Abstract:
PROBLEM TO BE SOLVED: To provide an industrial tube which has a polyamide resin layer having superior impermeability of various liquids, steam and/or gas, having a wide moldable temperature and superior melting-moldability, low moisture absorbency, chemical resistance, and hydrolysis resistance. SOLUTION: The industrial tube is characterized by including the polyamide resin layer in which a dicarboxylic acid component consists of oxalic acid, a diamine component consists of 1,9-nonane diamine and 2-methyl-1,8-octane diamine, and a molar ratio of the 1,9-nonane diamine to 2-methyl-1,8-octane diamine is 1:99 to 99:1. COPYRIGHT: (C)2011,JPO&INPIT
Abstract:
PURPOSE: To obtain a crystalline copolyamide excellent in heat resistance and rigidity by producing a copolyamide consisting of hexamethyleneterephthalamide units, hexamethyleneisophthalamide units and ε-capronamide units at a specified molar ratio. CONSTITUTION: This copolyamide consists of hexamethyleneterephthalamide units (A), hexamethyleneisophthalamide units (B) and ε-capronamide units (C) of the formula (wherein n is 10 or 11), wherein the proportions of these units are adjusted so as to provide a composition represented by any point within the circumference defined by the points (75,22,3), (75,10,15), (64,10,26), (48,26,26) and (48,49,3) on a triangular diagram (A,B,C) showing the proportions (mol%) to thereby produce a crystalline copolyamide. The obtained resin gives a molding having high deflection temperature under load, tough with excellent tensile elongation, impact strength, etc., and excellent in dimensional stability.
Abstract:
PURPOSE:To provide a special polyamide separation membrane for separating a cyclohexane derivative from a mixed system containing said derivative. CONSTITUTION:A cyclohexane derivative separating membrane is composed of polyamide having a polyoxyethylene chain in its side chain or in its side chain and terminal.
Abstract:
PURPOSE:To obtain a gas separating membrane having superior selective permeability to CO2 and steam by forming a gas separating layer of a polyamide grafted with alkylene oxide. CONSTITUTION:A gas separating layer of an alkylene oxide grafted polyamide is formed to obtain a gas separating membrane for separating CO2 and/or steam from a gaseous mixture contg. CO2 and/or steam. The grafted polyamide may be produced by grafting 2-alkylene oxide on polyamide such as nylon.
Abstract:
PURPOSE:To enable the separation and recovery of Ga from a Ga-containing solution in high selectivity and efficiency, by using a membrane containing a specific hydrophobic compound having N-nitrosohydroxyamine group. CONSTITUTION:A membrance containing a hydrophobic compound of formula (R1 is 3-30C straight, branched or alicyclic alkyl or alkenyl; R2 is phenylene, naphthylene, hydrophenylene or hydronaphthylene; X is H, inorganic or organic ammonium ion or alkali metal; n is 0, 1 or 2) having N-nitrosohydroxy amino group is prepared beforehand. Gallium is separated and recovered selectively from a gallium-containing solution by using the above membrane. The compound of formula is e.g. N-nitrophenylhydroxylamine ammonium salt, N- nitrosonaphthylhydroxylamine ammonium salt, etc., having hydrophobic substituent group such as octyl, dodecyl, etc.
Abstract:
PROBLEM TO BE SOLVED: To provide a more efficient method for producing a polyoxamide resin that shortens a polymerization cycle in the method for producing the polyoxamide resin.SOLUTION: In the production method for obtaining the polyoxamide resin by the polycondensation reaction of an oxalic acid diester and a diamine, the polymerization cycle is shortened due to the finding that a high molecular weight polyoxamide resin is produced without lowering the temperature in a pressure vessel to not higher than the melting point of the polyoxamide resin by adding 0.1-5.0 mol% excess oxalic acid diester to a diamine at a temperature not lower than the melting point of the polyoxamide resin obtained and mixing them, by performing pressure polymerization in the presence of alcohol produced by the polycondensation reaction, and then by performing melt polymerization at normal pressure and a temperature not lower than the melting point of the polyoxamide resin in the pressure vessel.
Abstract:
PROBLEM TO BE SOLVED: To provide a process for effectively producing a polyoxamide resin having a reduced viscosity of 1.3-5.0 by solid phase polymerization which inhibits decomposition and discoloration in the postpolymerization step in producing the polyoxamide resin.SOLUTION: The process for producing a polyoxamide resin from an oxalic diester and 1,5-pentanediamine comprises: synthesizing a prepolymer in the prepolymerization step with the use of the oxalic diester and the 1,5-pentanediamine; and then subjecting the powder of the obtained prepolymer to solid phase polymerization with the use of a horizontal rotational reactor.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for mixing raw materials so that unreacted raw materials do not remain and producing a polyoxamide resin so that the ballance of terminal group concentration is not destroyed instead of the conventional polycondensation process in a solvent, which is traditionally required for producing a polyoxamide resin, and the reaction at a high temperature under high pressure in a pressure-proof container.SOLUTION: In the method for producing the polyoxamide resin, using an oxalic acid diester and a diamine as raw materials, the diamine is preliminarily charged into a reservoir and then the oxalic acid diester is kneaded for mixing.