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    ELECTROSTATICALLY PAINTED POLYMERS AND A PROCESS FOR MAKING SAME
    1.
    发明申请
    ELECTROSTATICALLY PAINTED POLYMERS AND A PROCESS FOR MAKING SAME 审中-公开
    静电涂料聚合物及其制备方法

    公开(公告)号：WO1994007612A1

    公开(公告)日：1994-04-14

    申请号：PCT/US1993008470

    申请日：1993-09-09

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  CARSWELL, Robert ,  CORNELL, Martin, C. ,  GROSETH, Cynthia, K. ,  PORTER, James, R. ,  PRIESTER, Ralph, D., Jr. ,  TABOR, Ricky, L. ,  ZAWISZA, Melissa, J.

    IPC: B05D01/04

    CPC classification number: H01B1/20 ,  B05D1/045

    Abstract: Polyurethane/polyurea polymers can be electrostatically painted without first being coated with a conductive primer. Disclosed is an improvement in a process for electrostatically painting polyurethane/polyurea polymers, the improvement being to prepare the polymer from a formulation including a non-volatile metal salt conductivity inducing material. The polymers painted by the process of the present invention can have physical properties and aesthetic properties substantially similar to those of otherwise identical polymers prepared without the non-volatile metal salt conductivity inducing materials of the present invention. The increased conductivity of the polymers can allow them to be charged with sufficient charge density to permit efficient paint transfer to the polymer surface. Also disclosed is a composition of at least two layers, one layer being an outer layer of electrostatically applied paint, and the other an inner layer of polyurethane/polyurea polymer.

    Abstract translation: 聚氨酯/聚脲聚合物可以静电涂漆，而无需首先涂覆导电底漆。 公开了用于静电涂覆聚氨酯/聚脲聚合物的方法的改进，其改进在于从包含非挥发性金属盐导电诱导材料的制剂制备聚合物。 通过本发明的方法涂覆的聚合物可以具有与没有本发明的非挥发性金属盐导电性诱导材料制备的其它相同聚合物的物理性质和美学性质。 聚合物的增加的电导率可以允许它们以足够的电荷密度进行充电以允许有效的涂料转移到聚合物表面。 还公开了至少两层的组合物，一层是静电涂料的外层，另一层是聚氨酯/聚脲聚合物的内层。

    POLYURETHANES HAVING IMPROVED PHYSICAL PROPERTIES
    3.
    发明申请
    POLYURETHANES HAVING IMPROVED PHYSICAL PROPERTIES 审中-公开
    具有改进的物理性质的聚氨酯

    公开(公告)号：WO1993004103A2

    公开(公告)日：1993-03-04

    申请号：PCT/US1992007178

    申请日：1992-08-19

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： THE DOW CHEMICAL COMPANY ,  PARKS, Franklin, E. ,  SCHROCK, Alan, K. ,  PRIESTER, Ralph, D., Jr. ,  McCLUSKY, John, V. ,  TURNER, Robert, B. ,  WILTZ, Eugene, P., Jr. ,  THOMAS, Raymond, E.

    IPC: C08G18/48

    CPC classification number: C08G18/40 ,  C08G18/4829 ,  C08G18/4837 ,  C08G18/4883 ,  C08G18/5021 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083 ,  C08J9/0004 ,  C08J9/0066 ,  C08J2375/04

    Abstract: In one aspect the invention is a flexible polyurethane foam composition prepared from a formulation comprising (1) an organic polyisocyanate, (2) an isocyanate-reactive component, (3) a catalyst, and (4) a foam stabilizing agent. Foam stabilizing agents can be, (a) alkali metal dihydrogen phosphates and polyphosphates; (b) alkali metal sulfates; (c) aluminum sulfates, phosphates, polyphosphates, borates and alkanoates; (d) ammonium sulfates, phosphates, polyphosphates, borates and alkanoates; (e) acid chlorides; or (f) mixtures thereof. Preferably the isocyanate-reactive component has an average nominal functionality greater than or equal to 3 and the formulation is processed at an isocyanate index of from 80 to 130, preferably 85 to 100. In another aspect the invention is a foam prepared from a similar formulation, using the same relatively high functionality isocyanate-reactive component and reduced index, but without the foam stabilizing agent. Advantages are improved processability and physical properties, including tensile strength, tear resistance and resiliency, even when the formulations use water as a sole blowing agent.

