Abstract:
The invention relates to a process for minimizing evaporator scaling during the recovery of liquids and solids from the aqueous effluent discharged during a partial oxidation gasification from a gasifier (16), wherein the aqueous effluent contains ammonium chloride. The aqueous effluent is evaporated in an evaporator (106) to produce a distillate water line (110) and a line containing brine (112) with a brine concentration of about 10 to 60 weight percent. The brine can be further concentrated and ammonium chloride crystals are recovered. The distillate is recycled to the gasification reaction. No effluent discharges to the environment.
Abstract:
The present invention relates to a method for minimizing hydrogen halide corrosion in quench gasifier during the non-catalytic partial oxidation reaction of a halogen-containing hydrocarbonaceous feed, to produce a hydrogen halide-containing synthesis gas, finely divided particulate solids, and a nontoxic slag. The hydrogen halide-containing synthesis gas is contacted with water in the quench zone (14) of the gasifier (10). The quench water contains a neutralizing agent, in excess of the amount necessary to neutralize hydrogen halide acids present therein, to thereby form halide salts. The quench water containing the halide salts is purified to recover the halide salts. The salt-free water is essentially environmentally non-toxic and can either be recycled to the process or discarded in conformity with environmental regulations.
Abstract:
An integrated liquefaction and gasification process converts bulk particulate halogen-containing waste plastic materials with minimal particle size reduction into a synthesis gas and a non-leachable, vitreous environmentally nontoxic slag. The process involves melting and cracking bulk particulate halogen-containing waste plastic material to form a lower boiling point, lower molecular weight halogen-containing oil composition which then undergoes partial oxidation in a quench gasifier to produce a synthesis gas. Any hazardous gases, liquids or solids that are produced can be purified into commercially valuable byproducts or recycled to the process, which does not release hazardous materials to the environment.
Abstract:
ESTA INVENCION SE REFIERE A UN PROCEDIMIENTO PARA MINIMIZAR LA CORROSION PROVOCADA POR EL HALURO DE HIDROGENO EN UN GASIFICADOR DE EXTINCION DURANTE LA REACCION DE OXIDACION PARCIAL NO CATALITICA DE UNA CARGA HIDROCARBONADA QUE CONTIENE UN HALOGENO, PARA OBTENER UN GAS DE SINTESIS QUE CONTIENE HALURO DE HIDROGENO, PARTICULAS SOLIDAS FINAMENTE DIVIDIDAS Y ESCORIAS NO TOXICAS. ESTE GAS DE SINTESIS QUE CONTIENE HALURO DE HIDROGENO SE PONE EN CONTACTO CON AGUA EN LA ZONA DE EXTINCION (14) DEL GASIFICADOR (10). EL AGUA DE EXTINCION CONTIENE UN AGENTE NEUTRALIZADOR, EN CANTIDAD EXCESIVA CON RELACION A LA QUE ES NECESARIA PARA NEUTRALIZAR LOS ACIDOS DE HALURO DE HIDROGENO PRESENTES EN EL GAS, DE MANERA QUE SE OBTENGAN SALES DE HALURO. EL AGUA EXENTA DE SALES NO ES PRACTICAMENTE TOXICA PARA EL MEDIO AMBIENTE Y SE PUEDE RECICLAR MEDIANTE EL PROCEDIMIENTO O DESCARTAR DE ACUERDO CON LA REGLAMENTACION DEL MEDIO AMBIENTE.
Abstract:
A process for minimizing evaporator scaling during the recovery of liquids and solids from the aqueous effluent discharged during a partial oxidation gasification, wherein the aqueous effluent contains ammonium chloride (NH4Cl). The aqueous effluent is evaporated to produce a distillate water and a brine having an NH4Cl concentration of about 10 to 60 weight percent. The brine can be further concentrated and ammonium chloride crystals are recovered. The distillate water is recycled to the gasification reaction. No effluent discharges to the environment.
Abstract:
A process for minimizing evaporator scaling during the recovery of liquids and solids from the aqueous effluent discharged during a partial oxidation gasification, wherein the aqueous effluent contains ammonium chloride (NH4Cl). The aqueous effluent is evaporated to produce a distillate water and a brine having an NH4Cl concentration of about 10 to 60 weight percent. The brine can be further concentrated and ammonium chloride crystals are recovered. The distillate water is recycled to the gasification reaction. No effluent discharges to the environment.
Abstract:
A process for minimizing evaporator scaling during the recovery of liquids and solids from the aqueous effluent discharged during a partial oxidation gasification, wherein the aqueous effluent contains ammonium chloride (NH4Cl). The aqueous effluent is evaporated to produce a distillate water and a brine having an NH4Cl concentration of about 10 to 60 weight percent. The brine can be further concentrated and ammonium chloride crystals are recovered. The distillate water is recycled to the gasification reaction. No effluent discharges to the environment.
Abstract:
A pumpable slurry of shredded scrap solid carbonaceous plastic-containing material that contains associated inorganic matter in admixture with a comminuted aluminosilicate-containing material having noncombustible constituents is reacted by partial oxidation to produce synthesis gas, reducing gas, or fuel gas. The noncombustible constituents in the aluminosilicate-containing material captures the inorganic matter in the scrap solid carbonaceous plastic-containing material while in the reducing atmosphere of the gasifier to produce nontoxic, nonleachable slag. The slurrying medium is water, liquid hydrocarbonaceous fuel, or mixtures thereof. Scrap plastics may be disposed of by the subject process without polluting the nation's environment.