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公开(公告)号：CA2772028C
公开(公告)日：2013-05-28
申请号：CA2772028
申请日：2005-04-21
Applicant: TORAY INDUSTRIES
Inventor： MASUDA JUN ICHI , OHKURA MASATOSHI , TANAKA SHIGERU , MORITA REIKO , FUKUSHIMA HAJIME
Abstract: The present invention provides a microporous polypropylene film where film formability is improved in accordance with a .beta.-crystal technique which allows microporous films to be continuously manufactured at low cost. In addition, a microporous polypropylene film of which the specific gravity is further reduced is provided. Furthermore, a microporous polypropylene film with a significantly high permeability is provided. In addition, manufacturing methods for these microporous polypropylene films are provided. As for the means for solving the above, a microporous polypropylene film comprising a polypropylene with the Trouton ratio of not less than 30, a microporous polypropylene film with the Trouton ratio of not less than 6, a microporous polypropylene film comprising a polypropylene having a long chain branch in the main chain, a microporous polypropylene film comprising a polypropylene where the relationship between the melt strength (MS) and the melt flow rate (MFR), measured at 230 °C , can be represented by the following formula (1) and/or the melt strength (MS) , measured at 230 °C , is less than 5 cN and the relationship between the MS and the melt flow rate (MFR) can be represented by the following formula (2), or a microporous polypropylene film where the following formula (3) is satisfied in the in-plane intensity distribution profile scanned in the direction of an azimuthal angle for (-113) plane in accordance with X-ray diffraction method, and which has a .beta.-crystal activity and a specific gravity of 0.1 to 0.6 and/or a porosity of 30 % to 95 %. log (MS) > -0.61 log (MFR) + 0.82 (1) log (MS) > -0.9 log (MFR) + 0.6 (2) 0.5
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公开(公告)号：CA2771872C
公开(公告)日：2013-10-01
申请号：CA2771872
申请日：2005-04-21
Applicant: TORAY INDUSTRIES
Inventor： MASUDA JUN ICHI , OHKURA MASATOSHI , TANAKA SHIGERU , MORITA REIKO , FUKUSHIMA HAJIME
Abstract: The present invention provides a microporous polypropylene film where film formability is improved in accordance with a .beta.-crystal technique which allows microporous films to be continuously manufactured at low cost. In addition, a microporous polypropylene film of which the specific gravity is further reduced is provided. Furthermore, a microporous polypropylene film with a significantly high permeability is provided. In addition, manufacturing methods for these microporous polypropylene films are provided. As for the means for solving the above, a microporous polypropylene film comprising a polypropylene with the Trouton ratio of not less than 30, a microporous polypropylene film with the Trouton ratio of not less than 6, a microporous polypropylene film comprising a polypropylene having a long chain branch in the main chain, a microporous polypropylene film comprising a polypropylene where the relationship between the melt strength (MS) and the melt flow rate (MFR), measured at 230 °C , can be represented by the following formula (1) and/or the melt strength (MS) , measured at 230 °C , is less than 5 cN and the relationship between the MS and the melt flow rate (MFR) can be represented by the following formula (2), or a microporous polypropylene film where the following formula (3) is satisfied in the in-plane intensity distribution profile scanned in the direction of an azimuthal angle for (-113) plane in accordance with X-ray diffraction method, and which has a .beta.-crystal activity and a specific gravity of 0.1 to 0.6 and/or a porosity of 30 % to 95 %. log (MS) > -0.61 log (MFR) + 0.82 (1) log (MS) > -0.9 log (MFR) + 0.6 (2) 0.5
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公开(公告)号：DE602005026121D1
公开(公告)日：2011-03-10
申请号：DE602005026121
申请日：2005-04-21
Applicant: TORAY INDUSTRIES
Inventor： MASUDA JUN ICHI , OHKURA MASATOSHI , TANAKA SHIGERU , MORITA REIKO , FUKUSHIMA HAJIME
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公开(公告)号：AT429330T
公开(公告)日：2009-05-15
申请号：AT04807409
申请日：2004-12-21
Applicant: TORAY INDUSTRIES
Inventor： TANAKA SHIGERU , OHKURA MASATOSHI , MASUDA JUN ICHI , TONEGAWA KOUICHI , MORITA REIKO