    Abstract translation: 一方面，本发明是由包含（1）有机多异氰酸酯，（2）异氰酸酯反应性组分，（3）催化剂和（4）泡沫稳定剂）的制剂制备的柔性聚氨酯泡沫组合物。 泡沫稳定剂可以是（a）碱金属磷酸二氢盐和多磷酸盐; （b）碱金属硫酸盐; （c）硫酸铝，磷酸盐，多磷酸盐，硼酸盐和链烷酸盐; （d）硫酸铵，磷酸盐，多磷酸盐，硼酸盐和链烷酸盐; （e）酰氯; 或（f）它们的混合物。 优选地，异氰酸酯反应性组分具有大于或等于3的平均标称官能度，并且制剂在异氰酸酯指数为80至130，优选85至100的条件下进行处理。另一方面，本发明是由类似配方 ，使用相同的相对高官能度的异氰酸酯反应性组分和降低的指数，但没有泡沫稳定剂。 优点是改进的加工性能和物理性能，包括拉伸强度，抗撕裂性和弹性，即使配方使用水作为唯一的发泡剂。

    ELECTROSTATICALLY PAINTED POLYMERS AND A PROCESS FOR MAKING SAME
    5.
    发明公开
    ELECTROSTATICALLY PAINTED POLYMERS AND A PROCESS FOR MAKING SAME 失效
    聚合物制品及其制造方法的静电涂装。

    公开(公告)号：EP0662867A1

    公开(公告)日：1995-07-19

    申请号：EP93920503.0

    申请日：1993-09-09

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： CARSWELL, Robert ,  CORNELL, Martin, C. ,  GROSETH, Cynthia K. ,  PORTER, James, R. ,  PRIESTER, Ralph, D., Jr. ,  TABOR, Ricky L. ,  ZAWISZA, Melissa, J.

    IPC: B05D1 ,  B05D7 ,  C09D5 ,  C09D175 ,  H01B1

    CPC classification number: H01B1/20 ,  B05D1/045

    Abstract: Polyurethane/polyurea polymers can be electrostatically painted without first being coated with a conductive primer. Disclosed is an improvement in a process for electrostatically painting polyurethane/polyurea polymers, the improvement being to prepare the polymer from a formulation including a non-volatile metal salt conductivity inducing material. The polymers painted by the process of the present invention can have physical properties and aesthetic properties substantially similar to those of otherwise identical polymers prepared without the non-volatile metal salt conductivity inducing materials of the present invention. The increased conductivity of the polymers can allow them to be charged with sufficient charge density to permit efficient paint transfer to the polymer surface. Also disclosed is a composition of at least two layers, one layer being an outer layer of electrostatically applied paint, and the other an inner layer of polyurethane/polyurea polymer.

    POLYURETHANES HAVING IMPROVED PHYSICAL PROPERTIES
    6.
    发明公开
    POLYURETHANES HAVING IMPROVED PHYSICAL PROPERTIES 失效
    改进的物理HAVING聚氨酯。

    公开(公告)号：EP0553343A1

    公开(公告)日：1993-08-04

    申请号：EP92918902.0

    申请日：1992-08-19

    Applicant: THE DOW CHEMICAL COMPANY

    Inventor： PARKS, Franklin, E. ,  SCHROCK, Alan, K. ,  PRIESTER, Ralph, D., Jr. ,  McCLUSKY, John, V. ,  TURNER, Robert, B. ,  WILTZ, Eugene, P., Jr. ,  THOMAS, Raymond, E.

    IPC: C08G ,  C08G18 ,  C08J9 ,  C08L75 ,  C08G101

    CPC classification number: C08G18/40 ,  C08G18/4829 ,  C08G18/4837 ,  C08G18/4883 ,  C08G18/5021 ,  C08G2101/0008 ,  C08G2101/005 ,  C08G2101/0083 ,  C08J9/0004 ,  C08J9/0066 ,  C08J2375/04

    Abstract: Selon un aspect de l'invention, on décrit une composition d'une mousse de polyuréthanne souple préparée à partir d'une formulation comprenant (1) un polyisocyanate organique, (2) un constituant réagissant à l'isocyanate, (3) un catalyseur, et (4) un agent de stabilisation de mousse. Les agents de stabilisation de mousse peuvent comprendre a) des polyphosphates et phosphates de dihydrogène de métal alcalin; b) des sulfates de métal alcalin; c) des sulfates, phosphates, polyphosphates, borates et alcanoates d'aluminium; d) des sulfates, phosphates, polyphosphates, borates et alcanoates d'ammonium; e) des chlorures d'acide; ou f) des mélanges de ces éléments. Le constituant réagissant à l'isocyanate présente de préférence une fonctionnalité nominale moyenne supérieure ou égale à 3, et la formulation est développée alors qu'elle présente un indice d'isocyanate compris entre 80 et 130, de préférence 85 et 100. Selon un autre aspect, l'invention se rapporte à une mousse préparée à partir d'une formulation analogue, où l'on utilise le même constituant réagissant à l'isocyanate et à fonctionnalité relativement élevée, ainsi que l'indice réduit, mais sans l'agent de stabilisation de mousse. Les avantages que présente cette mousse résident dans une facilité de traitement ainsi que des caractéristiques physiques améliorées, y compris en ce qui concerne la résistance à la traction et l'élasticité et la résistance à la déchirure, même lorsque les formulations utilisent l'eau comme agent gonflant unique.

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