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公开(公告)号:JP2001187859A
公开(公告)日:2001-07-10
申请号:JP2000283187
申请日:2000-09-19
Applicant: TORAY INDUSTRIES
Inventor: ANDO ARIYOSHI , OSANAI YOSHITAKA , YANAI HIDEKI
IPC: C08G59/70 , C08F20/26 , C08F30/08 , C09D133/08 , C09D163/00 , C09D183/06
Abstract: PROBLEM TO BE SOLVED: To provide coating resin compositions which have good storage stability and excellent curability at low temperatures (
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公开(公告)号:JP2000080332A
公开(公告)日:2000-03-21
申请号:JP16319899
申请日:1999-06-10
Applicant: TORAY INDUSTRIES
Inventor: YANAI HIDEKI , ANDO ARIYOSHI , OSHIMA KEISUKE
IPC: C09D183/04 , C09D5/00 , C09D5/44 , C09D133/00 , C09D163/00
Abstract: PROBLEM TO BE SOLVED: To improve coating stability, flatting appearance, weatherability and gloss stability of flatting anion electrodeposition coating by a resin composition comprising an acrylic resin containing a carboxyl group, a specific organoalkoxysilane compound and an aluminum chelate compound. SOLUTION: In producing an acrylic resin, a polymerizable unsaturated carboxylic acid, a hydroxyl group-containing unsaturated monomer according to needs, an alkoxysilane group-containing unsaturated monomer or an epoxy group-containing unsaturated monomer are copolymerized to obtain an acrylic resin having a carboxyl group and a hydroxyl group or an epoxy group at a side chain or a termination of the copolymer. The acrylic resin has a hydroxyl value of 20-150 mgKOH/g, preferably 30-100 mgKOH/g and number average molecular weight of 2,000-70,000, preferably 4,000-50,000. A resin composition is obtained by compounding 100 pts.wt. of the acrylic resin, and 0.05-100 pts.wt. of an organoalkoxysilane compound having a glycidyl group and a hydrolyzable alkoxy silane group and 0.01-10 pts.wt. of an aluminum chelate compound.
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公开(公告)号:JP2000044864A
公开(公告)日:2000-02-15
申请号:JP21080598
申请日:1998-07-27
Applicant: TORAY INDUSTRIES
Inventor: YOSHIDA MINORU , YANAI HIDEKI
IPC: C09D133/00 , C09D161/20
Abstract: PROBLEM TO BE SOLVED: To obtain a resin composition for coatings capable of forming coating films having excellent appearance and design and hardly forming scratches, struck cracks, etc., by compounding an acrylic resin, an amino resin and inorganic particles having a primary particle diameter of a prescribed value or less and forming secondary aggregates. SOLUTION: This resin composition for coatings comprises (A) an acrylic resin copolymerized with a silane compound in an amount corresponding to the 0.01-1.0 wt.% as Si element, (B) an amino resin which is a triazine ring- having compound containing 1.5-6.0 >=2C alkoxymethyl groups per triazine ring, and (C) one or more kinds of inorganic particles having a primary particle diameter of =5, and selected from inactive inorganic particles such as δ type alumina. The components A and B are compounded in a ratio of 90/10 to 30/70, and the component C is preferably compounded in an amount of 0.05-10 pts.wt. per 100 pts.wt. of the component A.
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公开(公告)号:JP2001187860A
公开(公告)日:2001-07-10
申请号:JP2000293659
申请日:2000-09-27
Applicant: TORAY INDUSTRIES
Inventor: OSANAI YOSHITAKA , YANAI HIDEKI , ANDO ARIYOSHI
IPC: C09D133/14 , C09D163/00 , C09D183/06
Abstract: PROBLEM TO BE SOLVED: To provide coating resin composition which have good storage stability and excellent curability at low temperatures (
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公开(公告)号:JP2000086967A
公开(公告)日:2000-03-28
申请号:JP25807598
申请日:1998-09-11
Applicant: TORAY INDUSTRIES
Inventor: YANAI HIDEKI , OSANAI YOSHITAKA , KAGEISHI KAZUJI
IPC: C09D133/14 , C09D155/00 , C09D163/00
Abstract: PROBLEM TO BE SOLVED: To obtain a coating resin composition having excellent coating film performance and storage stability and exhibiting low-temperature curability by compounding a specific resin composition with an alicyclic epoxy resin. SOLUTION: The objective resin composition contains (A) 100 pts.wt. of an acrylic resin having epoxy group and hydroxyl group on the side chain, (B) 0.05-100 pts.wt. of an organoalkoxysilane compound having glycidyl group and hydrolyzable alkoxysilane group (e.g. γ-glycidoxypropyl trimethoxysilane), (C) 0.01-10 pts.wt. of an aluminum chelate compound (e.g. aluminum ethylacetoacetate diisopropylate) and (D) 5-50 pts.wt. of a compound of formula [R1 is CH2OCO or CH2OCHO(CH2)nCOOCH2; (n) is 1-5; R2 is H or a lower alkyl] (e.g. 3,4-epoxycyclohexylmethyl-3',4'-epoxycyclohexanecarbonate). The component A is preferably a graft copolymer copolymerized with 0.5-10 wt.% of a polyalkyl (meth)acrylate macromonomer.
