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    METHOD FOR PRODUCING PARTLY HYDROPHILIC POROUS ADSORBENT
    6.
    发明专利
    METHOD FOR PRODUCING PARTLY HYDROPHILIC POROUS ADSORBENT 审中-公开

    公开(公告)号：JP2003175336A

    公开(公告)日：2003-06-24

    申请号：JP2002242283

    申请日：2002-08-22

    Applicant: TOSOH CORP

    Inventor： NAKAMURA KOJI ,  KOMIYA KATSUO ,  FUJII SATOSHI

    IPC: A61M1/36 ,  B01J20/26 ,  B01J20/30 ,  C08J9/36

    Abstract: PROBLEM TO BE SOLVED: To provide a method for simply producing a partly hydrophilic adsorbent, to provide a method for producing a double-structure adsorbent comprising the above adsorbent, and to provide a method for producing a double-structure adsorbent and the like excellent in biocompatibility. SOLUTION: Porous particles comprising an organic compound showing the property of contracting in a solvent based on water and of swelling in a solvent based on an organic solvent are used as a raw material. Sites reactive with any compound selected from the group consisting of a hydroxy-containing compound, an amino-containing compound, a carboxy-containing compound, a halogen-group-containing compound, and an epoxy-containing compound are freshly formed by treatment in a solvent based on an organic solvent. The resultant particles are reacted with a compound having an alcoholic OH group in a solvent based on water to fix the compound to the outer surfaces of the particles. COPYRIGHT: (C)2003,JPO

    PRODUCTION OF POLYETHYLENE POLYAMINE
    7.
    发明专利
    PRODUCTION OF POLYETHYLENE POLYAMINE 失效

    公开(公告)号：JPH04202161A

    公开(公告)日：1992-07-22

    申请号：JP32994290

    申请日：1990-11-30

    Applicant: TOSOH CORP

    Inventor： HARA YASUSHI ,  FUJII SATOSHI ,  ITO YUKIO ,  KANAI NOBUYUKI ,  KANEZAKI HIROKI

    IPC: C07C209/60 ,  C07C211/14

    Abstract: PURPOSE:To reduce an undesirable influence of a catalyst on material components caused by corrosion of reactor materials in obtaining the title compound from ethyleneamine and ethanolamine using a solid bed flow type reactor by packing alumina to the upper stream side of a catalytic layer. CONSTITUTION:In producing a polyethylene polyamine from ethyleneamine and ethanolamine by a solid bed flow type reactor using an acid catalyst, alumina is packed into the upper stream side of a catalytic layer, preferably from part (namely part heated to high temperature of >=100 deg.C) causing metal corrosion to the catalytic layer and material components eluted by the corrosion of reactor materials are adsorbed. Consequently, reduction in catalytic activity and reduction in catalytic selectivity caused by adsorption of the material components on the catalyst are reduced.

    Anion exchanger, method of producing the same, and application using the same
    8.
    发明专利
    Anion exchanger, method of producing the same, and application using the same 审中-公开
    阴离子交换剂，其制备方法及其应用

    公开(公告)号：JP2013136025A

    公开(公告)日：2013-07-11

    申请号：JP2011288381

    申请日：2011-12-28

    Applicant: Tosoh Corp ,  東ソー株式会社

    Inventor： FUJII SATOSHI ,  NAKAMURA KOJI

    IPC: B01J41/16 ,  B01J41/10 ,  B01J41/14 ,  B01J47/12 ,  G01N30/88

    Abstract: PROBLEM TO BE SOLVED: To provide an anion exchanger having large adsorption amount of biopolymer such as protein and excellent separation capacity.SOLUTION: Dimethylamine epichlorohydrin polymer and/or dimethylamine ethylenediamine epichlorohydrin polymer is bound to a carrier for chromatography.

    Abstract translation: 要解决的问题：提供具有大量吸附量的生物聚合物如蛋白质和优异的分离能力的阴离子交换剂。解决方案：将二甲胺表氯醇聚合物和/或二甲胺乙二胺表氯醇聚合物结合到用于色谱的载体上。

    HALOGENATION OF MONO-SUBSTITUTED BENZENE DERIVATIVE
    9.
    发明专利
    HALOGENATION OF MONO-SUBSTITUTED BENZENE DERIVATIVE 失效

    公开(公告)号：JP2001072620A

    公开(公告)日：2001-03-21

    申请号：JP24976699

    申请日：1999-09-03

    Applicant: TOSOH CORP

    Inventor： FUJII SATOSHI ,  EGUCHI HISAO

    IPC: B01J29/60 ,  C07B61/00 ,  C07C17/12 ,  C07C25/02

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a para-substituted halogenated benzene derivative under an industrially advantageous mild condition by using an inexpensive zeolite and an additive in high para-selectivity. SOLUTION: This method for halogenating a monosubstituted benzene derivative by bringing the monosubstituted benzene derivative into contact with a halogen in the presence of a zeolite in liquid phase to halogenate the benzene derivative is carried out in the coexistence of an aliphatic nitro compound in a liquid phase. Preferably, the halogen is chlorine, the monosubstituted benzene derivative is (1-bromoethyl)benzene and/or (2-bromoethyl)benzene, and the zeolite is an L-type zeolite.

    PRODUCTION OF PARA-SUBSTITUTED HALOGENATED BENZENE DERIVATIVE
    10.
    发明专利
    PRODUCTION OF PARA-SUBSTITUTED HALOGENATED BENZENE DERIVATIVE 失效

    公开(公告)号：JP2000038357A

    公开(公告)日：2000-02-08

    申请号：JP20634398

    申请日：1998-07-22

    Applicant: TOSOH CORP

    Inventor： FUJII SATOSHI ,  TENMA HIROAKI ,  EGUCHI HISAO

    IPC: B01J29/08 ,  B01J29/60 ,  C07B61/00 ,  C07C17/12 ,  C07C25/02

    Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a para-substituted halogenated benzene derivative in high yield at high conversion rates of raw materials in high selectivity of reaction by reacting a benzene derivative with a halogen in the presence of a specific catalyst and A-type zeolite in liquid phase. SOLUTION: This derivative is obtained by reacting (A) a benzene derivative with (B) a halogen in the presence of (C) pref. 0.5 to 100 wt.% of zeolite catalyst based on the component A and (D) pref. 0.1 to 20 wt.% of zeolite based on the component A in a liquid phase (of e.g. methylene chloride). The component A is pref. an alkylated benzene, more pref., toluene or ethyl benzene. The component B is pref. chlorine or bromine. The component C is pref. a Y-type zeolite or L-type zeolite. The component D is pref. a NaA-type zeolite and/or CaA-type zeolite.

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