公开(公告)号：US20050256272A1

公开(公告)日：2005-11-17

申请号：US10519464

申请日：2004-02-17

Applicant: Mitsuo Najima ,  Takashi Isogai

Inventor： Mitsuo Najima ,  Takashi Isogai

IPC: C08F255/00 ,  C08F255/02 ,  C08F285/00 ,  C08L51/06 ,  C09D151/06 ,  C08F2/00

CPC classification number: C08L51/06 ,  C08F255/00 ,  C08F255/023 ,  C08F285/00 ,  C09D151/06

Abstract: This method for preparing an acrylic-modified chlorinated polyolefin resin comprises graft-copolymerizing an acid-modified chlorinated polyolefin resin with a monomer mixture containing a (meth)acrylate ester monomer having one hydroxyl group and another vinyl monomer in the presence of a cyclic ether compound. Also, the cyclic ether compound may be added in an amount of 1 to 100 parts by weight based on 100 parts by weight of the acid-modified chlorinated ployolefin resin, and the cyclic ether compound may be dioxane and/or 1,3-dioxolane.

Abstract translation: 制备丙烯酸改性氯化聚烯烃树脂的方法包括在环醚化合物存在下，将酸改性氯化聚烯烃树脂与含有具有一个羟基的（甲基）丙烯酸酯单体和另一乙烯基单体的单体混合物接枝共聚 。 此外，相对于100重量份的酸改性氯化聚烯烃树脂，环醚化合物的添加量可以为1〜100重量份，环状醚化合物可以是二恶烷和/或1,3-二氧戊环 。

公开(公告)号：US06235407B1

公开(公告)日：2001-05-22

申请号：US09194130

申请日：1998-11-23

Applicant: Hiroyuki Ogata ,  Sachiko Suzuki ,  Kazuo Mochizuki ,  Takashi Isogai ,  Shigeru Usuda ,  Toru Sano

Inventor： Hiroyuki Ogata ,  Sachiko Suzuki ,  Kazuo Mochizuki ,  Takashi Isogai ,  Shigeru Usuda ,  Toru Sano

IPC: B32B1508

CPC classification number: B05D7/51 ,  B05D7/14 ,  B32B15/08 ,  B60K15/03 ,  C23C28/00 ,  Y10T428/12014 ,  Y10T428/12063 ,  Y10T428/12111 ,  Y10T428/12569 ,  Y10T428/12597 ,  Y10T428/12736 ,  Y10T428/12757 ,  Y10T428/1355 ,  Y10T428/31678

Abstract: A highly corrosion resistant steel sheet for fuel tank comprising a lowermost layer of Zn or Zn-based plating layer deposited on each side of the steel sheet; a chemical conversion film deposited on each of the Zn or Zn-based plating layer; a metal powder-containing organic resin film deposited on one of the chemical conversion film, said metal powder-containing organic resin film containing Al and Ni metal powders and an amine modified epoxy resin; and a silica-containing organic resin film deposited on the other chemical conversion film, said silica-containing organic resin film containing at least one resin having at least one functional group selected from hydroxyl group, isocyanate group, carboxyl group, glycidyl group, and amino group; silica; and a lubricant. The steel sheet of the present invention has excellent corrosion resistance, press workability, resistance weldability and brazing ability, and therefore, the steel sheet of the present invention is particularly useful when it is used in contact with an alcohol or an alcohol-blended gasoline.

Abstract translation: 一种用于燃料箱的高耐腐蚀钢板，包括沉积在钢板两侧的最下层的Zn或Zn基镀层; 沉积在每个Zn或Zn基镀层上的化学转化膜; 沉积在化学转化膜之一上的含金属粉末的有机树脂膜，含有Al和Ni金属粉末的所述含金属粉末的有机树脂膜和胺改性环氧树脂; 和沉积在另一化学转化膜上的含二氧化硅的有机树脂膜，所述含二氧化硅的有机树脂膜含有至少一种具有至少一个选自羟基，异氰酸酯基，羧基，缩水甘油基和氨基的官能团的树脂 组; 二氧化硅 和润滑剂。 本发明的钢板具有优异的耐腐蚀性，冲压加工性，电阻可焊性和钎焊性，因此本发明的钢板在与醇或醇混汽油接触时特别有用。

