Abstract:
Provided is AEI zeolite having a uniform acid strength of an appropriate degree. AEI zeolite comprising phosphorus, preferably AEI zeolite comprising phosphorus in the pores, and a method for producing AEI zeolite comprising a crystallization step of crystallizing a raw material mixture containing a tetraethylphosphonium cation.
Abstract:
Provided is a method for producing an AEI zeolite without the use of a zeolite Y and a raw material containing fluorine and phosphorus, the method including a crystallization step of crystallizing a composition containing a structure directing agent, a sodium source, water, and a zeolite having at least one of the following structures as a silica alumina source.
Abstract:
Provided is a production method by which an AEI zeolite is obtained without inducing a structural transformation in a crystalline aluminosilicate having a Y-structure and without using fluorine or phosphorus, the method including a crystallization step of crystallizing a composition containing an alumina source, a silica source, a structure directing agent, a sodium source, and water, a weight proportion of crystalline aluminosilicate relative to a total weight of the alumina source and the silica source being from 0 wt.% to 1 0 wt.%, and the crystallization step satisfying at least one of the following conditions: a molar ratio of hydroxide ion to silica in the composition is 0.45 or greater, the composition contains a cation represented by (CHJ)JRN+ (R represents an alkyl group having from l to 4 carbons, and the alkyl group may contain at least one substituent), and the crystallization time is 80 hours or longer.
Abstract:
Provided is AEI zeolite having a uniform acid strength of an appropriate degree. AEI zeolite comprising phosphorus, preferably AEI zeolite comprising phosphorus in the pores, and a method for producing AEI zeolite comprising a crystallization step of crystallizing a raw material mixture containing a tetraethylphosphonium cation.
Abstract:
Provided is a production method by which an AEI zeolite is obtained without inducing a structural transformation in a crystalline aluminosilicate having a Y-structure and without using fluorine or phosphorus, the method including a crystallization step of crystallizing a composition containing an alumina source, a silica source, a structure directing agent, a sodium source, and water, a weight proportion of crystalline aluminosilicate relative to a total weight of the alumina source and the silica source being from 0 wt.% to 10 wt.%, and the crystallization step satisfying at least one of the following conditions: a molar ratio of hydroxide ion to silica in the composition is 0.45 or greater, the composition contains a cation represented by (CH 3 ) 3 RN + (R represents an alkyl group having from 1 to 4 carbons, and the alkyl group may contain at least one substituent), and the crystallization time is 80 hours or longer.
Abstract:
[Problem] To provide a novel MFI zeolite that when used as a catalyst, can be used for a selective catalytic reaction for larger molecules and to provide a method for producing the MFI zeolite. [Solution] An MFI zeolite comprising the following properties: (i) the MFI zeolite includes uniform mesopores having a pore distribution curve which a peak-width thereof at half height (hw) is at most 20 nm (hw ‰¤ 20 nm) and a center value (µ) of a maximum peak is 10 nm or more and 20 nm or less (10 nm ‰¤ µ ‰¤20 nm), and having a pore volume (pv) of the uniform mesopores of at least 0.05 mL/g (0.05 mL/g ‰¤ pv); (ii) the MFI zeolite has no peak in a range of 0.1° to 3° in powder X-ray diffraction measurement with a diffraction angle represented by 2¸; and (iii) the MFI zeolite has an average particle diameter (PD) of at most 100 nm (PD ‰¤ 100 nm).
Abstract:
PROBLEM TO BE SOLVED: To provide ZSM-5 fine particles with a small particle size, a dispersion wherein the particles are dispersed stably, and a method for efficiently producing the fine particles.SOLUTION: In the ZSM-5 fine particles, a molar ratio SiO/AlOis 40-300, and an average particle size measured by a dynamic light scattering method in a dispersion condition is 20-300 nm. The dispersion wherein the ZSM-5 fine particles are dispersed is also provided. In the method for producing the dispersion: a hydrogel is prepared by mixing a silicon compound solution and an aluminum compound solution together; subsequently, aqueous mixture slurry is obtained by adding and mixing an organic structure directing agent and water together while adjusting a total of alkali metal ions, halogen ions, sulfate ions, nitrate ions, and acetate ions to 0.5 mol/L or below and a total of Na, K, Cl, Br and SOconcentrations to 0.15 mol/L; and then, hydrothermal synthesis is carried out.
Abstract:
PROBLEM TO BE SOLVED: To provide a fine chabazite type zeolite having a small average particle diameter and a large outer surface area, a method for producing the same, and application thereof.SOLUTION: In a fine chabazite type zeolite, a TEM-average particle diameter or a SEM-average particle diameter is ≥0.02 μm and
Abstract:
PROBLEM TO BE SOLVED: To provide an LEV type zeolite having a core-shell structure, and a synthesis method thereof.SOLUTION: The LEV type zeolite having a core-shell structure includes a core and a shell, which are different in an Si/Almolar ratio. The zeolite can be synthesized by a method performing hydrothermal synthesis of a mixture including FAU type zeolite, sodium ions, hydroxide ions, LEV type zeolite seed crystal, and water.