Abstract: [Problem to be Solved] To provide a biaxially oriented white film for thermal transfer recording which has low specific gravity required as a thermal transfer film, high whiteness and cushion factor, and is excellent in crease resistance, and has a high-level compatibility between high sensitivity and productivity when used as a substrate of a receiving sheet, and a receiving sheet for thermal transfer recording using the same. [Means for Solving the Problem] (1) A biaxially oriented white polypropylene film for thermal transfer recording characterized in that it is a film comprising of polypropylene resin of which ²-crystal ratio is 30% or more and melting temperature is 140 to 172°C, which has a substantially non-nucleus voids, a void ratio of 30 to 80% and a sum of strengths of longitudinal direction and of transverse direction of the film at 2% elongation (F2 value) being in the range of 10 to 70 MPa and a surface glossiness being in the range of 10 to 145 % (the first configuration). (2) A biaxially oriented white polypropylene film for thermal transfer recording characterized in that a skin layer (B layer) of which surface glossiness is 10 to 145 % is laminated to at least one side of a core layer (A layer) of polypropylene resin of which ²-crystal ratio is 30% or more, melting temperature is 140 to 172°C, which has a substantially non-nucleus voids, a void ratio of 30 to 80%, and a sum of the strengths of longitudinal direction and of transverse direction of the film at 2% elongation (F2 value) being in the range of 10 to 70 MPa (the second configuration). (3) A biaxially oriented white polypropylene film for thermal transfer recording in which a skin layer (B layer) of which surface glossiness is in the range of 10 - 145 % is laminated to at least one side of a core layer (A layer) characterized in that a sum of strengths of longitudinal direction and of transverse direction of the film at 2% elongation (F2 value) is in the range of 30 to 100 MPa and that the film has ²-crystal activity (the third configuration). (4) A biaxially oriented white polypropylene film for thermal transfer recording which is a film in which a skin layer (B layer) having a half-crystallization time of 60 seconds or less and a surface glossiness of 30 to 145 % is laminated at least on one side of a core layer (A layer) which consists of polypropylene resin having a substantially non-nucleus void, characterized in that it is a film of a specific gravity of 0.3 to 0.7 and has ²-crystal activity (the fourth configuration).
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5.发明专利
公开(公告)号：CA2563787C
公开(公告)日：2013-05-21
申请号：CA2563787
申请日：2005-04-21
Applicant: TORAY INDUSTRIES
Inventor： MASUDA JUN ICHI , OHKURA MASATOSHI , TANAKA SHIGERU , MORITA REIKO , FUKUSHIMA HAJIME
Abstract: The present invention provides a microporous polypropylene film where film formability is improved in accordance with a .beta.-crystal technique which allows microporous films to be continuously manufactured at low cost. In addition, a microporous polypropylene film of which the specific gravity is further reduced is provided. Furthermore, a microporous polypropylene film with a significantly high permeability is provided. In addition, manufacturing methods for these microporous polypropylene films are provided. As for the means for solving the above, a microporous polypropylene film comprising a polypropylene with the Trouton ratio of not less than 30, a microporous polypropylene film with the Trouton ratio of not less than 6, a microporous polypropylene film comprising a polypropylene having a long chain branch in the main chain, a microporous polypropylene film comprising a polypropylene where the relationship between the melt strength (MS) and the melt flow rate (MFR), measured at 230 °C , can be represented by the following formula (1) and/or the melt strength (MS), measured at 230 °C , is less than 5 cN and the relationship between the MS and the melt flow rate (MFR) can be represented by the following formula (2), or a microporous polypropylene film where the following formula (3) is satisfied in the in-plane intensity distribution profile scanned in the direction of an azimuthal angle for (-113) plane in accordance with X-ray diffraction method, and which has a beta.-crystal activity and a specific gravity of 0.1 to 0.6 and/or a porosity of 30 % to 95 %. log (MS) > -0.61 log (MFR) + 0.82 (1) log (MS) > -0.9 log (MFR) + 0.6 (2) 0.5
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Patent Agency Ranking
公开(公告)号：CA2551526C
公开(公告)日：2012-11-13
申请号：CA2551526
申请日：2004-12-21
Applicant: TORAY INDUSTRIES
Inventor： TANAKA SHIGERU , OHKURA MASASHI , MASUDA JUN ICHI , TONEGAWA KOUICHI , MORITA REIKO
Abstract: With white films or micro-porous films for thermal transfer recording in the prior art involving .beta.-crystal transitions, production of the film and receiving sheet were not compatible, at a high level, with the sensitivity of the receiving sheet. The present invention relates to a biaxially oriented white film for thermal transfer recording which has low specific gravity required as a thermal transfer film, high whiteness and cushion factor, and is excellent in crease resistance, and has a high--level compatibility between high sensitivity and productivity when used as a substrate of a receiving sheet, and a receiving sheet for thermal transfer recording using the same.