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公开(公告)号:JP2001089194A
公开(公告)日:2001-04-03
申请号:JP26679999
申请日:1999-09-21
Applicant: TORAY INDUSTRIES
Inventor: ANDO ARIYOSHI , YANAI HIDEKI , OSANAI YOSHITAKA
IPC: C03C17/30 , C09D133/14 , C09D163/00 , C09D183/04
Abstract: PROBLEM TO BE SOLVED: To improve the design of the glass article, for example, transparency, opacity, coloration and the like by forming a specific coating layer on the surface of the glass article through a technique exerting small environmental load, and provide glass articles having excellent resistance to cracking and chemicals. SOLUTION: The objective glass article has the coating layer that includes 0.04-0.80 wt.% of aluminum(Al) originating from the organoaluminum compound and 2.35-11.0 wt.% of silicon(Si) originating from organic silane on the dry basis of the coating layer.
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公开(公告)号:JP2000086968A
公开(公告)日:2000-03-28
申请号:JP25807698
申请日:1998-09-11
Applicant: TORAY INDUSTRIES
Inventor: YANAI HIDEKI , OSANAI YOSHITAKA , KAGEISHI KAZUJI
IPC: C08F290/02 , C09D133/14 , C09D151/00 , C09D163/00
Abstract: PROBLEM TO BE SOLVED: To obtain a coating resin composition having excellent storage stability, low-temperature curability and coating film performance by compounding a specific acrylic resin, a specific organoalkoxysilane compound, an aluminum chelate compound and water. SOLUTION: The objective composition contains (A) 100 pts.wt. of an acrylic resin having epoxy group and hydroxyl group on the side chain, (B) 0.05-100 pts.wt. of an organoalkoxysilane compound having glycidyl group and hydrolyzable alkoxysilane group (e.g. γ-glycidoxypropyl trimethoxysilane), (C) 0.01-10 pts.wt. of an aluminum chelate compound (e.g. aluminum ethylacetoacetate diisopropylate) and (D) 0.01-10 pts.wt. of water. The component A is preferably a graft copolymer copolymerized with 0.5-10 wt.% of a polyalkyl (meth)acrylate macromonomer. The component D preferably has an electrical conductivity of
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公开(公告)号:JPH11256079A
公开(公告)日:1999-09-21
申请号:JP5695998
申请日:1998-03-09
Applicant: TORAY INDUSTRIES
Inventor: YANAI HIDEKI , OSHIMA KEISUKE , ANDO ARIYOSHI
IPC: C09D5/44 , C09D5/00 , C09D133/06 , C09D143/04 , C09D161/20
Abstract: PROBLEM TO BE SOLVED: To obtain a flat electrodeposition coating compsn. which is stable and gives a coating film excellent in gloss stability and finished appearance by compounding a specific water-soluble or water-dispersible acrylic resin with an amino resin. SOLUTION: This compsn. contains (A) a water-soluble or water-dispersible acrylic resin having silicon atoms bonded to alkoxy groups and (B) an amino resin which, when mixed with resin A in a wt. ratio to resin A of 40/60 and the mixture is dispersed in water and applied, gives a cured coating film having a transmittance at a wavelength of 400 nm of higher than 90%. Pref., the wt. ratio (solid basis) of resin A to resin B is (40/60)-90/10). Pref., resin A has an acid value of 20-150 mgKOH/g and a hydroxyl value of 30-150 mgKOH/g. Resin B is pref. an alkyl-etherified methylolmelamine resin, still pref. a melamine resin having, on average, 0-4 (at least 4C)-alkyl ether groups per molecule.
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公开(公告)号:JPH09241696A
公开(公告)日:1997-09-16
申请号:JP4865396
申请日:1996-03-06
Applicant: TORAY INDUSTRIES
Inventor: YANAI HIDEKI , YOKOTA MITSURU
Abstract: PROBLEM TO BE SOLVED: To obtain a liquid composition maintaining high enzymatic activity over a long period, free from any turbidity and precipitate, easy to regulate, excellent in safety, and useful as a contact lens cleaner, containing a protease, specific polyols and a boron compound. SOLUTION: This liquid composition contains (A) a protease such as serine protease, (B) two or more kinds of polyol 0.5-2 in the number ratio C/OH in the molecule (e.g. one kind being glycerol or sorbitol) and (C) a boron compound such as boric acid or borax. Specifically, for example, the composition is as follows (based on 100 pts.wt. of water plus the component B): 0.1-10 pts.wt. of serine protease, 5-40 pts.wt. of the component B (5 to =0.5 (esp. 5-20) pts.wt. of the component C.
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公开(公告)号:JPH09185021A
公开(公告)日:1997-07-15
申请号:JP34412395
申请日:1995-12-28
Applicant: TORAY INDUSTRIES
Inventor: YANAI HIDEKI , YOKOTA MITSURU
Abstract: PROBLEM TO BE SOLVED: To obtain a cleaning and preservative liquid capable of keeping the enzyme activity at a high level and hardly causing any deactivation or precipitation by adjusting the pH of the mixture of a cleaning liquid and a preservative liquid to a value below a specified value. SOLUTION: In this liquid contg. a protease, a preservative and a surfactant, the pH is adjusted to
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