公开(公告)号：WO2004022210A3

公开(公告)日：2004-09-23

申请号：PCT/US0326230

申请日：2003-08-19

Applicant: TEXACO DEVELOPMENT CORP

Inventor： VUONG DINH-CUONG ,  VON KLOCK BYRON

IPC: A62D3/00 ,  A62D3/176 ,  A62D3/38 ,  A62D101/20 ,  A62D101/26 ,  A62D101/45 ,  B01J20060101 ,  C02F1/32 ,  C02F1/72

CPC classification number: A62D3/176 ,  A62D3/38 ,  A62D2101/20 ,  A62D2101/26 ,  A62D2101/45 ,  C02F1/32 ,  C02F1/72 ,  C02F1/722 ,  C02F1/76 ,  C02F1/78 ,  C02F2101/18 ,  C02F2103/18 ,  Y10S210/904

Abstract: A method for substantially reducing cyanide and formate concentrations in gasification wastewater streams comprising first removing suspended solids from the wastewater stream, then adding sufficient hydrogen peroxide to completely oxidize contained cyanide ions and formate ions to form a feed solution, and then irradiating the resultant solution with sufficient UV light so as to substantially reduce said contained cyanide ions and formate ions.

Abstract translation: 一种用于显着降低气化废水流中氰化物和甲酸盐浓度的方法，包括首先从废水流中除去悬浮固体，然后加入足够的过氧化氢以完全氧化所含氰化物离子并甲酸根离子形成进料溶液，然后用所得溶液 足够的紫外光以基本上减少所述含有的氰化物离子和甲酸根离子。

公开(公告)号：JP2001200273A

公开(公告)日：2001-07-24

申请号：JP2000373155

申请日：2000-12-07

Applicant: TEXACO DEVELOPMENT CORP

Inventor： VON KLOCK BYRON ,  CHAN HENRY C

IPC: C10J3/02 ,  C01B3/36 ,  C01B3/52 ,  C10J3/46 ,  C10J3/48 ,  C10K1/02 ,  C10K1/04 ,  C10K1/06 ,  C10K1/10

Abstract: PROBLEM TO BE SOLVED: To provide an oil-gasification system which requires no expensive water-treatment device nor additional introduction of water into the system and is adapted to the strict environmental standards, and an oil-gasification process. SOLUTION: A treatment device to be used with the oil-gasification system contains a flash gas condenser part formed to receive a flash gas from the oil-gasification system; a vacuum pump containing a water outlet which is connected to the flash gas condenser part and extracts vapor from the flash gas condenser part and a drying flash gas outlet; a synthetic gas washing part having a wash water inlet, an outlet for used wash water, a cooled synthetic gas inlet and a synthetic gas outlet; and a synthetic gas cooler part formed to receive the used wash water from the synthetic gas washing part and to receive a seal and a flash water from the flash gas condenser part. The oil- gasification system and the oil-gasification process use this.

公开(公告)号：EP0958333A4

公开(公告)日：2000-02-23

申请号：EP97937978

申请日：1997-07-14

Applicant: TEXACO DEVELOPMENT CORP

Inventor： WEBSTER GEORGE HENRY ,  VON KLOCK BYRON ,  VUONG DONH-CUONG ,  STEVENSON JOHN SAUNDERS ,  JOHNSON STEVEN ROBERT

IPC: C10J3/72 ,  C01B3/52 ,  C01C1/16 ,  C02F1/04 ,  C10J3/46 ,  C10K1/00 ,  C10K1/12 ,  C10K1/06 ,  C10K1/10

CPC classification number: C01C1/164 ,  C01B3/52 ,  C01B2203/0415 ,  C01B2203/0465 ,  C01B2203/0485 ,  C01B2203/0495 ,  C02F1/042 ,  C10J3/466 ,  C10J3/84 ,  C10J2300/0926 ,  C10J2300/093 ,  C10J2300/169 ,  C10J2300/1807 ,  C10J2300/1846 ,  C10K1/00 ,  C10K1/002 ,  C10K1/10 ,  C10K1/101 ,  Y10S159/13

