公开(公告)号：WO0230861A3

公开(公告)日：2002-08-29

申请号：PCT/US0131320

申请日：2001-10-04

Applicant: UNION CARBIDE CHEM PLASTIC ,  CULP GARY LYNN

Inventor： CULP GARY LYNN

IPC: C07C51/215 ,  C07C57/05 ,  C07C51/44 ,  C07C51/46 ,  C07C53/08

CPC classification number: C07C51/215 ,  Y02P20/582 ,  C07C53/08 ,  C07C57/04

Abstract: Continuous processes are provided for the partial oxidation in the vapor phase over a heterogeneous catalyst in a reaction zone of hydrocarbyl reactant to produce carboxylic acids or anhydrides wherein at least a portion of unreacted hydrocarbyl reactant is returned via a cyclic loop to the reaction zone. The partial oxidation generates carbon oxides which are used as ballast gas in the cyclic loop. The carboxylic acids or anhydrides are removed from the cyclic loop by condensation. Purification of the products can be by stripping lights and then dehydrating the carboxylic acid or anhydride product removed from the cyclic loop.

Abstract translation: 提供连续方法用于在烃基反应物的反应区中的非均相催化剂中的气相中的部分氧化，以产生羧酸或酸酐，其中至少一部分未反应的烃基反应物通过循环回路返回到反应区。 部分氧化产生在循环中用作压载气体的碳氧化物。 通过冷凝从环状环中除去羧酸或酸酐。 产物的纯化可以通过剥离光，然后使从循环中除去的羧酸或酸酐产物脱水。

公开(公告)号：NO20031209A

公开(公告)日：2003-05-13

申请号：NO20031209

申请日：2003-03-17

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： CULP GARY LYNN ,  STRICKER VINCENT JOSEPH ,  RUSSELL JAMES ,  BHASIN MADAN MOHAN ,  NIELSEN KENNETH ANDREW

IPC: B01J23/12 ,  B01J23/34 ,  C07B61/00 ,  C07C2/84 ,  C07C5/48 ,  C07C7/152 ,  C07C7/156 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/113

CPC classification number: C07C11/02 ,  C07C2/84 ,  C07C5/48 ,  C07C7/152 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/10 ,  C07C2523/28 ,  C07C2523/34 ,  C07C2527/232 ,  Y10S585/943

公开(公告)号：AU9266601A

公开(公告)日：2002-04-02

申请号：AU9266601

申请日：2001-09-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： CULP GARY LYNN ,  STRICKER VINCENT JOSEPH ,  NELSON JAMES RUSSELL ,  BHASIN MADAN MOHAN ,  NIELSEN KENNETH ANDREW

IPC: B01J23/12 ,  B01J23/34 ,  C07B61/00 ,  C07C2/84 ,  C07C5/48 ,  C07C7/152 ,  C07C7/156 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/113

Abstract: The present invention provides methods for manufacturing olefins such as ethylene and propylene from lower alkanes, that is, methane, ethane and/or propane, by oxidative dehydrogenation at elevated pressure. The olefins are selectively recovered from unconverted lower alkane feed and reaction byproducts by using a complexation separation, such as an absorption separation that uses aqueous silver nitrate as the complexation agent. Catalysts are used that give high selectivity for oxidative dehydrogenation of lower alkanes to olefins at elevated pressure, such as a nonstoichiometric rare earth oxycarbonate catalyst.

公开(公告)号：MY117933A

公开(公告)日：2004-08-30

申请号：MYPI20014358

申请日：2001-09-18

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： CULP GARY LYNN ,  STRICKER VINCENT JOSEPH ,  NELSON JAMES RUSSELL ,  BHASIN MADAN MOHAN ,  NIELSEN KENNETH ANDREW

IPC: B01J23/12 ,  B01J23/34 ,  C07B61/00 ,  C07C2/84 ,  C07C5/48 ,  C07C7/152 ,  C07C7/156 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/113

Abstract: THE PRESENT INVENTION PROVIDES METHOD FOR MANUFACTURING OLEFINS SUCH AS ETHYLENE AND PROPYLENE FROM LOWER ALKANES (5), THAT IS, METHANE, ETHANE AND/OR PROPANE, BY OXIDATIVE DEHYDROGENATION AT ELEVATED PRESSURE. THE OLEFINS ARE SELECTIVELY RECOVERED FROM UNCONVERTED LOWER ALKANE (10) FEED AND REACTION BYPRODUCTS BY USING A COMPLEXATION SEPARATION, SUCH AS AN ABSORPTION SEPARATION THAT USES AQUEOUS SILVER NITRATE AS THE COMPLEXATION AGENT. CATALYSTS ARE USED THAT GIVE HIGH SELECTIVITY FOR OXIDATIVE DEHYDROGENATION OF LOWER ALKANES (5) TO OLEFINS (8) AT ELEVATED PRESSURE, SUCH AS A NONSTOICHIOMETRIC RARE EARTH OXYCARBONATE CATALYST.

