公开(公告)号：CA1056826A

公开(公告)日：1979-06-19

申请号：CA238870

申请日：1975-11-03

Applicant: TEXACO DEVELOPMENT CORP

Inventor： POBER KENNETH W ,  SHULL DON L

IPC: C07C45/00 ,  C07C45/46 ,  C07C45/62 ,  C07C49/792 ,  C07C51/00 ,  C07C51/27 ,  C07C51/305 ,  C07C61/08 ,  C07C63/26 ,  C07C67/00 ,  C07D201/10

Abstract: Lactams alone or in combination with terephthalic acid are prepared in a sequence of steps from the carbonyl halide reaction product of a cycloparaffin and phosgene and ultimately, where desired, carbon monoxide and chlorine, by acylation of benzene or an alkyl-substituted benzene with the carbonyl chloride derivative of the cycloparaffin; and reduction and nitrosation of the resulting ketone; or, nitrosation alone, in the event the benzene nucleus is alkyl-substituted, to yield the desired lactam and aromatic acid which latter compound may be oxidized to the desired phthalic acid. I