METHOD OF MANUFACTURING SHAPED ARTICLE OF HYDROGEL

    公开(公告)号:DE3475791D1

    公开(公告)日:1989-02-02

    申请号:DE3475791

    申请日:1984-06-20

    Abstract: A method for the manufacture of shaped article of hydrogel is provided. This shaped article of hydrogel is obtained by the polymerization in a mold of a mixture comprising:A. an alkylene glycol mono(meth)acrylate or a monomer mixture consisting preponderantly of an alkylene glycol mon(meth)acrylate,B. a polymer synthesized from a component A and possessing a polymerizable double bond in the molecular unit thereof,C. a water-soluble dipolar aprotic solvent, andD. at least one member selected from the group consisting of (a) water-soluble organic acids, (b) surface active agents, and (c) water-soluble organic substances which are poor solvents or non-solvents of the component B, and having the weight ratio of the componentAtothe component B in the range of 45 : 55 to 20 : 80.

    2.
    发明专利
    未知

    公开(公告)号:IT8567023D0

    公开(公告)日:1985-01-11

    申请号:IT6702385

    申请日:1985-01-11

    Abstract: PCT No. PCT/JP85/00009 Sec. 371 Date Sep. 3, 1985 Sec. 102(e) Date Sep. 3, 1985 PCT Filed Jan. 11, 1985 PCT Pub. No. WO85/03138 PCT Pub. Date Jul. 18, 1985.An oxygen-permeable contact lens consisting essentially of a polymer having an organic polysiloxane skeleton and a three-dimensional crosslinked structure, and a process for the preparation thereof. The polymer comprises structural units comprising (A) a residue of a trifunctional isocyanate, (B) a residue of at least one compound selected from the group consisting of unsaturated carboxylic acids, monoalkyl esters of unsaturated dicarboxylic acid, monoalkyl and dialkyl esters of unsaturated tricarboxylic acids, hydroxyalkyl esters of unsaturated carboxylic acids, acrylamide, methacrylamide, vinyl ethers, and styrene derivatives having an active hydrogen atom, (C) a polydimethylsiloxane residue modified with an active hydrogen-containing functional group, and (D) a residue of at least one compound selected from the group consisting of alkyl esters of acrylic acid, alkyl esters of methacrylic acid, fluorine-containing acrylates, fluorine-containing methacrylates, acrylates and methacrylates having an alicyclic hydrocarbon group, aryl acrylates and methacrylates, halogen-containing aryl acrylates and methacrylates, styrene, styrene derivatives, alkyl esters of unsaturated carboxylic acids.

    CONTACT LENS AND PROCESS FOR ITS PRODUCTION

    公开(公告)号:DE3572226D1

    公开(公告)日:1989-09-14

    申请号:DE3572226

    申请日:1985-01-11

    Abstract: PCT No. PCT/JP85/00009 Sec. 371 Date Sep. 3, 1985 Sec. 102(e) Date Sep. 3, 1985 PCT Filed Jan. 11, 1985 PCT Pub. No. WO85/03138 PCT Pub. Date Jul. 18, 1985.An oxygen-permeable contact lens consisting essentially of a polymer having an organic polysiloxane skeleton and a three-dimensional crosslinked structure, and a process for the preparation thereof. The polymer comprises structural units comprising (A) a residue of a trifunctional isocyanate, (B) a residue of at least one compound selected from the group consisting of unsaturated carboxylic acids, monoalkyl esters of unsaturated dicarboxylic acid, monoalkyl and dialkyl esters of unsaturated tricarboxylic acids, hydroxyalkyl esters of unsaturated carboxylic acids, acrylamide, methacrylamide, vinyl ethers, and styrene derivatives having an active hydrogen atom, (C) a polydimethylsiloxane residue modified with an active hydrogen-containing functional group, and (D) a residue of at least one compound selected from the group consisting of alkyl esters of acrylic acid, alkyl esters of methacrylic acid, fluorine-containing acrylates, fluorine-containing methacrylates, acrylates and methacrylates having an alicyclic hydrocarbon group, aryl acrylates and methacrylates, halogen-containing aryl acrylates and methacrylates, styrene, styrene derivatives, alkyl esters of unsaturated carboxylic acids.

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