公开(公告)号：NO20031209L

公开(公告)日：2003-05-13

申请号：NO20031209

申请日：2003-03-17

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： CULP GARY LYNN ,  STRICKER VINCENT JOSEPH ,  RUSSELL JAMES ,  BHASIN MADAN MOHAN ,  NIELSEN KENNETH ANDREW

IPC: B01J23/34 ,  C07B61/00 ,  C07C2/84 ,  B01J23/12 ,  C07C5/48 ,  C07C7/152 ,  C07C7/156 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/113

Abstract: The present invention provides methods for manufacturing olefins such as ethylene and propylene from lower alkanes, that is, methane, ethane and/or propane, by oxidative dehydrogenation at elevated pressure. The olefins are selectively recovered from unconverted lower alkane feed and reaction byproducts by using a complexation separation, such as an absorption separation that uses aqueous silver nitrate as the complexation agent. Catalysts are used that give high selectivity for oxidative dehydrogenation of lower alkanes to olefins at elevated pressure, such as a nonstoichiometric rare earth oxycarbonate catalyst.

公开(公告)号：NO20031209D0

公开(公告)日：2003-03-17

申请号：NO20031209

申请日：2003-03-17

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： CULP GARY LYNN ,  STRICKER VINCENT JOSEPH ,  RUSSELL JAMES ,  BHASIN MADAN MOHAN ,  NIELSEN KENNETH ANDREW

IPC: B01J23/34 ,  B01J23/12 ,  C07B61/00 ,  C07C2/84 ,  C07C5/48 ,  C07C7/152 ,  C07C7/156 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/113 ,  C07C

Abstract: The present invention provides methods for manufacturing olefins such as ethylene and propylene from lower alkanes, that is, methane, ethane and/or propane, by oxidative dehydrogenation at elevated pressure. The olefins are selectively recovered from unconverted lower alkane feed and reaction byproducts by using a complexation separation, such as an absorption separation that uses aqueous silver nitrate as the complexation agent. Catalysts are used that give high selectivity for oxidative dehydrogenation of lower alkanes to olefins at elevated pressure, such as a nonstoichiometric rare earth oxycarbonate catalyst.

公开(公告)号：AU9666601A

公开(公告)日：2002-04-22

申请号：AU9666601

申请日：2001-10-04

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： CULP GARY LYNN

IPC: C07C51/215 ,  C07C57/05 ,  C07C53/08

公开(公告)号：CA2421816C

公开(公告)日：2009-11-17

申请号：CA2421816

申请日：2001-09-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： NELSON JAMES RUSSELL ,  BHASIN MADAN MOHAN ,  STRICKER VINCENT JOSEPH ,  CULP GARY LYNN ,  NIELSEN KENNETH ANDREW

IPC: B01J23/12 ,  C07C11/02 ,  B01J23/34 ,  C07B61/00 ,  C07C2/84 ,  C07C5/48 ,  C07C7/152 ,  C07C7/156 ,  C07C11/04 ,  C07C11/06 ,  C07C11/113

Abstract: The present invention provides methods for manufacturing olefins such as ethylene and propylene from lower alkanes, that is, methane, ethane and/or propane, by oxidative dehydrogenation at elevated pressure. The olefins are selectively recovered from unconverted lower alkane feed and reaction byproducts by using a complexation separation, such as an absorption separation that uses aqueous silver nitrate as the complexation agent. Catalysts are used that give high selectivity for oxidative dehydrogenation of lower alkanes to olefins at elevated pressure, such as a nonstoichiometric rare earth oxycarbonate catalyst.

公开(公告)号：BR0114133A

公开(公告)日：2003-07-29

申请号：BR0114133

申请日：2001-09-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： CULP GARY LYNN ,  STRICKER VICENT JOSEPH ,  NELSON JAMES RUSSELL ,  BHASIN MADAN MOHAN ,  NIELSEN KENNETH ANDREW

IPC: B01J23/12 ,  B01J23/34 ,  C07B61/00 ,  C07C2/84 ,  C07C5/48 ,  C07C7/152 ,  C07C7/156 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/113

Abstract: The present invention provides methods for manufacturing olefins such as ethylene and propylene from lower alkanes, that is, methane, ethane and/or propane, by oxidative dehydrogenation at elevated pressure. The olefins are selectively recovered from unconverted lower alkane feed and reaction byproducts by using a complexation separation, such as an absorption separation that uses aqueous silver nitrate as the complexation agent. Catalysts are used that give high selectivity for oxidative dehydrogenation of lower alkanes to olefins at elevated pressure, such as a nonstoichiometric rare earth oxycarbonate catalyst.

公开(公告)号：CA2421816A1

公开(公告)日：2002-03-28

申请号：CA2421816

申请日：2001-09-14

Applicant: UNION CARBIDE CHEM PLASTIC

Inventor： NIELSEN KENNETH ANDREW ,  STRICKER VINCENT JOSEPH ,  BHASIN MADAN MOHAN ,  NELSON JAMES RUSSELL ,  CULP GARY LYNN

IPC: B01J23/12 ,  B01J23/34 ,  C07B61/00 ,  C07C2/84 ,  C07C5/48 ,  C07C7/152 ,  C07C7/156 ,  C07C11/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/113

Abstract: The present invention provides methods for manufacturing olefins such as ethylene and propylene from lower alkanes, that is, methane, ethane and/or propane, by oxidative dehydrogenation at elevated pressure. The olefins are selectively recovered from unconverted lower alkane feed and reaction byproducts by using a complexation separation, such as an absorption separation that uses aqueous silver nitrate as the complexation agent. Catalysts are used that give high selectivity for oxidative dehydrogenation of lower alkanes to olefins at elevated pressure, such as a nonstoichiometric rare earth oxycarbonate catalyst.