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公开(公告)号：AU2018343713A1
公开(公告)日：2020-01-16
申请号：AU2018343713
申请日：2018-09-20
Applicant: TORAY INDUSTRIES
Inventor： HIRANO MASANORI , TOMIOKA NOBUYUKI
Abstract: The purpose of the present invention is to provide: a thermosetting resin composition for a fiber-reinforced composite material, the thermosetting resin composition having an excellent balance of rapid curability and storage stability as well as excellent handleability at normal temperature and ability to impregnate a reinforcing fiber base material; and a preform for a fiber-reinforced composite material and a fiber-reinforced composite material that use the same. To achieve this purpose, the first embodiment of the thermosetting resin composition for a fiber-reinforced composite material according the present invention has the following constitution. Specifically, a thermosetting resin composition for a fiber-reinforced composite material having domains of each of [A] a base compound and [B] a curing agent and/or [C] a catalyst and having a specific gravity of 0.90-1.30 and a complex viscosity η* of 1 x 10 7 Pa·s or higher in dynamic viscoelasticity measurement at 25°C.
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公开(公告)号：AU2018293968A1
公开(公告)日：2019-11-07
申请号：AU2018293968
申请日：2018-06-05
Applicant: TORAY INDUSTRIES
Inventor： HIRANO MASANORI , TOMIOKA NOBUYUKI
IPC: C08J5/24
Abstract: The present invention addresses the problem of providing a preform having exceptional handling at normal temperature and little composition unevenness during curing, a thermosetting resin composition having an exceptional ability to impregnate reinforcing fibers used in the preform, and a fiber-reinforced composite material obtained by using the same. A preform for a fiber-reinforced composite material containing a thermosetting resin composition and a dry reinforcing fiber substrate, the thermosetting resin composition of the preform for a fiber-reinforced composite material having a temperature change ΔT of 45°C or less when the complex viscosity η
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公开(公告)号：CA2842643A1
公开(公告)日：2013-01-31
申请号：CA2842643
申请日：2012-07-25
Applicant: TORAY INDUSTRIES
Inventor： SHIMIZU YUKO , TOMIOKA NOBUYUKI , HONDA SHIROU , NAGANO MAKI , ECHIGO YUJI , TAKEZAKI HIROSHI , KAWASAKI JUNKO , TAIKO HIROSHI
IPC: C08J5/24
Abstract: Provided is a prepreg for obtaining a fiber-reinforced composite material which combines stable impact resistance and interlaminar toughness with compressive strength under wet heat conditions. The prepreg comprises an epoxy resin, reinforcing fibers, and polymer particles [C] which are insoluble in the epoxy resin and are either [Cx] or [Cy], wherein 90% or more of [C] are present in the range of from one or each surface of the prepreg to a depth corresponding to 20% of the thickness of the prepreg. [Cx] Polymer particles giving a particle diameter distribution chart (x-i) which has at least two peaks and (x-ii) in which the particle diameter ratio between the two highest peaks is in the range of 1.5-7 and (x-iii) in which the peak, of the two highest peaks, that is located on the larger-particle-diameter side has a half-value width in the range of 1.1-3. [Cy] Polymer particles (y-i) which have an average particle diameter which is 1-18 µm or is larger than 12 µm but not larger than 50 µm, (y-ii) which have a degree of sphericity of 90-100, and (y-iii) which have a glass transition temperature of 80-155ºC.
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公开(公告)号：ES2908294T3
公开(公告)日：2022-04-28
申请号：ES18805134
申请日：2018-05-21
Applicant: TORAY INDUSTRIES
Inventor： HONDO KAZUNORI , ISHIKAWA NORIKAZU , HIRANO MASANORI , TOMIOKA NOBUYUKI
Abstract: Una composición de resina epoxi para materiales compuestos reforzados con fibras que comprende los siguientes componentes (A) a (E): componente (A): una resina epoxi componente (B): una diciandiamida o un derivado de la misma componente (C): un compuesto poliisocianato, y componente (D): un compuesto de urea representado por la fórmula (1): **(Ver fórmula)** (en la que R1 y R2 son cada uno independientemente H, CH3, OCH3, OC2H5, NO2, halógeno, o NH-CO-NR3R4; y R3 y R4 son cada uno independientemente un grupo hidrocarburo, grupo alilo, grupo alcoxi, grupo alquenilo, grupo aralquilo, o un compuesto alicíclico que contiene a la vez R3 y R4, conteniendo todos de 1 a 8 átomos de carbono), y componente (E): al menos un compuesto seleccionado del grupo que consiste en sales de amonio cuaternario, sales de fosfonio, compuestos de imidazol y compuestos de fosfina.