公开(公告)号：US09249309B2

公开(公告)日：2016-02-02

申请号：US13574746

申请日：2011-01-25

Applicant: Takashi Isogai ,  Hirohito Kudou ,  Keiji Koike

Inventor： Takashi Isogai ,  Hirohito Kudou ,  Keiji Koike

IPC: C09D4/00 ,  C09D163/00 ,  C09D163/10 ,  C23C14/02 ,  C23C14/16 ,  C08F220/32 ,  C09D133/06 ,  B05D5/06 ,  B05D7/00

CPC classification number: C09D4/00 ,  B05D5/068 ,  B05D7/50 ,  C08F220/32 ,  C09D133/06 ,  C09D163/00 ,  C09D163/10 ,  C23C14/024 ,  C23C14/165 ,  Y10T428/265

Abstract: A base coat coating composition which is able to suppress cracking of a metal thin film, even when a tough top coat layer capable of satisfactorily protecting the metal thin film is formed on the metal thin film, and even when a heat resistance test is performed, as well as a composite film and a method for producing the composite film. Specifically, a base coat coating composition used for undercoating a metal thin film formed on a metal substrate, and containing a coating film-forming component which contains at least 30% by mass of an epoxy (meth)acrylate having a cyclic structure and has an average molecular weight between crosslinks of 180 to 1,000, as well as a composite film having a base coat layer obtained from the base coat coating composition, and a method for producing the composite film.

Abstract translation: 即使在金属薄膜上形成能够令人满意地保护金属薄膜的坚韧的顶涂层，也能够抑制金属薄膜的龟裂的底涂层涂料组合物，即使进行耐热性试验， 以及复合膜和复合膜的制造方法。 具体而言，是在金属基材上形成的金属薄膜的底涂层，含有含有至少30质量％的具有环状结构的环氧（甲基）丙烯酸酯的涂膜形成成分的底涂层用组合物，其具有 交联间的平均分子量为180〜1000，以及由底涂层组合物得到的底涂层的复合膜，以及复合膜的制造方法。

公开(公告)号：US20100144956A1

公开(公告)日：2010-06-10

申请号：US12532029

申请日：2008-03-04

Applicant: Mitsuo Najima ,  Noboru Ohara ,  Masao Watanabe ,  Takashi Isogai ,  Kenji Kawai

Inventor： Mitsuo Najima ,  Noboru Ohara ,  Masao Watanabe ,  Takashi Isogai ,  Kenji Kawai

IPC: C09D123/14 ,  C08L33/02

CPC classification number: C09D123/145 ,  C08F255/08 ,  C08L23/14 ,  C08L23/142 ,  C08L33/02 ,  C08L33/06 ,  C08L33/08 ,  C09D5/02 ,  C09D123/14 ,  C09D133/06 ,  C09D151/06 ,  C08L2666/06 ,  C08L2666/04 ,  C08F212/08

Abstract: A resin composition for an aqueous coating material that includes a propylene-butene resin component and/or propylene-ethylene-butene resin component (A), and a (meth)acrylic resin component (B), wherein the mass ratio between the propylene-butene resin component and/or propylene-ethylene-butene resin component (A) and the (meth)acrylic resin component (B) is within a range from 15:85 to 75:25. Also disclosed are a method for producing such a resin composition and an aqueous coating material. The present invention is able to provide a resin composition for an aqueous coating material that is useful as a binder within an aqueous coating material that uses no organic solvents or chlorine compounds, and yet exhibits excellent adhesion to polyolefin-based resins and is capable of forming a coating film that is resistant to discoloration and exhibits favorable resistance to the oils contained within gasoline, cosmetic products and foodstuffs and the like, and is also able to provide a method for producing the resin composition and an aqueous coating material that uses the resin composition.