Abstract: The invention relates to a process for minimizing evaporator scaling during the recovery of liquids and solids from the aqueous effluent discharged during a partial oxidation gasification from a gasifier (16), wherein the aqueous effluent contains ammonium chloride. The aqueous effluent is evaporated in an evaporator (106) to produce a distillate water line (110) and a line containing brine (112) with a brine concentration of about 10 to 60 weight percent. The brine can be further concentrated and ammonium chloride crystals are recovered. The distillate is recycled to the gasification reaction. No effluent discharges to the environment.

公开(公告)号：EP0950041A4

公开(公告)日：2004-11-10

申请号：EP97937980

申请日：1997-07-14

Applicant: TEXACO DEVELOPMENT CORP

Inventor： STEVENSON JOHN SAUNDERS ,  VON KLOCK BYRON ,  WINTER JOHN DUCKETT ,  KASSMAN JERROLD SAMUEL ,  WEBSTER GEORGE HENRY ,  BRICKHOUSE PAUL ELLIS

IPC: C08J11/10 ,  C01B3/36 ,  C01B3/52 ,  C01B9/00 ,  C01D3/00 ,  C07C1/02 ,  C10K1/00 ,  C10K3/00 ,  B01D53/68 ,  B01D53/73 ,  C10J3/54

CPC classification number: C01B3/52 ,  C01B3/36 ,  C01B9/00 ,  C01B2203/0415 ,  C01B2203/0465 ,  C01B2203/0475 ,  C01B2203/0495 ,  C01D3/00 ,  C10K1/003 ,  C10K1/121 ,  C10K1/122

Abstract: The present invention relates to a method for minimizing hydrogen halide corrosion in quench gasifier during the non-catalytic partial oxidation reaction of a halogen-containing hydrocarbonaceous feed, to produce a hydrogen halide-containing synthesis gas, finely divided particulate solids, and a nontoxic slag. The hydrogen halide-containing synthesis gas is contacted with water in the quench zone (14) of the gasifier (10). The quench water contains a neutralizing agent, in excess of the amount necessary to neutralize hydrogen halide acids present therein, to thereby form halide salts. The quench water containing the halide salts is purified to recover the halide salts. The salt-free water is essentially environmentally non-toxic and can either be recycled to the process or discarded in conformity with environmental regulations.

公开(公告)号：EP0922124A4

公开(公告)日：1999-10-13

申请号：EP97936086

申请日：1997-07-14

Applicant: TEXACO DEVELOPMENT CORP

Inventor： WEBSTER GEORGE HENRY ,  VON KLOCK BYRON

IPC: C23G1/00 ,  B08B3/00 ,  C10J20060101 ,  C23G20060101 ,  C23G1/02 ,  C23G1/08 ,  C23G1/10

CPC classification number: C23G1/08 ,  C23G1/10 ,  C23G1/106

Abstract: Fluoride-containing scale can be removed from metal surfaces such as titanium, titanium alloys, nickel alloys, and stainless steel by contacting the metal surfaces with an aqueous salt solution of an inorganic acid, including its hydrates. The cationic portion of the salt can be aluminum, iron and mixtures thereof. The anionic portion of the salt can be a chloride, a nitrate, a sulfate, and mixtures thereof. The contracting occurs in the absence of the addition of an acid, such as hydrochloric, nitric, or sulfuric acid. The presence of the aqueous salt solution with the dissolved fluoride scale does not accelerate or increase the normal rate of metal corrosion that can occur in the absence of the aqueous salt solution or any acidic cleaning agent.