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公开(公告)号：ES2773002T3
公开(公告)日：2020-07-09
申请号：ES16850830
申请日：2016-07-21
Applicant: TORAY INDUSTRIES
Inventor： NAGANO MAKI , FUSE AYAKO , TOMIOKA NOBUYUKI
IPC: C08G59/20 , C08G59/24 , C08G59/28 , C08G59/30 , C08G59/50 , C08J5/24 , C08K5/315 , C08K5/41 , C08L63/00 , C08L101/00
Abstract: Una composición de resina epoxídica, que comprende al menos los componentes [A], [B] y [C], tal y como se relaciona a continuación: [A] una resina epoxídica como la representada por la Fórmula 1 o una resina epoxídica como la representada por la Fórmula 2, [A] representa de 15 a 70 partes en masa con respecto a la cantidad total de resina epoxídica, que representa 100 partes en masa, cuando [A] es una resina epoxídica como la representada por la Fórmula 1: **(Ver fórmula)** en las que cada R1 de la Formula 1 y de la Fórmula 2 es un átomo de hidrógeno o un grupo metilo, no siendo la pluralidad de R1 necesariamente idéntica entre sí; R2 a R6 son cada uno un grupo sustituyente seleccionado entre el grupo, que consiste en un grupo alquilo, que contiene de 1 a 10 átomos de carbono, un grupo cicloalquilo, que contiene de 6 a 15 átomos de carbono, un grupo arilo, que contiene de 6 a 18 átomos de carbono, un átomo de hidrógeno y un átomo de halógeno; cada k, que denota el número de sustituyentes, es un número entero de 0 a 4, no siendo la k necesariamente idéntica entre sí; n, que denota el número de unidades de repetición, es un número entero de 0 o más; X, que denota un grupo de unión, es uno seleccionado entre el grupo que consiste en -C(Y)(Z)- (en donde Y y Z son cada uno un grupo alquilo que contiene de 1 a 10 átomos de carbono, un grupo cicloalquilo, que contiene de 6 a 15 átomos de carbono, un grupo arilo, que contiene de 6 a 18 átomos de carbono, un átomo de hidrógeno o un átomo de halógeno, siendo Y y Z idénticos o diferentes entre sí), -C(=O)NH-, -C(=O)O-, -S(=O)2- , -C(=O)-, -O-, -S-, y- (sin átomos); [B] al menos un componente seleccionado entre el grupo, que consiste en resinas termoplásticas, que es compatible con la resina epoxídica [A] y con los polímeros de núcleo-envoltura; y [C] agente de curado de amina.
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Patent Agency Ranking
公开(公告)号：BRPI0507208A
公开(公告)日：2007-06-12
申请号：BRPI0507208
申请日：2005-03-02
Applicant: TORAY INDUSTRIES
Inventor： KUROKI MOTOHIRO , TOMIOKA NOBUYUKI , WADAHARA NAOMI , YOSHIOKA KENICHI , SAKATA HIROAKI , WADAHARA EISUKE , OOSEDO HIROKI
Abstract: The invention provides epoxy resin composition containing, as epoxy resin, the following epoxy resin (a) and epoxy resin (b), solid rubber at a ratio of 1 to 20 parts by weight to 100 parts by weight of the entire epoxy resins, and an aromatic amine as a curing agent and having a glass transition temperature of 160 to 220°C in form of a cured material after heat curing at 180°C for 2 hours: (a) an epoxy resin having oxazolidone rings and (b) a glycidylamine type epoxy resin.
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公开(公告)号：DE69822287D1
公开(公告)日：2004-04-15
申请号：DE69822287
申请日：1998-12-01
Applicant: TORAY INDUSTRIES
Inventor： NINOMIYA HIROAKI , TOMIOKA NOBUYUKI , TERASHITA TAKESHI , NAGATA HIDEO , KISHI HAJIME
IPC: C08L61/06 , C09D161/06
Abstract: The phenolic resin composition for fiber-reinforced composite materials of the invention comprises at least the following constituent elements A and B of a thermoplastic resin: A: phenolic resin, B: at least one thermoplastic resin selected from polyvinyl formals, polyvinyl acetals, polyvinyl butyrals, polyvinyl pyrrolidones, polyvinyl acetates, polyvinyl alcohols, polyethylene glycols, copolymerized nylons and dimer acid polyamides. The resin composition is filmwise applied to reinforcing fibers, and the resulting film is heated under pressure whereby it is impregnated into the reinforcing fibers to give a prepreg for fiber-reinforced composite materials.