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公开(公告)号：CA2563787A1
公开(公告)日：2005-11-03
申请号：CA2563787
申请日：2005-04-21
Applicant: TORAY INDUSTRIES
Inventor： MASUDA JUN ICHI , TANAKA SHIGERU , OHKURA MASATOSHI , FUKUSHIMA HAJIME , MORITA REIKO
Abstract: The present invention provides a microporous polypropylene film where film formability is improved in accordance with a ²-crystal technique which allows microporous films to be continuously manufactured at low cost. In addition, a microporous polypropylene film of which the specific gravity is further reduced is provided. Furthermore, a microporous polypropylene film with a significantly high permeability is provided. In addition, manufacturing methods for these microporous polypropylene films are provided. As for the means for solving the above, a microporous polypropylene film comprising a polypropylene with the Trouton ratio of not less than 30, a microporous polypropylene film with the Trouton ratio of not less than 6, a microporous polypropylene film comprising a polypropylene having a long chain branch in the main chain, a microporous polypropylene film comprising a polypropylene where the relationship between the melt strength (MS) and the melt flow rate (MFR), measured at 230 °C, can be represented by the following formula (1) and/or the melt strength (MS), measured at 230 °C, is less than 5 cN and the relationship between the MS and the melt flow rate (MFR) can be represented by the following formula (2), or a microporous polypropylene film where the following formula (3) is satisfied in the in-plane intensity distribution profile scanned in the direction of an azimuthal angle for (-113) plane in accordance with X-ray diffraction method, and which has a ²-crystal activity and a specific gravity of 0.1 to 0.6 and/or a porosity of 30 % to 95 %. log MS > - 0.61 log MFR + 0.82 log MS > - 0.9 log MFR + 0.6 0.5 ‰¤ I MD / I TD ‰¤ 8 [Here, I (MD) is the integral intensity in the longitudinal direction and I (TD) is the integral intensity in the transverse direction.]
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公开(公告)号：AU2005235863A1
公开(公告)日：2005-11-03
申请号：AU2005235863
申请日：2005-04-21
Applicant: TORAY INDUSTRIES
Inventor： OHKURA MASATOSHI , MASUDA JUN ICHI , FUKUSHIMA HAJIME , MORITA REIKO , TANAKA SHIGERU
IPC: C08J9/00
Abstract: The present invention provides a microporous polypropylene film where film formability is improved in accordance with a ²-crystal technique which allows microporous films to be continuously manufactured at low cost. In addition, a microporous polypropylene film of which the specific gravity is further reduced is provided. Furthermore, a microporous polypropylene film with a significantly high permeability is provided. In addition, manufacturing methods for these microporous polypropylene films are provided. As for the means for solving the above, a microporous polypropylene film comprising a polypropylene with the Trouton ratio of not less than 30, a microporous polypropylene film with the Trouton ratio of not less than 6, a microporous polypropylene film comprising a polypropylene having a long chain branch in the main chain, a microporous polypropylene film comprising a polypropylene where the relationship between the melt strength (MS) and the melt flow rate (MFR), measured at 230 °C, can be represented by the following formula (1) and/or the melt strength (MS), measured at 230 °C, is less than 5 cN and the relationship between the MS and the melt flow rate (MFR) can be represented by the following formula (2), or a microporous polypropylene film where the following formula (3) is satisfied in the in-plane intensity distribution profile scanned in the direction of an azimuthal angle for (-113) plane in accordance with X-ray diffraction method, and which has a ²-crystal activity and a specific gravity of 0.1 to 0.6 and/or a porosity of 30 % to 95 %. log MS > - 0.61 log MFR + 0.82 log MS > - 0.9 log MFR + 0.6 0.5 ‰¤ I MD / I TD ‰¤ 8 [Here, I (MD) is the integral intensity in the longitudinal direction and I (TD) is the integral intensity in the transverse direction.]
