公开(公告)号：DE69825556D1

公开(公告)日：2004-09-16

申请号：DE69825556

申请日：1998-12-22

Applicant: UBE INDUSTRIES

Inventor： HARADA KATSUMASA ,  MATSUSHITA AKIO ,  NAKAMURA TAKU ,  MIZUTARE KATSUHIKO ,  HIRAKAWA TAKAFUMI ,  IKUNO KEN ,  IWASE NORIAKI

IPC: C07D277/20 ,  C07D277/36

Abstract: Disclosed is a method for preparing 2-mercaptothiazole, which comprises adding a dithiocarbamate salt represented by the formula (1): wherein M is a cation, to a chloroacetaldehyde solution in the presence of an acid.

公开(公告)号：DE69403412T2

公开(公告)日：1997-09-18

申请号：DE69403412

申请日：1994-09-07

Applicant: UBE INDUSTRIES

Inventor： OGUNI NOBUKI ,  HAYASHI MASAHIKO ,  HARADA KATSUMASA ,  MATSUSHITA AKIO

IPC: C07C67/46 ,  C07C69/716

Abstract: Disclosed is a process for the preparation of a 5-hydroxy-3-ketoester derivative of the formula: in which R represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, and R represents an alkyl group or an aryl group, which comprises causing the reaction of an aldehyde compound of the formula R CHO in which R has the meanings as defined above and diketene in the presence of a metal compound selected from a titanium or aluminum compound having at least one group of -OR in which R represents an alkyl group or an aryl group. Further, a process for the preparation of an optically active substance of the 5-hydroxy-3-ketoester derivative causing the reaction of the above compounds in the presence of the metal compound and optically active Schiff base or a complex compound obtained by reacting the metal compound with the optically active Schiff base, also is disclosed.

公开(公告)号：DE69527684T2

公开(公告)日：2002-11-28

申请号：DE69527684

申请日：1995-09-06

Applicant: UBE INDUSTRIES

Inventor： HARADA KATSUMASA ,  MATSUSHITA AKIO ,  KAWACHI YASUHIRO ,  SASAKI HIROSHI

IPC: C07F7/18

Abstract: Methyl (3R, 6E)-3-Ä(tert-butyldimethylsilyl)oxyÜ-7-Ä2', 6'-diisopropyl-4'-(4''-fluorophenyl)-5'-(methoxymethyl)pyridin-3'-ylÜ- 5-oxy-6-heptenoate or other 3-oxy-5-oxo-6-heptenoic acid derivative is prepared by the reaction of an aromatic aldehyde and an oxyglutaric acid derivative in an aliphatic alcohol containing a small amount of water in the presence of an alkali metal carbonate or hydrogen carbonate.

公开(公告)号：DE69527684D1

公开(公告)日：2002-09-12

申请号：DE69527684

申请日：1995-09-06

Applicant: UBE INDUSTRIES

Inventor： HARADA KATSUMASA ,  MATSUSHITA AKIO ,  KAWACHI YASUHIRO ,  SASAKI HIROSHI

IPC: C07F7/18

Abstract: Methyl (3R, 6E)-3-Ä(tert-butyldimethylsilyl)oxyÜ-7-Ä2', 6'-diisopropyl-4'-(4''-fluorophenyl)-5'-(methoxymethyl)pyridin-3'-ylÜ- 5-oxy-6-heptenoate or other 3-oxy-5-oxo-6-heptenoic acid derivative is prepared by the reaction of an aromatic aldehyde and an oxyglutaric acid derivative in an aliphatic alcohol containing a small amount of water in the presence of an alkali metal carbonate or hydrogen carbonate.

公开(公告)号：DE69403412D1

公开(公告)日：1997-07-03

申请号：DE69403412

申请日：1994-09-07

Applicant: UBE INDUSTRIES

Inventor： OGUNI NOBUKI ,  HAYASHI MASAHIKO ,  HARADA KATSUMASA ,  MATSUSHITA AKIO

IPC: C07C67/46 ,  C07C69/716

Abstract: Disclosed is a process for the preparation of a 5-hydroxy-3-ketoester derivative of the formula: in which R represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, and R represents an alkyl group or an aryl group, which comprises causing the reaction of an aldehyde compound of the formula R CHO in which R has the meanings as defined above and diketene in the presence of a metal compound selected from a titanium or aluminum compound having at least one group of -OR in which R represents an alkyl group or an aryl group. Further, a process for the preparation of an optically active substance of the 5-hydroxy-3-ketoester derivative causing the reaction of the above compounds in the presence of the metal compound and optically active Schiff base or a complex compound obtained by reacting the metal compound with the optically active Schiff base, also is disclosed.

公开(公告)号：DE69825556T2

公开(公告)日：2005-08-04

申请号：DE69825556

申请日：1998-12-22

Applicant: UBE INDUSTRIES

Inventor： HARADA KATSUMASA ,  MATSUSHITA AKIO ,  NAKAMURA TAKU ,  MIZUTARE KATSUHIKO ,  HIRAKAWA TAKAFUMI ,  IKUNO KEN ,  IWASE NORIAKI

IPC: C07D277/20 ,  C07D277/36

Abstract: Disclosed is a method for preparing 2-mercaptothiazole, which comprises adding a dithiocarbamate salt represented by the formula (1): wherein M is a cation, to a chloroacetaldehyde solution in the presence of an acid.