Abstract translation: 通过使金属表面与无机酸（包括其水合物）的盐水溶液接触，可以从金属表面（例如钛，钛合金，镍合金和不锈钢）去除含氟化物的氧化皮。 盐的阳离子部分可以是铝，铁及其混合物。 盐的阴离子部分可以是氯化物，硝酸盐，硫酸盐及其混合物。 收缩发生在不添加酸如盐酸，硝酸或硫酸的情况下。 具有溶解的氟化物水垢的盐水溶液的存在不会加速或增加在不存在盐水溶液或任何酸性清洁剂的情况下可能发生的金属腐蚀的正常速率。

公开(公告)号：AT249509T

公开(公告)日：2003-09-15

申请号：AT97937978

申请日：1997-07-14

Applicant: TEXACO DEVELOPMENT CORP

Inventor： WEBSTER GEORGE HENRY ,  VON KLOCK BYRON ,  VUONG DONH-CUONG ,  STEVENSON JOHN SAUNDERS ,  JOHNSON STEVEN ROBERT

IPC: C10J3/72 ,  C01B3/52 ,  C01C1/16 ,  C02F1/04 ,  C10J3/46 ,  C10K1/00 ,  C10K1/12 ,  C10K1/06 ,  C10K1/10

Abstract: A process for minimizing evaporator scaling during the recovery of liquids and solids from the aqueous effluent discharged during a partial oxidation gasification, wherein the aqueous effluent contains ammonium chloride (NH4Cl). The aqueous effluent is evaporated to produce a distillate water and a brine having an NH4Cl concentration of about 10 to 60 weight percent. The brine can be further concentrated and ammonium chloride crystals are recovered. The distillate water is recycled to the gasification reaction. No effluent discharges to the environment.

公开(公告)号：CZ14799A3

公开(公告)日：1999-06-16

申请号：CZ14799

申请日：1997-07-14

Applicant: TEXACO DEVELOPMENT CORP

Inventor： WEBSTER GEORGE HENRY JR ,  VON KLOCK BYRON ,  VUONG DINH-CUONG ,  STEVENSON JOHN SAUNDERS ,  JOHNSON STEVEN ROBERT

IPC: C10J3/72 ,  C01B3/52 ,  C01C1/16 ,  C02F1/04 ,  C10J3/46 ,  C10K1/00 ,  C10K1/12

Abstract: A process for minimizing evaporator scaling during the recovery of liquids and solids from the aqueous effluent discharged during a partial oxidation gasification, wherein the aqueous effluent contains ammonium chloride (NH4Cl). The aqueous effluent is evaporated to produce a distillate water and a brine having an NH4Cl concentration of about 10 to 60 weight percent. The brine can be further concentrated and ammonium chloride crystals are recovered. The distillate water is recycled to the gasification reaction. No effluent discharges to the environment.

公开(公告)号：CA2259899A1

公开(公告)日：1998-01-22

申请号：CA2259899

申请日：1997-07-14

Applicant: TEXACO DEVELOPMENT CORP

Inventor： WINTER JOHN DUCKETT ,  WEBSTER GEORGE HENRY JR ,  STEVENSON JOHN SAUNDERS ,  KASSMAN JERROLD SAMUEL ,  VON KLOCK BYRON ,  BRICKHOUSE PAUL ELLIS

IPC: C08J11/10 ,  C01B3/36 ,  C01B3/52 ,  C01B9/00 ,  C01D3/00 ,  C07C1/02 ,  C10K1/00 ,  C10K3/00 ,  C10K1/12

Abstract: The present invention relates to a method for minimizing hydrogen halide corrosion in quench gasifier during the non-catalytic partial oxidation reaction of a halogen-containing hydrocarbonaceous feed, to produce a hydrogen halide-containing synthesis gas, finely divided particulate solids, and a nontoxic slag. The hydrogen halide-containing synthesis gas is contacted with water in the quench zone (14) of the gasifier (10). The quench water contains a neutralizing agent, in excess of the amount necessary to neutralize hydrogen halide acids present therein, to thereby form halide salts. The quench water containing the halide salts is purified to recover the halide salts. The saltfree water is essentially environmentally non-toxic and can either be recycled to the process or discarded in conformity with environmental regulations.

