions have living characteristics, including the re-initiation of polymer chains. Also, a seeded process for emulsions, which includes the step-wise addition of monomer is disclosed, providing access to a wide range of initiator types.

    Abstract translation: 具有不饱和部分的α-碳原子的硝基氧化物是用于乳液和水基聚合的有效控制剂，包括从宽范围的单体形成嵌段共聚物。 氮氧自由基可以用作自由基或与来自引发剂的残基一起加成。 乳液具有生物特性，包括聚合物链的重新引发。 此外，公开了一种用于乳液的接种方法，其包括逐步添加单体，提供对各种引发剂类型的接触。

    CONTROL AGENTS FOR LIVING-TYPE FREE RADICAL POLYMERIZATION, METHODS OF POLYMERIZING, EMULSIONS AND POLYMERS WITH SAME
    7.
    发明申请
    CONTROL AGENTS FOR LIVING-TYPE FREE RADICAL POLYMERIZATION, METHODS OF POLYMERIZING, EMULSIONS AND POLYMERS WITH SAME 审中-公开
    用于生活型自由基聚合的控制剂，聚合方法，乳液和聚合物

    公开(公告)号：WO0226836A3

    公开(公告)日：2002-06-27

    申请号：PCT/US0130066

    申请日：2001-09-26

    Applicant: SYMYX TECHNOLOGIES INC

    Inventor： CHARMOT DOMINIQUE ,  CHANG HAN TING ,  LI YUNXIAO ,  HUEFNER PETER

    IPC: C07D231/10 ,  C07C337/02 ,  C07C337/04 ,  C07D285/125 ,  C08F2/00 ,  C08F2/38 ,  C08F4/00 ,  C08F4/04 ,  C08F8/00 ,  C07C337/08 ,  C08F293/00

    CPC classification number: C08F2/38

    Abstract: Control agents that have a nitrogen-nitrogen bond covalently bonded to a thiocarbonyl moiety are provided for living-type free radical polymerization of a wide variety of monomers. These control agents provide superior properties for control of the polymerization and/or the properties of the polymers obtained and/or the monomers that may be polymerized. In some embodiments, a bulky group is pendant off the activated thiocarbonyl portion of the control agents. Multifunctional control agents provide the opportunity for a variety of structurally unique polymers, including block copolymers, stars and hyper-branched polymers.

    Abstract translation: 提供了共价键合到硫代羰基部分的氮 - 氮键的对照试剂用于各种单体的活性型自由基聚合。 这些控制剂提供了用于控制聚合的优异性质和/或所获得的聚合物和/或可被聚合的单体的性质。 在一些实施方案中，大体积基团从控制剂的活化的硫代羰基部分脱落。 多功能控制剂为各种结构独特的聚合物，包括嵌段共聚物，恒星和超支化聚合物提供了机会。

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