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    Process for the manufacture of acrylonitrile
    3.
    发明授权
    Process for the manufacture of acrylonitrile 失效
    丙烯腈制备工艺

    公开(公告)号：US3641100A

    公开(公告)日：1972-02-08

    申请号：US3641100D

    申请日：1969-03-05

    Applicant: UBE INDUSTRIES

    Inventor： YAMADA KEISHO ,  ODAN KYOJI ,  NAKAMURA YASUO ,  HIDAKA MIKIO

    IPC: B01J23/31 ,  B01J35/00 ,  C07C121/02

    CPC classification number: C07C253/26 ,  B01J23/31 ,  B01J35/0006 ,  Y02P20/52 ,  C07C255/08

    Abstract: IN THE PROCESS OF MANUFACTURING ACRYLONITRILE WHEREIN PROPYLENE, AMMONIA AND OXYGEN ARE CONTACTED WITH A SOLID OXIDIZING CATALYST IN THE VAPOR PHASE AT A TEMPERATURE IN THE RANGE OF 400-600*C., THE IMPROVED METHOD WHICH COMPRISES USING AS SAID SOLID CATALYST A CATALYST WHICH CONSISTS ESSENTIALLY OF (A) A BISMUTH ANTIMONATE IN WHIC THE ATOMIC RATIO OF BISMUTH TO ANTIMONY IS 1:1, AND (B) A SALT OF BISMUTH SELECTED FROM THE GROUP CONSISTING OF A BISMUTH MOLYBDATE IN WHICH THE ATOMIC RATIO OF BISMUTH TO MOLYBDENUM IS 2:3, AND A BISMUTH TUNGSTATE IN WHICH THE ATOMIC RATIO OF BISMUTH TO TUNGSTEN IS 2:3; THE WEIGHT RATIO OF SAID BISMUTH ANTIMONATE TO SAID BISMUTH MOLYBDATE OR BISMUTH TUNGSTATE BEING IN THE RANGE OF 95:5-50:50.

    5.
    发明专利
    未知

    公开(公告)号：NO981669A

    公开(公告)日：1998-10-16

    申请号：NO981669

    申请日：1998-04-14

    Applicant: UBE INDUSTRIES

    Inventor： MATSUZAKI TOKO ,  SUGIMOTO TSUNEMI ,  NAKAMURA YASUO ,  MANABE TAKUMI

    IPC: B01J23/18 ,  B01J27/02 ,  B01J27/16 ,  B01J27/18 ,  B01J23/644 ,  C07C5/333

    CPC classification number: B01J27/16 ,  B01J23/18 ,  B01J27/02 ,  B01J27/1815 ,  C07C41/09 ,  C07C43/23

    Abstract: A dehydration catalyst useful for producing a monoalkylether of dihydric phenolic compound by a dehydration reaction of a dihydric phenolic compound with a lower alkyl alcohol with a high conversion at a high selectivity, comprises at least one inorganic substance of the empirical formula (I): Ala Pb Tic Sid Xe Of wherein X represents a member selected from (1) an antimony and/or a bismuth atom, and (2) a sulfur atom, a, b, c, d, e and f respectively represent the numbers of Al, P, Ti, Si, X and O atoms, the atomic ratio a:b is 1:1.0 to 1.9, the atomic ratio a:c is 1:0.05 to 0.5, the atomic ratio a:d is 1:0.05 to 0.2, the atomic ratio a:e is 1:0.01 to 0.3 when X represents antimony and/or bismuth atom and 1:0.004 to 0.015 when X represents a sulfur atom, and the atomic ratio a:f is 1:4.1 to 8.4.

    HYDROGENATION CATALYST AND PRODUCTION OF ETHYENE GLYCOL
    7.
    发明专利
    HYDROGENATION CATALYST AND PRODUCTION OF ETHYENE GLYCOL 未知

    公开(公告)号：AU3809385A

    公开(公告)日：1985-08-01

    申请号：AU3809385

    申请日：1985-01-25

    Applicant: UBE INDUSTRIES

    Inventor： HIRAI KOICHI ,  UDA TAIZO ,  NAKAMURA YASUO

    IPC: B01J23/72 ,  B01J31/00 ,  C07C29/136 ,  C07C31/20

    Abstract: A hydrogenation catalyst composition composed of a reduction product of a copper-containing material formed by contacting an aqueous solution of an amine/copper complex with a carrier, characterized in that the carrier is a hydrolyzed product obtained by hydrolyzing a silicate ester in the presence of ammonia; a process for producing the aforesaid hydrogenation catalyst composition; and a process for producing ethylene glycol or a glycolate ester in the presence of the aforesaid hydrogenation catalyst.

    10.
    发明专利
    未知

    公开(公告)号：DE1919840C3

    公开(公告)日：1974-07-11

    申请号：DE1919840

    申请日：1969-04-18

    Applicant: UBE INDUSTRIES

    Inventor： YAMADA KEISHO ,  NAGAI SHIGEKI ,  ODAN KYOJI ,  NAKAMURA YASUO ,  HIDAKA MIKIO

    IPC: B01J23/31 ,  B01J35/00 ,  C07C121/32 ,  B01J11/00

    Abstract: 1,233,491. Ammoxidation catalysts. UBE INDUSTRIES Ltd. 14 March, 1969 [2 July, 1968; 12 July, 1968], No. 13690/69. Heading B1E. [Also in Divisions C1 and C2] An ammoxidation catalyst comprises 95-50 parts wt. of a bismuth antimonate in which the atomic ratio of bismuth to antimony is 1:1, containing less than 10% wt. of other bismuth antimonates and 5-50 parts wt. of a bismuth molybdate and/or bismuth tungstate in which the atomic ratio of bismuth to molybdenum or tungsten is 2:3, containing less than 20% wt. of other bismuth molybdates or tungstates. The catalyst may be supported, e.g. by silica, alumina, alumina-silica, silicates or carborundum, inactivated by treatment at elevated temperatures. Surface areas of 1 to 3 m 2 /g are disclosed.

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