Abstract:
This invention provides a moisture-permeable, waterproof film characterized in that it consists of two or more resin layers comprising, as polymerizing components, bishidroxyalkyl aliphatic acid and alkyleneglycol, said bishydroxyalkyl aliphatic acid content is 0.08 mmol/g to 0.5 mmol/g, at least a part of said alykyleneglycol is polyethylene glycol contained in an amount of 40 wt % to 80 wt % based on said solid resin, and a moisture permeability by JIS L-1099 "Potassium Acetate Method" (B-1 method) at average film thickness of 20 micrometers being not less than 3x103 g/m2.24 h and not more than 200x103 g/m2.24 h, and a moisture-permeable waterproof composite material to which said moisture-permeable, waterproof film is provided at least on one surface of a substrate material and its moisture permeability by JIS L-1099 "Potassium Acetate Method" (B-1 method) being not less than 1x103 g/m2.24 h and not more than 50x103 g/m2.24 h. This invention makes use of a polymer having excellent moisture permeability, waterproofness durability and capability of being made aqueous, and accordingly, this invention provides a moisture-permeable, waterproof film and a composite material which can be manufactured by an ecological process.
Abstract:
This invention provides a moisture-permeable, waterproof film characterized in that it consists of two or more resin layers comprising, as polymerizing components, bishidroxyalkyl aliphatic acid and alkyleneglycol, said bishydroxyalkyl aliphatic acid content is 0.08 mmol/g to 0.5 mmol/g, at least a part of said alykyleneglycol is polyethylene glycol contained in an amount of 40 wt% to 80 wt% based on said solid resin, and a moisture permeability by JIS L-1099 "Potassium Acetate Method" (B-1 method) at average film thickness of 20 micrometers being not less than 3 × 10 3 g/m2 - 24h and not more than 200 × 10 3 g/m2 .cndot. 24h, and a moisture-permeable waterproof composite material to which said moisture-permeable, waterproof film is provided at least on one surface of a substrate material and its moisture permeability by JIS L-1099 "Potassium Acetate Method" (B-1 method) being not less than 1 × 10 3 g/m2 -24h and not more than 50 × 10 3 g/m2 .cndot. 24h . This invention makes use of a polymer having excellent moisture permeability, waterproofness durability and capability of being made aqueous, and accordingly, this invention provides a moisture-permeable, waterproof film and a composite material which can be manufactured by an ecological process.
Abstract:
A moisture-permeable waterproof film characterized by comprising a resin layer which comprises two or more resins made up of monomer units comprising bishydroxyalkylfatty acid units and polyalkylene glycol units, the content of the bishydroxyalkylfatty acid units in each resin being 0.08 to 0.5 mmol per gram of the resin on a solid basis and the content of the polyalkylene glycol moieties in each resin being 40 to 80 wt.% on a solid basis, and by having a moisture permeability of 3×103 to 200×103 g/m2·24 h as measured by the potassium acetate method (method B-1) in accordance with JIS L-1099 when the film has an average thickness of 20 µm; and a moisture-permeable waterproof composite material which comprises a base and the film disposed at least on one side thereof and has a moisture permeability of 1×103 to 50×103 g/m2·24 h as measured by the potassium acetate method (method B-1) in accordance with JIS L-1099. Polymers which are excellent in moisture permeability, waterproofness, and durability and can be produced in the form of a water-compatible resin are used. Because of this, the moisture-permeable waterproof film and composite material can be produced by a process in which the burden to be imposed on the environment is lessened.
Abstract:
Disclosed is a sheet-like material which is produced by an environmentally friendly procedure and has an elegant appearance with piloerection, good wear resistance and good texture. Specifically disclosed is a sheet-like material which is characterized by containing a water-dispersed polyurethane within a fibrous base that contains extra-fine fibers having an average single fiber diameter of 0.3-7 um. The sheet-like material is also characterized in that the inside of the water-dispersed polyurethane is provided with pores each having a diameter of 10-200 um. Also specifically disclosed is a method for producing a sheet-like material by applying a polyurethane liquid to a fibrous base, which is characterized in that the polyurethane liquid is a water-dispersed polyurethane liquid that contains a foaming agent and a dry film of the polyurethane that constitutes the polyurethane liquid has a 100% modulus of 3-8 MPa.
Abstract:
PROBLEM TO BE SOLVED: To provide a comfortable moisture-permeable water-proofing material giving little filmy feeling and having soft touch. SOLUTION: The moisture-permeable water-proofing material has at least one resin layer on one side of a fiber structure and a waterproofness of 0.05-1.0 MPa and satisfies the following requirements at the same time. (1) The area S of the resin on the thickness cross-section of the material and the resin area (s) at the side of the fiber structure relative to a boundary line formed by continuously connecting the common tangential lines at the outermost faces of single fibers positioned at the outermost part of the warps and wefts constituting the fiber structure satisfy the formula 80 COPYRIGHT: (C)2003,JPO