公开(公告)号：DE3853180T2

公开(公告)日：1995-08-17

申请号：DE3853180

申请日：1988-08-11

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  YANO KAZUHISA ,  IWAMOTO MASATOSHI

IPC: C08L77/12 ,  C08G69/44 ,  C08G77/12 ,  C08L25/08 ,  C08L25/16 ,  C08L33/04 ,  C08L33/06 ,  C08L33/18 ,  C08L33/20 ,  C08L33/24 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L63/08 ,  C08L73/00 ,  C08L77/00

Abstract: A transparent polyether-ester amide having a permanently antistatic property is obtained by copolymerizing (a) an aminocarboxylic acid, a lactam, or a salt derived from a diamine and a dicarboxylic acid; (b) a diol of the formula: wherein R and R are an ethylene oxide or propylene oxide group, Y is covalent bond, alkylene, alkylidene, cycloalkylidene, arylalkylidene, O, SO, SO2 , CO, S, CF2 , C(CF3)2 or NH, X is H, alkyl, halogen, sulfonic acid or salt thereof, l is 0 or an integer of 1 - 4, and m and n an integer of 1 - 15; (c) a poly(alkylene oxide)glycol or a diol of the formula: HO - R - OH (IV) wherein R is alkylene, alkylidene, cycloalkylidene or arylalkylidene; and (d) a dicarboxylic acid; wherein the content of the polyether-ester units is 10 to 90 wt.%. The polyether-ester amide is used preferably as a blend thereof with a graft copolymerization product formed by graft-polymerizing (a) a rubbery polymer with (b) a monomer mixture of a methacrylic or acrylic acid ester, an aromatic vinyl monomer and an optional vinyl cyanide monomer, this product having a refractive index approximately similar to that of the polyether-ester amide.

公开(公告)号：DE3788818D1

公开(公告)日：1994-03-03

申请号：DE3788818

申请日：1987-04-13

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  IWAMOTO MASATOSHI ,  KISHIMOTO AKIHIKO

IPC: C08L25/06 ,  C08L51/04 ,  C08L67/00 ,  C08L69/00 ,  C08L71/12 ,  C08L77/00 ,  C08L77/12 ,  G11B23/03

Abstract: Thermoplastic resin compositions comprising 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, polyphenylene ether resins and polycarbonate resins are disclosed.These are permanently antistatic and in preferred forms are excellent in mechanical properties represented by impact resistance, heat resistance, moldability and also in the appearance and gloss of the moldings, and are suitable for housing of optical or magnetic recording media.

公开(公告)号：HK1006973A1

公开(公告)日：1999-03-26

申请号：HK98106118

申请日：1998-06-23

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  IWAMOTO MASATOSHI ,  KISHIMOTO AKIHIKO

IPC: C08L25/06 ,  C08L51/04 ,  C08L67/00 ,  C08L69/00 ,  C08L71/12 ,  C08L77/00 ,  C08L77/12 ,  G11B23/03 ,  C08L

Abstract: Thermoplastic resin compositions comprising 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, polyphenylene ether resins and polycarbonate resins are disclosed.These are permanently antistatic and in preferred forms are excellent in mechanical properties represented by impact resistance, heat resistance, moldability and also in the appearance and gloss of the moldings, and are suitable for housing of optical or magnetic recording media.

公开(公告)号：DE3788818T2

公开(公告)日：1994-06-30

申请号：DE3788818

申请日：1987-04-13

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  IWAMOTO MASATOSHI ,  KISHIMOTO AKIHIKO

IPC: C08L25/06 ,  C08L51/04 ,  C08L67/00 ,  C08L69/00 ,  C08L71/12 ,  C08L77/00 ,  C08L77/12 ,  G11B23/03

Abstract: Thermoplastic resin compositions comprising 1 to 40 wt % a polyether ester amide (A) and 99 to 60 wt % of at least one thermoplastic resin (B) selected from styrene based resins, polyphenylene ether resins and polycarbonate resins are disclosed.These are permanently antistatic and in preferred forms are excellent in mechanical properties represented by impact resistance, heat resistance, moldability and also in the appearance and gloss of the moldings, and are suitable for housing of optical or magnetic recording media.