公开(公告)号：ES2279545T3

公开(公告)日：2007-08-16

申请号：ES97937980

申请日：1997-07-14

Applicant: TEXACO DEVELOPMENT CORP

Inventor： STEVENSON JOHN SAUNDERS ,  VON KLOCK BYRON ,  WINTER JOHN DUCKETT ,  KASSMAN JERROLD SAMUEL ,  WEBSTER GEORGE HENRY ,  BRICKHOUSE PAUL ELLIS

IPC: C01B3/36 ,  C08J11/10 ,  B01D53/68 ,  B01D53/73 ,  C01B3/52 ,  C01B9/00 ,  C01D3/00 ,  C07C1/02 ,  C10J3/54 ,  C10K1/00 ,  C10K3/00

Abstract: ESTA INVENCION SE REFIERE A UN PROCEDIMIENTO PARA MINIMIZAR LA CORROSION PROVOCADA POR EL HALURO DE HIDROGENO EN UN GASIFICADOR DE EXTINCION DURANTE LA REACCION DE OXIDACION PARCIAL NO CATALITICA DE UNA CARGA HIDROCARBONADA QUE CONTIENE UN HALOGENO, PARA OBTENER UN GAS DE SINTESIS QUE CONTIENE HALURO DE HIDROGENO, PARTICULAS SOLIDAS FINAMENTE DIVIDIDAS Y ESCORIAS NO TOXICAS. ESTE GAS DE SINTESIS QUE CONTIENE HALURO DE HIDROGENO SE PONE EN CONTACTO CON AGUA EN LA ZONA DE EXTINCION (14) DEL GASIFICADOR (10). EL AGUA DE EXTINCION CONTIENE UN AGENTE NEUTRALIZADOR, EN CANTIDAD EXCESIVA CON RELACION A LA QUE ES NECESARIA PARA NEUTRALIZAR LOS ACIDOS DE HALURO DE HIDROGENO PRESENTES EN EL GAS, DE MANERA QUE SE OBTENGAN SALES DE HALURO. EL AGUA EXENTA DE SALES NO ES PRACTICAMENTE TOXICA PARA EL MEDIO AMBIENTE Y SE PUEDE RECICLAR MEDIANTE EL PROCEDIMIENTO O DESCARTAR DE ACUERDO CON LA REGLAMENTACION DEL MEDIO AMBIENTE.

公开(公告)号：ES2273651T3

公开(公告)日：2007-05-16

申请号：ES00310683

申请日：2000-12-01

Applicant: TEXACO DEVELOPMENT CORP

Inventor： VON KLOCK BYRON ,  CHAN HENRY C

IPC: C02F9/00 ,  C10J3/02 ,  C01B3/36 ,  C01B3/52 ,  C10J3/46 ,  C10J3/48 ,  C10K1/02 ,  C10K1/04 ,  C10K1/06 ,  C10K1/10

Abstract: Un procedimiento para proporcionar agua de obturación y chorreo a un sistema de gasificación de petróleo que comprende: recibir agua (232) de hollín caliente procedente del dispositivo de extinción de gas de síntesis y del limpiador de hollín (220) en un vaporizador a vacío de agua de hollín (230), recibir agua de hollín fresca del vaporizador (230) a vacío de agua de hollín en un filtro (270) de hollín, recibir agua de filtrado procedente del filtro de hollín en un filtro (280) de cartucho, proporcionar agua de obturación y chorreo al vaporizador (234) de vacío de agua de hollín y el dispositivo de extinción y el limpiador de hollín (224) del filtro de cartucho, proporcionar agua de filtrado a un tanque (290) de almacenamiento de agua y el dispositivo de extinción de gas de síntesis y el limpiador de hollín del filtro de hollín, recibir gas instantáneo procedente del vaporizador de vacío de agua de hollín en un condensador (105) de gas instantáneo, proporcionar agua de condensado instantáneo procedente del condensador de gas instantáneo a una bomba de vacío (110) como agua de obturación, a un enfriador (140) de gas de síntesis como agua de obturación y chorreo, y a un lavador (130) de gas de síntesis como agua de lavado de gas de síntesis.