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公开(公告)号：AT496963T
公开(公告)日：2011-02-15
申请号：AT05734391
申请日：2005-04-21
Applicant: TORAY INDUSTRIES
Inventor： MASUDA JUN ICHI , OHKURA MASATOSHI , TANAKA SHIGERU , MORITA REIKO , FUKUSHIMA HAJIME
Abstract: The present invention provides a microporous polypropylene film where film formability is improved in accordance with a ²-crystal technique which allows microporous films to be continuously manufactured at low cost. In addition, a microporous polypropylene film of which the specific gravity is further reduced is provided. Furthermore, a microporous polypropylene film with a significantly high permeability is provided. In addition, manufacturing methods for these microporous polypropylene films are provided. As for the means for solving the above, a microporous polypropylene film comprising a polypropylene with the Trouton ratio of not less than 30, a microporous polypropylene film with the Trouton ratio of not less than 6, a microporous polypropylene film comprising a polypropylene having a long chain branch in the main chain, a microporous polypropylene film comprising a polypropylene where the relationship between the melt strength (MS) and the melt flow rate (MFR), measured at 230 °C, can be represented by the following formula (1) and/or the melt strength (MS), measured at 230 °C, is less than 5 cN and the relationship between the MS and the melt flow rate (MFR) can be represented by the following formula (2), or a microporous polypropylene film where the following formula (3) is satisfied in the in-plane intensity distribution profile scanned in the direction of an azimuthal angle for (-113) plane in accordance with X-ray diffraction method, and which has a ²-crystal activity and a specific gravity of 0.1 to 0.6 and/or a porosity of 30 % to 95 %. log MS > - 0.61 log MFR + 0.82 log MS > - 0.9 log MFR + 0.6 0.5 ‰¤ I MD / I TD ‰¤ 8 [Here, I (MD) is the integral intensity in the longitudinal direction and I (TD) is the integral intensity in the transverse direction.]
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公开(公告)号：CA2772028A1
公开(公告)日：2005-11-03
申请号：CA2772028
申请日：2005-04-21
Applicant: TORAY INDUSTRIES
Inventor： MASUDA JUN ICHI , OHKURA MASATOSHI , TANAKA SHIGERU , MORITA REIKO , FUKUSHIMA HAJIME
Abstract: The present invention provides a microporous polypropylene film where film formability is improved in accordance with a .beta.-crystal technique which allows microporous films to be continuously manufactured at low cost. In addition, a microporous polypropylene film of which the specific gravity is further reduced is provided. Furthermore, a microporous polypropylene film with a significantly high permeability is provided. In addition, manufacturing methods for these microporous polypropylene films are provided. As for the means for solving the above, a microporous polypropylene film comprising a polypropylene with the Trouton ratio of not less than 30, a microporous polypropylene film with the Trouton ratio of not less than 6, a microporous polypropylene film comprising a polypropylene having a long chain branch in the main chain, a microporous polypropylene film comprising a polypropylene where the relationship between the melt strength (MS) and the melt flow rate (MFR), measured at 230 °C , can be represented by the following formula (1) and/or the melt strength (MS) , measured at 230 °C , is less than 5 cN and the relationship between the MS and the melt flow rate (MFR) can be represented by the following formula (2), or a microporous polypropylene film where the following formula (3) is satisfied in the in-plane intensity distribution profile scanned in the direction of an azimuthal angle for (-113) plane in accordance with X-ray diffraction method, and which has a .beta.-crystal activity and a specific gravity of 0.1 to 0.6 and/or a porosity of 30 % to 95 %. log (MS) > -0.61 log (MFR) + 0.82 (1) log (MS) > -0.9 log (MFR) + 0.6 (2) 0.5
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