Abstract translation: 一种含有丙烯 - 丁烯树脂组分和/或丙烯 - 乙烯 - 丁烯树脂组分（A）和（甲基）丙烯酸树脂组分（B）的水性涂料的树脂组合物，其中丙烯 - 丁烯树脂组分和/或丙烯 - 乙烯 - 丁烯树脂组分（A）和（甲基）丙烯酸树脂组分（B）的比例在15:85至75:25的范围内。 还公开了这种树脂组合物和水性涂料的制造方法。 本发明能够提供一种水性涂料用树脂组合物，其在不含有机溶剂或氯化合物的水性涂料中可用作粘合剂，并且对聚烯烃类树脂表现出优异的粘合性，并且能够形成 耐变色涂膜，对汽油，化妆品，食品等中所含的油具有良好的耐受性，还可以提供使用该树脂组合物的树脂组合物和水性涂料的制造方法 。

公开(公告)号：US09012023B2

公开(公告)日：2015-04-21

申请号：US13983317

申请日：2012-01-27

Applicant: Takashi Isogai

Inventor： Takashi Isogai

IPC: C08F230/08 ,  C09D175/14 ,  B32B27/40 ,  C08F222/10 ,  C08F290/06 ,  C08G18/08 ,  C08G18/32 ,  C08G18/34 ,  C08G18/67 ,  C08G18/73 ,  C08G18/75 ,  C09D7/12 ,  C09D133/12 ,  C09D151/00 ,  C09D175/16 ,  C09D201/06 ,  C09D201/08

CPC classification number: C09D133/12 ,  C08F222/1006 ,  C08F230/08 ,  C08F290/062 ,  C08F290/067 ,  C08G18/0823 ,  C08G18/3206 ,  C08G18/348 ,  C08G18/672 ,  C08G18/73 ,  C08G18/753 ,  C09D151/003 ,  C09D175/14 ,  C09D175/16 ,  C09D201/06 ,  C09D201/08 ,  Y10T428/31605 ,  Y10T428/31663 ,  C08F220/18 ,  C08F220/06

Abstract: A hard coat coating composition for a metal base material, includes a coated film forming component including a urethane(meth)acrylate (A) having a carboxyl group and having a solid fraction acid value being value of 0.5 to 2.0 mgKOH/g, a urethane(meth)acrylate (B) not having a carboxyl group, a thermoplastic resin (C) having a carboxyl group and having a solid fraction acid value of 1.0 to 30 mgKOH/g, and a silane coupling agent (D).

Abstract translation: 一种金属基材用硬涂层组合物，包括具有羧基，固体成分酸值为0.5〜2.0mgKOH / g的氨基甲酸酯（甲基）丙烯酸酯（A），氨基甲酸酯（甲基）丙烯酸酯 不具有羧基的（甲基）丙烯酸酯（B），具有羧基，固体成分酸值为1.0〜30mgKOH / g的热塑性树脂（C）和硅烷偶联剂（D）。

公开(公告)号：US20130309510A1

公开(公告)日：2013-11-21

申请号：US13983317

申请日：2012-01-27

Applicant: Takashi Isogai

Inventor： Takashi Isogai

IPC: C09D133/12

CPC classification number: C09D133/12 ,  C08F222/1006 ,  C08F230/08 ,  C08F290/062 ,  C08F290/067 ,  C08G18/0823 ,  C08G18/3206 ,  C08G18/348 ,  C08G18/672 ,  C08G18/73 ,  C08G18/753 ,  C09D151/003 ,  C09D175/14 ,  C09D175/16 ,  C09D201/06 ,  C09D201/08 ,  Y10T428/31605 ,  Y10T428/31663 ,  C08F220/18 ,  C08F220/06

Abstract: A hard coat coating composition for a metal base material, includes a coated film forming component including a urethane(meth)acrylate (A) having a carboxyl group and having a solid fraction acid value being value of 0.5 to 2.0 mgKOH/g, a urethane(meth)acrylate (B) not having a carboxyl group, a thermoplastic resin (C) having a carboxyl group and having a solid fraction acid value of 1.0 to 30 mgKOH/g, and a silane coupling agent (D).

Abstract translation: 一种金属基材用硬涂层组合物，包括具有羧基，固体成分酸值为0.5〜2.0mgKOH / g的氨基甲酸酯（甲基）丙烯酸酯（A），氨基甲酸酯（甲基）丙烯酸酯 不具有羧基的（甲基）丙烯酸酯（B），具有羧基，固体成分酸值为1.0〜30mgKOH / g的热塑性树脂（C）和硅烷偶联剂（D）。