公开(公告)号：DE69424463T2

公开(公告)日：2000-09-14

申请号：DE69424463

申请日：1994-03-29

Applicant: UBE INDUSTRIES

Inventor： HARADA KATSUMASA ,  MATSUSHITA AKIO ,  SASAKI HIROSHI ,  KAWACHI YASUHIRO

IPC: C07F9/40 ,  C07F9/53

公开(公告)号：DE69424463D1

公开(公告)日：2000-06-21

申请号：DE69424463

申请日：1994-03-29

Applicant: UBE INDUSTRIES

Inventor： HARADA KATSUMASA ,  MATSUSHITA AKIO ,  SASAKI HIROSHI ,  KAWACHI YASUHIRO

IPC: C07F9/40 ,  C07F9/53

公开(公告)号：DE69226813T2

公开(公告)日：1999-02-18

申请号：DE69226813

申请日：1992-06-04

Applicant: UBE INDUSTRIES

Inventor： HARADA KATSUMASA ,  ABE TAKAAKI ,  AKIYOSHI YUJI ,  MATSUSHITA AKIO ,  KOJIMA MIKIO ,  SHIRAISHI IKUO ,  YAMAMOTO KAORU ,  HAYAMA TAKASHI ,  FUKUDA SHOHEI

IPC: A01N43/50 ,  A01N43/54 ,  A01N43/66 ,  A01N43/68 ,  C07D233/84 ,  C07D239/38 ,  C07D239/60 ,  C07D251/26 ,  C07D251/30 ,  C07D251/38 ,  C07D403/12 ,  C07D521/00 ,  C07D239/52 ,  C07D239/56

Abstract: Disclosed are a pyrimidine or triazine compound represented by the following formula (I): wherein R represents cyano group, a halogen atom, hydroxy group or -O-R where R represents a lower alkyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group or a cyano-lower alkyl group; R represents hydrogen atom or a lower alkyl group; R represents hydrogen atom or a lower alkyl group; R represents a 1-imidazolyl group, -NHSO2-R where R represents a lower alkyl group or a phenyl group which may have a substituent, hydroxy group, a lower alkoxy group or a benzyloxy group when Z is nitrogen atom; or a 1-imidazolyl group, -NHSO2-R where R has the same meaning as defined above, hydroxy group, OK, a lower alkoxy group which may have a substituent, a lower alkenyloxy group, a lower alkynyloxy group, a cycloalkoxy group which may have a substituent, a phenoxy group, a benzyloxy group, a lower alkylthio group, a phenylthio group or an alkylsulfinylamino group when Z is -CH= group; R represents a lower alkoxy group; R represents a lower alkoxy group or a lower alkyl group; X represents oxygen atom or sulfur atom; and Z represents nitrogen atom or -CH= group. processes for preparing the same and a herbicide containing the same as an active ingredient(s).

公开(公告)号：DE69226813D1

公开(公告)日：1998-10-08

申请号：DE69226813

申请日：1992-06-04

Applicant: UBE INDUSTRIES

Inventor： HARADA KATSUMASA ,  ABE TAKAAKI ,  AKIYOSHI YUJI ,  MATSUSHITA AKIO ,  KOJIMA MIKIO ,  SHIRAISHI IKUO ,  YAMAMOTO KAORU ,  HAYAMA TAKASHI ,  FUKUDA SHOHEI

IPC: A01N43/50 ,  A01N43/54 ,  A01N43/66 ,  A01N43/68 ,  C07D233/84 ,  C07D239/38 ,  C07D239/60 ,  C07D251/26 ,  C07D251/30 ,  C07D251/38 ,  C07D403/12 ,  C07D521/00 ,  C07D239/52 ,  C07D239/56

Abstract: Disclosed are a pyrimidine or triazine compound represented by the following formula (I): wherein R represents cyano group, a halogen atom, hydroxy group or -O-R where R represents a lower alkyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group or a cyano-lower alkyl group; R represents hydrogen atom or a lower alkyl group; R represents hydrogen atom or a lower alkyl group; R represents a 1-imidazolyl group, -NHSO2-R where R represents a lower alkyl group or a phenyl group which may have a substituent, hydroxy group, a lower alkoxy group or a benzyloxy group when Z is nitrogen atom; or a 1-imidazolyl group, -NHSO2-R where R has the same meaning as defined above, hydroxy group, OK, a lower alkoxy group which may have a substituent, a lower alkenyloxy group, a lower alkynyloxy group, a cycloalkoxy group which may have a substituent, a phenoxy group, a benzyloxy group, a lower alkylthio group, a phenylthio group or an alkylsulfinylamino group when Z is -CH= group; R represents a lower alkoxy group; R represents a lower alkoxy group or a lower alkyl group; X represents oxygen atom or sulfur atom; and Z represents nitrogen atom or -CH= group. processes for preparing the same and a herbicide containing the same as an active ingredient(s).