POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE ASSEMBLY AND POLYMER ELECTROLYTE FUEL CELL EACH PRODUCED USING SAME

    公开(公告)号:CA2888558C

    公开(公告)日:2021-06-15

    申请号:CA2888558

    申请日:2013-11-22

    Abstract: 81787236 ABSTRACT Provided is a polymer electrolyte composition, and a polymer electrolyte membrane, a membrane electrode complex and a solid polymer-type fuel cell containing the composition. The composition comprises an ionic-group-containing polymer and a nitrogen-containing additive having a structure of (C1) or (C2). The additive has excellent chemical stability to tolerate a strongly acidic atmosphere, solubility in various general-purpose organic solvents, superior processability, and can be mixed with an ionic-group-containing polymer. The additive resists elution under a strongly acidic atmosphere during the operation of a fuel cell, can prevent the occurrence of phase separation during the formation of a film, and can prevent formation of an island-in-sea-like phase-separated structure or occurrence of bleeding out during the formation of a film. The polymer electrolyte composition can achieve excellent proton conductivity under slightly humidified conditions, excellent mechanical strength and excellent physical durability. ( \ -- \ Ar N . = ' . ' MI ' (CI ) .''\c,. if = i \ ' \ i ..._.),,,,,.:, ' k N N¨ N N X k n X (C2) . . . Date Recue/Date Received 2020-04-21

    MOLDED ARTICLE OF POLYMER ELECTROLYTE COMPOSITION AND SOLID POLYMER TYPE FUEL CELL USING SAME

    公开(公告)号:CA2849280C

    公开(公告)日:2020-01-21

    申请号:CA2849280

    申请日:2012-09-20

    Abstract: To provide a formed article of polymer electrolyte composition which exhibits excellent proton conductivity even under low-humidification conditions and under low-temperature conditions, which is excellent in chemical stability, mechanical strength, fuel shutoff properties, and which can achieve high output, high energy density, and excellent long-term durability when used in a polymer electrolyte fuel cell; and also to provide a polymer electrolyte fuel cell using thereof. The formed article of polymer electrolyte composition includes: a block copolymer having one or more of each of a hydrophilic segment (A1) containing an ionic group and a hydrophobic segment (A2) not containing an ionic group; and an additive, wherein the formed article forms co-continuous or lamellar phase separation structure, and the additive is hydrophilic.

    METHOD AND DEVICE FOR MANUFACTURING ASSEMBLY THAT INCLUDES POLYMER ELECTROLYTE MEMBRANE

    公开(公告)号:CA3004257A1

    公开(公告)日:2017-05-26

    申请号:CA3004257

    申请日:2016-11-15

    Abstract: The present invention addresses the problem of continuously manufacturing an assembly that includes a polymer electrolyte membrane, while minimizing the incidence of warping, electrolyte membrane wrinkling, and irregular joining. In order to overcome the aforedescribed problem, the present invention is a method for manufacturing an assembly that includes a polymer electrolyte membrane, said method comprising: a preliminary pressurization step for continuously applying pressure to a sheet to be joined, which includes a polymer electrolyte membrane (10), and a joining sheet, which includes a joining layer to be joined to at least one surface of the sheet to be joined, the sheet to be joined and the joining layer of the joining sheet being in a state of contact; and a heating pressurization step in which the sheet to be joined and the joining sheet, having passed through the preliminary pressurization step, are continuously subjected to pressurization while being heated.

    POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE ASSEMBLY AND POLYMER ELECTROLYTE FUEL CELL EACH PRODUCED USING SAME TECHNICAL FIELD

    公开(公告)号:CA2888558A1

    公开(公告)日:2014-06-05

    申请号:CA2888558

    申请日:2013-11-22

    Abstract: The present invention provides: a polymer electrolyte composition which can achieve excellent proton conductivity under slightly humidified conditions, excellent mechanical strength and excellent physical durability, has excellent practicality, and can be produced using a nitrogen-containing additive, wherein the nitrogen-containing additive can prevent the elution of the additive under a strongly acidic atmosphere during the operation of a fuel cell, has excellent chemical stability so as to tolerate a strongly acidic atmosphere, can be dissolved in various general-purpose organic solvents, has superior processability, can be mixed with an ionic-group-containing polymer, can prevent the occurrence of phase separation during the formation of a film, and can prevent the formation of an island-in-sea-like phase-separated structure or the occurrence of bleeding out during the formation of a film; and a polymer electrolyte membrane, a membrane electrode complex and a solid polymer-type fuel cell, each of which is produced using the polymer electrolyte composition. The polymer electrolyte composition according to the present invention comprises at least an ionic-group-containing polymer (A) and a nitrogen-containing additive (B), said polymer electrolyte composition being characterized in that the nitrogen-containing additive (B) is represented by a specific structural formula.

    POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE COMPLEX AND SOLID POLYMER-TYPE FUEL CELL EACH PRODUCED USING SAME
    7.
    发明公开
    POLYMER ELECTROLYTE COMPOSITION, AND POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE COMPLEX AND SOLID POLYMER-TYPE FUEL CELL EACH PRODUCED USING SAME 有权
    聚丙烯酰胺聚氨酯胶粘剂,聚乙烯醇缩丁醛,聚乙烯醇缩丁醛

    公开(公告)号:EP2927283A4

    公开(公告)日:2016-07-13

    申请号:EP13859073

    申请日:2013-11-22

    Abstract: he present invention provides: a polymer electrolyte composition which can achieve excellent proton conductivity under slightly humidified conditions, excellent mechanical strength and excellent physical durability, has excellent practicality, and can be produced using a nitrogen-containing additive, wherein the nitrogen-containing additive can prevent the elution of the additive under a strongly acidic atmosphere during the operation of a fuel cell, has excellent chemical stability so as to tolerate a strongly acidic atmosphere, can be dissolved in various general-purpose organic solvents, has superior processability, can be mixed with an ionic-group-containing polymer, can prevent the occurrence of phase separation during the formation of a film, and can prevent the formation of an island-in-sea-like phase separation structure or the occurrence of bleeding out during the formation of a film; and a polymer electrolyte membrane, a membrane electrode assembly and a polymer electrolyte fuel cell, each of which is produced using the polymer electrolyte composition. The polymer electrolyte composition according to the present invention comprises at least an ionic-group-containing polymer (A) and a nitrogen-containing additive (B), said polymer electrolyte composition being characterized in that the nitrogen-containing additive (B) is represented by a specific structural formula.

    Abstract translation: 本发明提供:在微加湿条件下可以获得优异的质子传导性,优异的机械强度和优异的物理耐久性的高分子电解质组合物具有优异的实用性,可以使用含氮添加剂制造含氮添加剂 在燃料电池运行过程中阻止添加剂在强酸性气氛下的溶出,具有优异的化学稳定性,能耐受强酸性气氛,可溶于各种通用有机溶剂,具有优异的加工性能,可混合 具有含离子基团的聚合物可以防止在膜形成期间发生相分离,并且可以防止海岛状相分离结构的形成或在形成期间出现渗出的情况 一个电影; 以及使用高分子电解质组合物制造的高分子电解质膜,膜电极接合体和固体高分子型燃料电池。 根据本发明的聚合物电解质组合物至少含有含离子基团的聚合物(A)和含氮添加剂(B),所述聚合物电解质组合物的特征在于含氮添加剂(B) 通过具体的结构式。

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