公开(公告)号：CA1302623C

公开(公告)日：1992-06-02

申请号：CA574691

申请日：1988-08-12

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  YANO KAZUHISA ,  IWAMOTO MASATOSHI

IPC: C08L77/12 ,  C08G69/44 ,  C08G77/12 ,  C08L25/08 ,  C08L25/16 ,  C08L33/04 ,  C08L33/06 ,  C08L33/18 ,  C08L33/20 ,  C08L33/24 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L63/08 ,  C08L73/00 ,  C08L77/00

Abstract: A transparent polyether-ester amide having a permanently antistatic property is obtained by copolymerizing (a) an aminocarboxylic acid, a lactam, or a salt derived from a diamine and a dicarboxylic acid; (b) a diol of the formula: (I), (II) and (III) wherein R1 and R2 are an ethylene oxide or propylene oxide group, Y is covalent bond, alkylene, alkylidene, cycloalkylidene, arylalkylidene, O, SO, SO2 , CO, S, CF2 , C(CF3)2 or NH, X is H, alkyl, halogen, sulfonic acid or salt thereof, ? is 0 or an integer of 1 - 4, and m and n an integer of 1 - 15; (c) a poly(alkylene oxide)glycol or a diol of the formula: HO - R3 - OH (IV) wherein R3 is alkylene, alkylidene, cycloalkylidene or arylalkylidene; and (d) a dicarboxylic acid; wherein the content of the polyether-ester units is 10 to 90 wt.%. The polyether-ester amide is used preferably as a blend thereof with a graft copolymerization product formed by graft-polymerizing (a) a rubbery polymer with (b) a monomer mixture of a methacrylic or acrylic acid ester, an aromatic vinyl monomer and an optional vinyl cyanide monomer, this product having a refractive index approximately similar to that of the polyether-ester amide.

公开(公告)号：HK1007319A1

公开(公告)日：1999-04-09

申请号：HK98106553

申请日：1998-06-25

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  YANO KAZUHISA ,  IWAMOTO MASATOSHI

IPC: C08G69/44 ,  C08G77/12 ,  C08L77/12 ,  C08L25/08 ,  C08L25/16 ,  C08L33/04 ,  C08L33/06 ,  C08L33/18 ,  C08L33/20 ,  C08L33/24 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L63/08 ,  C08L73/00 ,  C08L77/00 ,  C08G ,  C08L

Abstract: A transparent polyether-ester amide having a permanently antistatic property is obtained by copolymerizing (a) an aminocarboxylic acid, a lactam, or a salt derived from a diamine and a dicarboxylic acid; (b) a diol of the formula: wherein R and R are an ethylene oxide or propylene oxide group, Y is covalent bond, alkylene, alkylidene, cycloalkylidene, arylalkylidene, O, SO, SO2 , CO, S, CF2 , C(CF3)2 or NH, X is H, alkyl, halogen, sulfonic acid or salt thereof, l is 0 or an integer of 1 - 4, and m and n an integer of 1 - 15; (c) a poly(alkylene oxide)glycol or a diol of the formula: HO - R - OH (IV) wherein R is alkylene, alkylidene, cycloalkylidene or arylalkylidene; and (d) a dicarboxylic acid; wherein the content of the polyether-ester units is 10 to 90 wt.%. The polyether-ester amide is used preferably as a blend thereof with a graft copolymerization product formed by graft-polymerizing (a) a rubbery polymer with (b) a monomer mixture of a methacrylic or acrylic acid ester, an aromatic vinyl monomer and an optional vinyl cyanide monomer, this product having a refractive index approximately similar to that of the polyether-ester amide.

公开(公告)号：ES2070853T3

公开(公告)日：1995-06-16

申请号：ES88307455

申请日：1988-08-11

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  YANO KAZUHISA ,  IWAMOTO MASATOSHI

IPC: C08G69/44 ,  C08G77/12 ,  C08L25/08 ,  C08L25/16 ,  C08L33/04 ,  C08L33/06 ,  C08L33/18 ,  C08L77/12 ,  C08L33/20 ,  C08L33/24 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L63/08 ,  C08L73/00 ,  C08L77/00

Abstract: A transparent polyether-ester amide having a permanently antistatic property is obtained by copolymerizing (a) an aminocarboxylic acid, a lactam, or a salt derived from a diamine and a dicarboxylic acid; (b) a diol of the formula: wherein R and R are an ethylene oxide or propylene oxide group, Y is covalent bond, alkylene, alkylidene, cycloalkylidene, arylalkylidene, O, SO, SO2 , CO, S, CF2 , C(CF3)2 or NH, X is H, alkyl, halogen, sulfonic acid or salt thereof, l is 0 or an integer of 1 - 4, and m and n an integer of 1 - 15; (c) a poly(alkylene oxide)glycol or a diol of the formula: HO - R - OH (IV) wherein R is alkylene, alkylidene, cycloalkylidene or arylalkylidene; and (d) a dicarboxylic acid; wherein the content of the polyether-ester units is 10 to 90 wt.%. The polyether-ester amide is used preferably as a blend thereof with a graft copolymerization product formed by graft-polymerizing (a) a rubbery polymer with (b) a monomer mixture of a methacrylic or acrylic acid ester, an aromatic vinyl monomer and an optional vinyl cyanide monomer, this product having a refractive index approximately similar to that of the polyether-ester amide.

