Abstract:
PROBLEM TO BE SOLVED: To additionally increase a generation of byproducts of hydrogen cyanide with no considerable reduction in yield of nitrile. SOLUTION: A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum and calcium and characterized by the following empirical formula: A a B b C c D d Fe e Bi f Mo 12 O x , wherein A= one or more of Li, Na, K, Rb and Cs or their mixture; B= one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or their mixture; C= one or more of Ce, Cr, Al, Sb, P, Ge, La, Sn, V and W or their mixture; D= one or more of Ca, Sr, Ba or their mixture; a=0.01-1.0; b and e=1.0-10; c, d, and f=0.1-5.0; and x is a number determined by the valence requirements of the other elements present. COPYRIGHT: (C)2008,JPO&INPIT
Abstract translation:待解决的问题:为了额外地增加氰化氢副产物的产生,而不会显着降低腈的产率。 解决方案:一种催化剂组合物,其包含铁,铋,钼和钙的催化氧化物的络合物,其特征在于以下经验式:A a SB> B b> SB> C SB>ðð SB>铁电子 SB>双˚F SB>沫 12 SB> 0 X SB>其中A = Li,Na,K,Rb和Cs中的一种或多种或它们的混合物; B = Mg,Mn,Ni,Co,Ag,Pb,Re,Cd和Zn中的一种或多种或它们的混合物; C = Ce,Cr,Al,Sb,P,Ge,La,Sn,V和W中的一种或多种或它们的混合物; D = Ca,Sr,Ba或它们的混合物中的一种或多种; A = 0.01-1.0; b和e = 1.0-10; c,d和f = 0.1-5.0; x是由其他元素的化合价要求确定的数。 版权所有(C)2008,JPO&INPIT