IMPROVED SYNGAS CONVERSION CATALYST, PRODUCTION AND USE THEREOF
    1.
    发明申请
    IMPROVED SYNGAS CONVERSION CATALYST, PRODUCTION AND USE THEREOF 审中-公开
    改进的SYNGAS转换催化剂,生产和使用

    公开(公告)号:WO1987004085A1

    公开(公告)日:1987-07-16

    申请号:PCT/GB1987000007

    申请日:1987-01-08

    Abstract: A composition for use after reductive activation as a catalyst in the conversion of synthesis gas to hydrocarbons, the composition having formula: RuaAbCeOx, wherein A is an alkali metal, x is a number such that the valence requirements of the other elements for oxygen is satisfied, a is greater than zero and less than 5% w/w, based on the total weight of the composition, b is in the range from zero to 10% w/w, based on the total weight of the composition, and Ce and O constitute the remainder of the composition, is produced by the steps of: (A) adding a solution or solutions of soluble compounds of the metals ruthenium and cerium, and optionally also an alkali metal compound, to a solution of a precipitant comprising a carbonate and/or a bicarbonate and/or a hydroxide of an alkali metal or ammonium under conditions whereby there is formed a precipitate comprising ruthenium and cerium, and optionally also an alkali metal, in the form of compounds thermally decomposable to the metals and/or their oxides, and (B) recovering the precipitate obtained in step (A).

    SOLID FUEL AND PROCESS FOR ITS COMBUSTION
    3.
    发明申请
    SOLID FUEL AND PROCESS FOR ITS COMBUSTION 审中-公开
    固体燃料及其燃烧过程

    公开(公告)号:WO1986001528A1

    公开(公告)日:1986-03-13

    申请号:PCT/GB1985000385

    申请日:1985-08-29

    CPC classification number: C10L9/10

    Abstract: A solid carbonaceous fuel containing up to 10% wt of calcium compounds and 0.1 to 5% wt of added iron added as oxide, carbonate or elemental iron or as as substantially halogen and sulphate-free iron-containing substances forming iron oxide or carbonate under furnace conditions. The additives act synergistically to reduce NOx.

    Abstract translation: 含有高达10重量%的钙化合物的固体碳质燃料和作为氧化物,碳酸盐或元素铁添加的添加的铁的0.1至5重量%,或者作为在炉下形成氧化铁或碳酸盐的基本上无卤素和无硫酸盐的含铁物质 条件。 添加剂协同作用以减少NOx。

    SYNGAS CONVERSION CATALYST PRODUCTION AND USE THEREOF
    4.
    发明申请
    SYNGAS CONVERSION CATALYST PRODUCTION AND USE THEREOF 审中-公开
    SYNGAS转换催化剂生产及其使用

    公开(公告)号:WO1986000885A1

    公开(公告)日:1986-02-13

    申请号:PCT/GB1985000330

    申请日:1985-07-25

    Abstract: A composition for use after reductive activation as a catalyst for the conversion of synthesis gas to hydrocarbons having a carbon number greater than one, which composition has the formula: RuaAbCeOx wherein A is an alkali metal, x is a number such that the valence requirements of the other elements for oxygen is satisfied, a is greater than zero and less than 1% w/w, based on the total weight of the composition, b is in the range from zero to 10% w/w, based on the total weight of the composition, and Ce and O constitute the remainder of the composition, is produced by the process comprising the steps of: (A) bringing together in solution soluble salts of the metals ruthenium and cerium and a precipitant comprising a carbonate and/or bicarbonate and/or a hydroxide of an alkali metal or ammonium under conditions whereby there is formed a precipitate comprising ruthenium and cerium in the form of compounds thermally decomposable to their oxides, and (B) recovering the precipitate obtained in step (A). Also a process for the conversion of synthesis gas using the catalyst produced as aforesaid, optionally in combination with a zeolite.

    PROCESS FOR PRODUCING SYNTHESIS GAS BY PARTIAL COMBUSTION OF HYDROCARBONS
    5.
    发明申请
    PROCESS FOR PRODUCING SYNTHESIS GAS BY PARTIAL COMBUSTION OF HYDROCARBONS 审中-公开
    通过部分燃烧烃生产合成方法

    公开(公告)号:WO1985004647A1

    公开(公告)日:1985-10-24

    申请号:PCT/GB1985000141

    申请日:1985-04-02

    CPC classification number: C01B3/44

    Abstract: Process for the production of synthesis gas and higher hydrocarbons in which a saturated hydrocarbon and an oxygen containing gas having a ratio of hydrocarbon to oxygen of greater than the stoichiometric ratio for complete combustion are introduced into a bed of an inert particulate material. The upward flow rate of the hydrocarbon/oxygen containing gas stream is sufficient to fluidise or to produce a spouting action of the bed material, whereby the particulate material is thrown up above the bed surface and subsequently falls back into the bed. The hydrocarbon and oxygen containing gas are ignited reacted together, and the products of the reaction withdrawn.

    Abstract translation: 一种生产合成气和高级烃的方法,其中将饱和烃和烃与氧的比率高于完全燃烧所需的化学计量比的含氧气体引入到 惰性颗粒物质床。 包含烃/氧混合物的气流的上升流速足以流化床材料或对材料产生喷涌效应,由此颗粒材料被推进到床材料的表面上。 床回落到床上。 含有烃和氧的气体被点燃并相互反应; 然后提取反应的产物。

    NOVEL LAYERED CLAYS, A PROCESS FOR THEIR PRODUCTION AND USES THEREOF
    8.
    发明申请
    NOVEL LAYERED CLAYS, A PROCESS FOR THEIR PRODUCTION AND USES THEREOF 审中-公开
    新型层状粘土,其生产工艺及其用途

    公开(公告)号:WO1985003015A1

    公开(公告)日:1985-07-18

    申请号:PCT/GB1985000002

    申请日:1985-01-03

    Abstract: A silanised layered clay comprising a layered clay chemically modified by incorporation therein of a silicon-containing residue inthe absence of a polymeric cationic hydroxy inorganic metal complex. The silanised layered clays are produced by hydrolysing a hydrolysable silicon compound, for example a tetraalkoxysilane, in the presence of the layered clay and in the absence of a polymeric cationic hydroxy inorganic metal complex. The resulting silanised layered clays are more thermally and/or hydrothermally stable than the layered clays from which they are derived.

    Abstract translation: 一种硅烷化层状粘土,其包含在没有聚合阳离子羟基无机金属络合物的情况下通过掺入含硅残余物而化学改性的层状粘土。 硅烷化层状粘土通过在层状粘土的存在下和不存在聚合阳离子羟基无机金属络合物的情况下水解可水解的硅化合物,例如四烷氧基硅烷来制备。 所得的硅烷化层状粘土比它们衍生的层状粘土更热和/或水热稳定。

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