公开(公告)号：DE3853180D1

公开(公告)日：1995-04-06

申请号：DE3853180

申请日：1988-08-11

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  YANO KAZUHISA ,  IWAMOTO MASATOSHI

IPC: C08L77/12 ,  C08G69/44 ,  C08G77/12 ,  C08L25/08 ,  C08L25/16 ,  C08L33/04 ,  C08L33/06 ,  C08L33/18 ,  C08L33/20 ,  C08L33/24 ,  C08L35/06 ,  C08L51/00 ,  C08L51/04 ,  C08L63/08 ,  C08L73/00 ,  C08L77/00

Abstract: A transparent polyether-ester amide having a permanently antistatic property is obtained by copolymerizing (a) an aminocarboxylic acid, a lactam, or a salt derived from a diamine and a dicarboxylic acid; (b) a diol of the formula: wherein R and R are an ethylene oxide or propylene oxide group, Y is covalent bond, alkylene, alkylidene, cycloalkylidene, arylalkylidene, O, SO, SO2 , CO, S, CF2 , C(CF3)2 or NH, X is H, alkyl, halogen, sulfonic acid or salt thereof, l is 0 or an integer of 1 - 4, and m and n an integer of 1 - 15; (c) a poly(alkylene oxide)glycol or a diol of the formula: HO - R - OH (IV) wherein R is alkylene, alkylidene, cycloalkylidene or arylalkylidene; and (d) a dicarboxylic acid; wherein the content of the polyether-ester units is 10 to 90 wt.%. The polyether-ester amide is used preferably as a blend thereof with a graft copolymerization product formed by graft-polymerizing (a) a rubbery polymer with (b) a monomer mixture of a methacrylic or acrylic acid ester, an aromatic vinyl monomer and an optional vinyl cyanide monomer, this product having a refractive index approximately similar to that of the polyether-ester amide.

公开(公告)号：JP2000143930A

公开(公告)日：2000-05-26

申请号：JP32550198

申请日：1998-11-16

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  TAMURA SHINICHI ,  TAMAI AKIYOSHI

IPC: C08J5/18 ,  C08K5/13 ,  C08K5/521 ,  C08L51/04 ,  C08L55/02

Abstract: PROBLEM TO BE SOLVED: To obtain a flame-retarded thermoplastic resin composition excellent in light resistance, rigidity, molding resistance, the flame retardance of a thin molded product and the drop impact resistance of the thin molded product and suitable for the thin molded products by adding a specific organic phosphorous compound and a specific cresol novolak resin in a specified ratio. SOLUTION: This flame-retarded thermoplastic resin composition comprises (A) 100 pts.wt. of a rubber-reinforced styrenic resin, (B) 1-20 pts.wt. of an organic phosphorous compound of formula I [X is a group of formula II or III (R1 to R8 are each H or a 1-5C alkyl) or the like; Ar1 to Ar4 are each (substituted) phenyl; (n) is 0 or larger; (k) and (m) are each 0-2, respectively, provided that (k)+(m)=0 to 2], and (C) 0.1-10 pts.wt. of a non-thermally reactive cresol novolak resin containing p-cresol residues in an amount of >=40 mol.%.

公开(公告)号：JP2000109636A

公开(公告)日：2000-04-18

申请号：JP28268298

申请日：1998-10-05

Applicant: TORAY INDUSTRIES

Inventor： FUKUMOTO TADAO ,  TAMURA SHINICHI

IPC: B29C45/00 ,  B29K25/00 ,  B29K55/00 ,  C08F2/38 ,  C08K3/22 ,  C08K5/521 ,  C08L25/16 ,  C08L51/04 ,  C08L55/02

Abstract: PROBLEM TO BE SOLVED: To obtain a resin composition excellent in moldability and desirable for a thin-wall molding having well-balanced and excellent flame retardancy, impact resistance, rigidity, heat resistance, and moldability by mixing a modified rubber-reinforced styrene resin with an organic phosphorus compound, a phenolic resin, and a colorant in a specified ratio. SOLUTION: This composition comprises 100 pts.wt. (A) modified rubber- reinforced styrene resin containing 1-20 wt.% α-methylstyrene residues and/or maleimido residues represented by formula I, 1-20 pts.wt. (B) organic phosphorus compound represented by formula II, 0.1-10 pts.wt. (C) phenolic resin, and 0.1-5 pts.wt. (D) colorant in a C/D ratio of 90/10 to 10/90 by weight. In formula I, R is hydrogen, a 1-5C alkyl, or the like. In formula II, X is formula III, IV, or V; R1 to R8 are each H or a 1-5C alkyl; Ar1, Ar2, Ar3, and Ar4 are each a (substituted)phenyl; Y is a direct bond, S, or the like; n is an integer of 0 or greater; and k and m are each an integer of 0-2, provided that k+m is an integer of 0-2.