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Patent Agency Ranking
公开(公告)号：EP0194059A1
公开(公告)日：1986-09-10
申请号：EP86301011.2
申请日：1986-02-14
Applicant: THE STANDARD OIL COMPANY
Inventor： Tsou, Dean T. , Burrington, James D. , Blachman, Marc W.
IPC: C07C121/26 , C07C120/00
CPC classification number: C07C255/00
Abstract: A first row transition metal catalyzed procedure for the production of adiponitrile from acrylonitrile comprising mixing a first row transition metal salt, acrylonitrile, metallic reducing agent and solvent, heating the solution, and adding a quench solution to the mixture comprising a proton donor material having a 0 a
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公开(公告)号：EP0194059B1
公开(公告)日：1989-09-20
申请号：EP86301011.2
申请日：1986-02-14
Applicant: THE STANDARD OIL COMPANY
Inventor： Tsou, Dean T. , Burrington, James D. , Blachman, Marc W.
IPC: C07C121/26 , C07C120/00
CPC classification number: C07C255/00
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3.发明授权Method of making a diastereomeric mixture containing two diastereomeric N-acyl-amino acid esters 失效制备含有两种二异氰酸N-亚氨基酸酯的二异氰酸酯混合物的方法
公开(公告)号：EP0315716B1
公开(公告)日：1992-09-02
申请号：EP87309927.9
申请日：1987-11-10
Applicant: THE STANDARD OIL COMPANY
Inventor： Cesa, Mark C. , Burrington, James D. , Dubbert, Robert A.
IPC: C07C231/00 , C07C233/45 , C07C323/00 , C07D233/64 , C07D209/20
CPC classification number: C07C51/14 , C07B2200/07 , C07C67/38 , C07C231/00 , C07C237/00 , C07C59/08 , C07C53/08
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4.发明公开Method of making a diastereomeric mixture containing two diastereomeric N-acyl-amino acid esters 失效Verfahren zur Herstellung einer zwei非对映异构体N-酰基氨基甲酸酯异构体非对映异构体Mischung。
公开(公告)号：EP0315716A1
公开(公告)日：1989-05-17
申请号：EP87309927.9
申请日：1987-11-10
Applicant: THE STANDARD OIL COMPANY
Inventor： Cesa, Mark C. , Burrington, James D. , Dubbert, Robert A.
IPC: C07C231/00 , C07C233/45 , C07C323/00 , C07D233/64 , C07D209/20
CPC classification number: C07C51/14 , C07B2200/07 , C07C67/38 , C07C231/00 , C07C237/00 , C07C59/08 , C07C53/08
Abstract: In the process of hydrocarboxylating an α-enamide with CO and an organic hydroxyl compound to produce a N-acyl-α-amino acid ester, the improvement comprising using as the organic hydroxyl compound reactant, an organic hydroxyl compound which has a chiral center that is essentially all L or D, thereby producing a reaction mixture having essentially no enantiomeric pairs and containing diastereomeric N-acyl-α-amino acid esters having two chiral centers.
Abstract translation: 在用CO和有机羟基化合物加氢羧化α-烯酰胺以制备N-酰基-α-氨基酸酯的过程中，改进包括使用具有手性中心的有机羟基化合物作为有机羟基化合物反应物， 基本上都是L或D，从而产生基本上没有对映体对并含有具有两个手性中心的非对映体N-酰基-α-氨基酸酯的反应混合物。
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5.发明公开Process for making an optically active mixture of an n-acyl-amino acid or ester containing at least two chiral centers 失效一种用于具有至少两个手性核产生N-酰基 - 氨基酸或酯的光学活性的混合物的方法。
公开(公告)号：EP0413068A1
公开(公告)日：1991-02-20
申请号：EP89308419.4
申请日：1989-08-18
Applicant: THE STANDARD OIL COMPANY
Inventor： Burrington, James D. , Cesa, Mark C. , Dubbert, Robert A.
IPC: C07C227/32 , C07C231/18
CPC classification number: C07C227/32 , C07C231/00 , C07C231/18 , C07C237/00 , C07C319/28 , C07C323/58 , C07C2601/14 , C07D207/16 , C07D209/16 , C07D233/54 , C07D233/64
Abstract: In the process of hydrocarboxylating an α-enamide with CO and H₂O or an organic hydroxyl compound to produce an N-acyl-α-amino acid or ester, respectively, the improvement comprising using as the α-enamide reactant, an α-enamide which has a chiral center that is essentially all L or D, thereby producing a reaction mixture containing diastereomeric N-acyl-α-amino acids or esters having two chiral centers, said mixture having essentially no enantiomeric pairs.
Abstract translation: 在阿尔法-enamide与CO和H 2 O或者有机羟基化合物的hydrocarboxylating以产生N-酰基的α氨基酸或酯的过程中，分别使用改进作为阿尔法-enamide反应物包括与α--enamide哪 具有手性中心，其基本上所有L或D，从而产生反应混合物含有具有两个手性中心的非对映的N-酰基 - α氨基酸或酯，所述的基本上无混合物对映体对。
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