公开(公告)号：US20120288707A1

公开(公告)日：2012-11-15

申请号：US13574746

申请日：2011-01-25

Applicant: Takashi Isogai ,  Hirohito Kudou ,  Keiji Koike

Inventor： Takashi Isogai ,  Hirohito Kudou ,  Keiji Koike

IPC: C09D5/00 ,  C23C14/34 ,  B32B15/092 ,  B82Y30/00

CPC classification number: C09D4/00 ,  B05D5/068 ,  B05D7/50 ,  C08F220/32 ,  C09D133/06 ,  C09D163/00 ,  C09D163/10 ,  C23C14/024 ,  C23C14/165 ,  Y10T428/265

Abstract: A base coat coating composition which is able to suppress cracking of a metal thin film, even when a tough top coat layer capable of satisfactorily protecting the metal thin film is formed on the metal thin film, and even when a heat resistance test is performed, as well as a composite film and a method for producing the composite film. Specifically, a base coat coating composition used for undercoating a metal thin film formed on a metal substrate, and containing a coating film-forming component which contains at least 30% by mass of an epoxy (meth)acrylate having a cyclic structure and has an average molecular weight between crosslinks of 180 to 1,000, as well as a composite film having a base coat layer obtained from the base coat coating composition, and a method for producing the composite film.

Abstract translation: 即使在金属薄膜上形成能够令人满意地保护金属薄膜的坚韧的顶涂层，也能够抑制金属薄膜的龟裂的底涂层涂料组合物，即使进行耐热性试验， 以及复合膜和复合膜的制造方法。 具体而言，是在金属基材上形成的金属薄膜的底涂层，含有含有至少30质量％的具有环状结构的环氧（甲基）丙烯酸酯的涂膜形成成分的底涂层用组合物， 交联间的平均分子量为180〜1000，以及由底涂层组合物得到的底涂层的复合膜，以及复合膜的制造方法。

公开(公告)号：US20100203325A1

公开(公告)日：2010-08-12

申请号：US12602671

申请日：2008-06-24

Applicant: Takashi Isogai ,  Mitsuo Najima ,  Noboru Ohara ,  Masao Watanabe ,  Kenji Kawai ,  Shuhei Kawabata

Inventor： Takashi Isogai ,  Mitsuo Najima ,  Noboru Ohara ,  Masao Watanabe ,  Kenji Kawai ,  Shuhei Kawabata

IPC: B32B5/00 ,  B05D3/06 ,  C09D4/02 ,  C09D175/14

CPC classification number: C08F290/06 ,  B05D3/067 ,  B05D5/061 ,  B05D5/067 ,  C08F290/061 ,  C08F290/067 ,  C08F299/00 ,  C08F299/06 ,  C08G18/672 ,  C08G18/753 ,  C08G18/755 ,  C08G18/758 ,  C09D4/00 ,  C09D5/08 ,  C09D175/16 ,  C23C14/20 ,  C23C14/205 ,  C23C14/58 ,  C23C14/584 ,  Y10T428/265 ,  Y10T428/31605 ,  Y10T428/31609

Abstract: A coating composition for a metal thin film for coating a vapor-deposited film or sputtered film provided on the surface of a base material, comprising: a coating film forming component containing 50% by weight or more of urethane (meth)acrylate that is a reaction product of hydrogenated xylene diisocyanate and/or hydrogenated diphenylmethane diisocyanate, polyol, and (meth)acrylate having a hydroxyl group.

Abstract translation: 一种用于涂布在基材表面上形成的气相沉积膜或溅射膜的金属薄膜用涂料组合物，其包含：含有50重量％以上的聚氨酯（甲基）丙烯酸酯的涂膜形成组分，其为 氢化二甲苯二异氰酸酯和/或氢化二苯基甲烷二异氰酸酯的反应产物，多元醇和具有羟基的（甲基）丙烯酸酯。

公开(公告)号：US09567676B2

公开(公告)日：2017-02-14

申请号：US12294579

申请日：2007-03-27

Applicant: Takashi Isogai ,  Noboru Ohara ,  Masao Watanabe ,  Mitsuo Najima ,  Kenji Kawai ,  Hiroyuki Ishii

Inventor： Takashi Isogai ,  Noboru Ohara ,  Masao Watanabe ,  Mitsuo Najima ,  Kenji Kawai ,  Hiroyuki Ishii

IPC: C09D175/16 ,  C23C26/00 ,  B05D5/00 ,  C08F283/00 ,  C08F290/06 ,  C08F299/06 ,  C08G18/73 ,  C08G18/75 ,  C08G18/80 ,  C08G18/81 ,  C09D4/00 ,  C09D5/08 ,  B05D1/02 ,  B05D3/02 ,  B05D3/06