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公开(公告)号：AU2021217266A1
公开(公告)日：2022-08-18
申请号：AU2021217266
申请日：2021-01-27
Applicant: TORAY INDUSTRIES
Inventor： MATSUKAWA KO , KOYANAGI SHIZUE , HIRANO MASANORI , TOMIOKA NOBUYUKI
Abstract: The purpose of the present invention is to provide: a molding material from which a carbon fiber reinforced composite material having excellent impact resistance and tensile strength is obtained; and a molding material from which a glass fiber reinforced composite material, that has high bending strength and impact resistance, has excellent weather resistance, and can suppress a decrease in bending strength after water absorption, is obtained. In order to achieve the purpose, the molding material according to the present invention is a molding material formed of an epoxy resin composition and a carbon fiber and/or a glass fiber, wherein the epoxy resin composition includes all of [A] to [C], the carbon fiber satisfies conditions [a] and [b], and the glass fiber has a surface functional group capable of forming a covalent bond with an isocyanate group. [A] Epoxy resin having at least two oxylan groups in molecule [B] Epoxy resin curing agent having at least two isocyanate groups in molecule [C] Catalyst [a] Having substantially perfect circular cross section [b] Average fiber diameter of 4.0-8.0 μm
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公开(公告)号：RU2715237C1
公开(公告)日：2020-02-26
申请号：RU2018116012
申请日：2016-07-21
Applicant: TORAY INDUSTRIES
Inventor： NAGANO MAKI , FUSE AYAKO , TOMIOKA NOBUYUKI
Abstract: Изобретениеотноситсяк композицииэпоксиднойсмолы, препрегуи композитномуматериалу, которыйможетбытьпримененв аэрокосмическойпромышленностиилидляпроизводстваспортивныхтоваров. Композицияэпоксиднойсмолысодержитпоменьшеймереодинкомпонент [A], выбранныйизгруппыглицидильногосоединения 2,2'-бифенола, 2,2'-дигидроксидифенилметана, 2,2'-метилен-бис(4-метилфенола), 2,2'-изопропилидендифенола, 2,2'-тиодифенолаи 2,2'-оксидифенола, илиглицидильноесоединение 2-аминофенола; поменьшеймереодинкомпонент [B], выбранныйизгруппы, состоящейизтермопластичныхсмол, которыесовместимыс [A], илиполимеровтипасердцевина-оболочка; поменьшеймереодинкомпонент [C], представляющийсобойаминовыйотверждающийагент. Компонент [A] составляетот 15 до 70 частеймассовыхпоотношениюк общемуколичествуэпоксиднойсмолы. Препрегполучаютимпрегнированиемармирующеговолокнавышеуказаннойкомпозиции. Композитныйматериал, армированныйволокнами, получаютотверждениемвышеуказанногопрепрега. Композитныйматериалсодержитматериалотвержденнойэпоксиднойсмолы, полученнойотверждениемкомпозицииэпоксиднойсмолы, иармирующееволокно. Изобретениепозволяетполучитьотвержденнуюкомпозицию, котораяимеетвысокиймодульупругостии высокуюноминальнуюдеформациюсжатияприразрыве, атакжеполучитькомпозитныйматериал, имеющийпревосходнуюпрочностьприсжатиии межслойнуюжесткость. 4 н. и 8 з.п. ф-лы, 11 табл., 29 пр.
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公开(公告)号：CA2825080A1
公开(公告)日：2012-08-02
申请号：CA2825080
申请日：2012-01-20
Applicant: TORAY INDUSTRIES
Inventor： GOTO YUKO , TOMIOKA NOBUYUKI , ECHIGO YUJI , SAKATA HIROAKI , HONDA SHIRO , TAIKO HIROSHI
Abstract: Provided are: a fiber-reinforced composite material which has mode I interlaminar fracture toughness, mode II interlaminar fracture toughness and compressive strength under wet heat conditions at the same time; an epoxy resin composition for obtaining the fiber-reinforced composite material; and a prepreg which is obtained using the epoxy resin composition. An epoxy resin composition for fiber-reinforced composite materials, which contains at least the following constituent elements (A), (B), (C) and (D). (A) An epoxy resin (B) Resin particles that satisfy the following conditions (b1)-(b3) and are insoluble in an epoxy resin (b1) The particle size distribution index is 1.0-1.8. (b2) The particle sphericity is 90 or more. (b3) The glass transition temperature of the particles is 80-180°C. (C) At least one elastomer component that is selected from among block copolymers containing a block having a glass transition temperature of 20°C or less and rubber particles (D) An epoxy resin curing agent
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