CPC classification number: C23C26/00 ,  B05D1/02 ,  B05D3/0209 ,  B05D3/0254 ,  B05D3/067 ,  B05D5/00 ,  B05D2202/25 ,  C08F283/006 ,  C08F290/06 ,  C08F290/067 ,  C08F299/06 ,  C08G18/73 ,  C08G18/753 ,  C08G18/755 ,  C08G18/757 ,  C08G18/758 ,  C08G18/8016 ,  C08G18/8175 ,  C09D4/00 ,  C09D5/08 ,  C09D175/16

Abstract: The object of the present invention is to provide a hard coating composition for a metal substrate, including a film-forming resin component which contains a urethane (meth)acrylate obtained by reacting a polyisocyanate compound, a polyol, and a (meth)acrylate monomer having a hydroxyl group, wherein the polyisocyanate compound is hydrogenated xylylene diisocyanate and/or dicyclohexylmethane diisocyanate.

Abstract translation: 本发明的目的是提供一种用于金属基材的硬质涂料组合物，其包括含有由多异氰酸酯化合物，多元醇和（甲基）丙烯酸酯单体反应得到的氨基甲酸酯（甲基）丙烯酸酯的成膜树脂组分， 具有羟基，其中所述多异氰酸酯化合物是氢化苯二甲基二异氰酸酯和/或二环己基甲烷二异氰酸酯。

公开(公告)号：US09029466B2

公开(公告)日：2015-05-12

申请号：US12532029

申请日：2008-03-04

Applicant: Mitsuo Najima ,  Noboru Ohara ,  Masao Watanabe ,  Takashi Isogai ,  Kenji Kawai

Inventor： Mitsuo Najima ,  Noboru Ohara ,  Masao Watanabe ,  Takashi Isogai ,  Kenji Kawai

IPC: C08L23/14 ,  C08L33/02 ,  C08L33/06 ,  C08L33/08 ,  C09D123/14 ,  C09D133/06 ,  C09D5/02 ,  C08F255/08 ,  C09D151/06

CPC classification number: C09D123/145 ,  C08F255/08 ,  C08L23/14 ,  C08L23/142 ,  C08L33/02 ,  C08L33/06 ,  C08L33/08 ,  C09D5/02 ,  C09D123/14 ,  C09D133/06 ,  C09D151/06 ,  C08L2666/06 ,  C08L2666/04 ,  C08F212/08

Abstract: A resin composition for an aqueous coating material that includes a propylene-butene resin component and/or propylene-ethylene-butene resin component (A), and a (meth)acrylic resin component (B), wherein the mass ratio between the propylene-butene resin component and/or propylene-ethylene-butene resin component (A) and the (meth)acrylic resin component (B) is within a range from 15:85 to 75:25. Also disclosed are a method for producing such a resin composition and an aqueous coating material. The present invention is able to provide a resin composition for an aqueous coating material that is useful as a binder within an aqueous coating material that uses no organic solvents or chlorine compounds, and yet exhibits excellent adhesion to polyolefin-based resins and is capable of forming a coating film that is resistant to discoloration and exhibits favorable resistance to the oils contained within gasoline, cosmetic products and foodstuffs and the like, and is also able to provide a method for producing the resin composition and an aqueous coating material that uses the resin composition.

Abstract translation: 一种含有丙烯 - 丁烯树脂组分和/或丙烯 - 乙烯 - 丁烯树脂组分（A）和（甲基）丙烯酸树脂组分（B）的水性涂料的树脂组合物，其中丙烯 - 丁烯树脂组分和/或丙烯 - 乙烯 - 丁烯树脂组分（A）和（甲基）丙烯酸树脂组分（B）的比例在15:85至75:25的范围内。 还公开了这种树脂组合物和水性涂料的制造方法。 本发明能够提供一种水性涂料用树脂组合物，其在不含有机溶剂或氯化合物的水性涂料中可用作粘合剂，并且对聚烯烃类树脂表现出优异的粘合性，并且能够形成 耐变色涂膜，对汽油，化妆品，食品等中所含的油具有良好的耐受性，还可以提供使用该树脂组合物的树脂组合物和水性涂料的制造方法 。